A solar thermal fuel can include a plurality of photoswitchable moieties associated with a nanomaterial. The plurality of photoswitchable moieties can be densely arranged on the nanomaterial, such that adjacent photoswitchable moieties interact with one another. The solar thermal fuel can provide high volumetric energy density.

A solar thermal fuel can include a plurality of photoswitchable moieties associated with a nanomaterial. The plurality of photoswitchable moieties can be densely arranged on the nanomaterial, such that adjacent photoswitchable moieties interact with one another. The solar thermal fuel can provide high volumetric energy density.

The present disclosure relates to an azobenzene-graphene metal coordination solar photothermal energy storage material based on metal coordination bonds and a preparation method thereof. The method comprises the following steps: preparing reduced graphene oxide; preparing an azobenzene-graphene material; and preparing an azobenzene-graphene metal coordination solar photothermal energy storage material: dispersing the prepared azobenzene-graphene material in DMF, dissolving a certain amount of metal compound in DMF, adding the DMF solution of the metal compound into the DMF solution of the azobenzene-graphene, taking out the precipitate, washing off metal ions which do not participate in coordination, and drying the obtained product to obtain the azobenzene-graphene metal coordination solar photothermal energy storage material. The present disclosure also relates to a method for improving the solar photothermal energy storage ability of a molecular solar energy fuel, comprising using an azobenzene-graphene metal coordination solar photothermal energy storage material.

The present disclosure relates to an azobenzene-graphene metal coordination solar photothermal energy storage material based on metal coordination bonds and a preparation method thereof. The method comprises the following steps: preparing reduced graphene oxide; preparing an azobenzene-graphene material; and preparing an azobenzene-graphene metal coordination solar photothermal energy storage material: dispersing the prepared azobenzene-graphene material in DMF, dissolving a certain amount of metal compound in DMF, adding the DMF solution of the metal compound into the DMF solution of the azobenzene-graphene, taking out the precipitate, washing off metal ions which do not participate in coordination, and drying the obtained product to obtain the azobenzene-graphene metal coordination solar photothermal energy storage material. The present disclosure also relates to a method for improving the solar photothermal energy storage ability of a molecular solar energy fuel, comprising using an azobenzene-graphene metal coordination solar photothermal energy storage material.

Apparatus operable using concentrated solar radiation, the apparatus comprising a body having a cavity adapted to receive concentrated solar radiation, a heat energy absorber associated with the cavity to receive heat from concentrated solar radiation within the cavity, a chamber containing a body of matter, the chamber being in heat exchange relation with the heat energy absorber to receive heat therefrom for heating the body of matter, and an inlet means for introducing fluid into the chamber for contacting the contained body of matter. Also, a reactor system for contacting a reactant liquid with two gaseous reactants, the reactor system comprising two reactors interconnected for circulation of a reactant liquid therebetween, whereby the circulating reactant liquid is enabled to react with a gaseous reactant introduced into one reactor and to also react with a gaseous reactant introduced into the other reactor.

The invention proposes a method and a device (110) for thermal-electrochemical energy storage and energy provision. The device (110) comprises: at least one thermal energy store (118), wherein the thermal energy store (118) comprises at least one heat transport medium (121) and at least one storage medium (119) selected from the group consisting of: an electromagnetic storage medium, a thermal storage medium; at least one heating device (134), wherein the heating device (134) is designed to receive the heat transport medium (121) from the thermal energy store (118), to heat this medium and return it to the thermal energy store (118); at least one electrochemical cell (146), wherein the electrochemical cell (146) comprises at least one gas chamber (148), wherein the electrochemical cell (146) further comprises at least one first electrode (150) and at least one second electrode (152): wherein the second electrode (152) is designed as a 3-phase electrode (154), wherein the 3-phase electrode (154) has at least one first phase boundary (156) to the gas chamber (148) and at least one second phase boundary (158) to the electrochemical storage medium (119); wherein the electrochemical cell (146) is designed to electrochemically react the electrochemical storage medium (119); and at least one container (160), wherein the container (160) is designed to receive a supply on the heat transport medium (119), wherein the container (160) is further designed to receive the thermal storage medium (119) from the thermal energy store (118).

The invention proposes a method and a device (110) for thermal-electrochemical energy storage and energy provision. The device (110) comprises: at least one thermal energy store (118), wherein the thermal energy store (118) comprises at least one heat transport medium (121) and at least one storage medium (119) selected from the group consisting of: an electromagnetic storage medium, a thermal storage medium; at least one heating device (134), wherein the heating device (134) is designed to receive the heat transport medium (121) from the thermal energy store (118), to heat this medium and return it to the thermal energy store (118); at least one electrochemical cell (146), wherein the electrochemical cell (146) comprises at least one gas chamber (148), wherein the electrochemical cell (146) further comprises at least one first electrode (150) and at least one second electrode (152): wherein the second electrode (152) is designed as a 3-phase electrode (154), wherein the 3-phase electrode (154) has at least one first phase boundary (156) to the gas chamber (148) and at least one second phase boundary (158) to the electrochemical storage medium (119); wherein the electrochemical cell (146) is designed to electrochemically react the electrochemical storage medium (119); and at least one container (160), wherein the container (160) is designed to receive a supply on the heat transport medium (119), wherein the container (160) is further designed to receive the thermal storage medium (119) from the thermal energy store (118).

A method and a system of a high-temperature calcium looping thermochemical energy storage are provided. A thermochemical energy storage system is based on CaCO.sub.3/CaO, and an energy storage is performed by a mutual transformation between a thermal energy and a chemical energy. When solar irradiation is sufficient, CaCO.sub.3 solid particulates are indirectly heated by hot air generated from solar energy to perform an endothermic decomposition reaction, and received heat is stored in decomposition products of CaO and CO.sub.2 in a form of the chemical energy. When heat is required, a reversible thermochemical reaction occurs between the CaO and CO.sub.2 under an atmospheric pressure, and the chemical energy stored in the CaO and CO.sub.2 is transformed into the heat for release.

A method and a system of a high-temperature calcium looping thermochemical energy storage are provided. A thermochemical energy storage system is based on CaCO.sub.3/CaO, and an energy storage is performed by a mutual transformation between a thermal energy and a chemical energy. When solar irradiation is sufficient, CaCO.sub.3 solid particulates are indirectly heated by hot air generated from solar energy to perform an endothermic decomposition reaction, and received heat is stored in decomposition products of CaO and CO.sub.2 in a form of the chemical energy. When heat is required, a reversible thermochemical reaction occurs between the CaO and CO.sub.2 under an atmospheric pressure, and the chemical energy stored in the CaO and CO.sub.2 is transformed into the heat for release.

An inflatable non-imaging solar concentrator powered high temperature thermo-chemical reaction system, which is designed to reduce CO2 into CO and H2O into H2 for liquid fuels such as methanol and kerosene, comprises: 1) an inflatable non-imaging solar concentrator with a transparent cover and a Compound Parabolic Concentrator (CPC); 2) the first stage of the multi-stage non-imaging non-tracking solar concentrator with a domed divergent Fresnel Lens transparent cover and a CPC; 3) the second stage of the multi-stage non-imaging non-tracking solar concentrator with a domed divergent Fresnel Lens transparent cover and a CPC; 4) a high temperature thermo-chemical reactor with a steel high pressure vessel, an insulation layer, a first CeO2 catalyst layer, and a second CeO2 catalyst layer.