F01N3/2073

Exhaust gas purification device for internal combustion engine, and vehicle
11761364 · 2023-09-19 · ·

Provided is an exhaust gas purification apparatus having a control device that monitors the transition of a detection value of each of an upstream NOx sensor and a downstream NOx sensor, and when the NOx purification rate of the SCR catalyst falls to a value of a first threshold or lower, generates an abnormality detection signal indicating that an over storage state has occurred in an SCR catalyst if the amount of change in the detection value of the upstream NOx sensor per unit time is at least a second threshold and the amount of change in the detection value of the downstream NOx sensor per unit time is at most a third threshold.

Systems and methods for generating ammonia

An ammonia generating apparatus comprises a housing comprising a first end wall on which a reductant injector configured to insert a reductant into the housing is mountable. A heating coil assembly is disposed within the housing. A first end of the heating coil assembly is located proximate to a location of the first end wall where a reductant injector tip of the reductant injector is located when the reductant injector is mounted on the first end wall. The heating coil assembly is configured to generate heat sufficient to thermolyze the reductant to generate ammonia and reaction byproducts, in response to an electric current being passed therethrough. A hydrolysis catalyst can be disposed downstream of the heating coil assembly for catalyzing hydrolysis of the reaction byproducts into ammonia.

INTERNAL COMBUSTION ENGINE WITH EXHAUST GAS AFTERTREATMENT AND CONTROL OF THE NITROGEN OXIDE EMISSIONS
20220403793 · 2022-12-22 ·

An internal combustion engine, with an engine regulating device and an exhaust gas aftertreatment device with an SCR catalytic converter for the reduction of at least one NO.sub.x component, and with a catalytic converter regulating device, wherein the engine regulating device is prescribed a target value for an NO.sub.x mean value of the NO.sub.x component of the exhaust gases, which mean value results at an outlet point of the exhaust gas aftertreatment device in relation to a predefinable time period, and the engine regulating device is configured at least in one operating mode to continuously calculate an NO.sub.x reference value for the catalytic converter regulating device with consideration of No.sub.x components which have already been emitted and the predefined target value, which reference value is selected in such a way that the predefined target value results at the outlet point of the exhaust gas aftertreatment device at the end of the predefinable time period when the calculated NO.sub.x reference value of the catalytic converter regulating device is fed as NO.sub.x setpoint value to the regulating means.

Combustion system

Provided is a combustion system using a catalyst having better denitration efficiency at low temperatures, during a selective catalytic reduction reaction in which ammonia is used as a reducing agent. This combustion system comprises: a combustion device that combusts fuel; an exhaust path through which flows exhaust gas generated from the combustion of fuel in the combustion device; a dust collection device that is arranged on the exhaust path and collects ash dust/dust in the exhaust gas; and a denitration device that is arranged on the exhaust path and removes nitrogen oxides from the exhaust gas by means of a denitration catalyst, wherein the denitration device is arranged downstream of the dust collection device on the exhaust path, and the denitration catalyst contains vanadium oxide including vanadium pentoxide and has a defect site in which an oxygen atom is deficient in a crystal structure of the vanadium pentoxide.

Method for monitoring a gas sensor

A method for monitoring a gas sensor (14) which comprises two electrochemical measuring cells (20, 30) and which is arranged in an exhaust tract (10) of an internal combustion engine (11), wherein the sensor elements (20, 30) exhibit a substantially identical sensitivity towards a first gas component and a different sensitivity towards a second gas component and are insensitive towards further gas components. In an operating state in which an exhaust gas stream at the gas sensor (14) contains less of the second gas component than of the first gas component a concentration of the first gas component is calculated from each of the sensor signals from the sensor elements (20, 30) and a defect in a sensor element (20, 30) is deduced from the concentrations of the first gas component.

PERFORMANCE ENHANCEMENT OF A PLATINUM-CONTAINING CATALYST VIA EXHAUST GAS HYDROGEN ENRICHMENT
20230338940 · 2023-10-26 ·

The disclosure provides a platinum-containing three-way conversion (TWC) catalyst, and a system for treating an exhaust gas stream from a gasoline engine using the TWC catalyst. The system is configured to introduce controlled quantities of hydrogen gas into the exhaust gas stream upstream of the platinum-containing TWC catalyst article during a cold-start period. Further provided are related methods of treating such exhaust streams. Such systems and methods are useful in reducing a level of one or more of hydrocarbons, carbon monoxide, and nitrogen oxide in a gaseous exhaust stream from a gasoline engine.

Method for adapting an amount of reductant for controlling the nitrogen oxide pollution of gases in a motor exhaust line

In a process for adapting an amount of reducing agent for a removal of nitrogen oxides from the gases in an exhaust line, a first alignment of the amounts of nitrogen oxides measured by upstream and downstream sensors is performed without injection of agent and with a catalyst of the system emptied of ammonia. A second alignment of the estimated reduction of nitrogen oxides with the measured reduction is performed by a difference between amounts of nitrogen oxides upstream and downstream during a substoichiometric injection of reducing agent without creating a store of ammonia in a catalyst of the system with a first correction of the amount of agent. A third alignment of an estimated efficiency of retaining nitrogen oxides with a efficiency measured by the sensors is performed, this third alignment taking place via a second correction of the amount of reducing agent injected as an adaptive correction.

Internal combustion engine with exhaust gas aftertreatment and control of the nitrogen oxide emissions

An internal combustion engine (1), with an engine regulating device (3) and an exhaust gas aftertreatment device (16) with an SCR catalytic converter (4) for the reduction of at least one NO.sub.x component, and with a catalytic converter regulating device (6), wherein the engine regulating device (3) is prescribed a target value for an NO.sub.x mean value of the NO.sub.x component of the exhaust gases, which mean value results at an outlet point (7) of the exhaust gas aftertreatment device (16) in relation to a predefinable time period, and the engine regulating device (3) is configured at least in one operating mode to continuously calculate an NO.sub.x reference value for the catalytic converter regulating device (6) with consideration of No.sub.x components which have already been emitted and the predefined target value, which reference value is selected in such a way that the predefined target value results at the outlet point of the exhaust gas aftertreatment device (16) at the end of the predefinable time period when the calculated NO.sub.x reference value of the catalytic converter regulating device (6) is fed as NO.sub.x setpoint value to the regulating means.

Reductant injecting device, exhaust gas processing device and exhaust gas processing method
11391191 · 2022-07-19 · ·

A reductant injecting device includes: a honeycomb structure comprising: a pillar shaped honeycomb structure portion having a partition wall that defines a plurality of cells each extending from a fluid inflow end face to a fluid outflow end face; and at least one pair of electrode portions arranged on a side surface of the honeycomb structure portion; an outer cylinder being configured to house the honeycomb structure, the outer cylinder having a carrier gas introduction port on the fluid inflow end face side; a urea sprayer arranged at one end of the outer cylinder; a carrier gas introduction cylinder provided at the carrier gas introduction port of the outer cylinder; and a carrier gas flow rate amplifier provided in the carrier gas introduction cylinder.

Aftertreatment system and method of treating exhaust gases
11415034 · 2022-08-16 · ·

An aftertreatment system for treatment of exhaust gases exiting an engine includes a first Selective Catalytic Reduction (SCR) device in fluid communication with the engine. The first SCR device receives the exhaust gases exiting the engine for reducing a first quantity of oxides of nitrogen (NOx) present in the exhaust gases. The aftertreatment system also includes an oxidation catalyst in fluid communication with the first SCR device. The oxidation catalyst receives the exhaust gases exiting the first SCR device for oxidizing ammonia present in the exhaust gases into a second quantity of NOx. The aftertreatment system further includes a second SCR device in fluid communication with the oxidation catalyst. The second SCR device receives the exhaust gases exiting the oxidation catalyst for reducing the second quantity of NOx.