An embodiment provides a method for deriving an alkalinity measurement, including: introducing a fluid sample; measuring, a phosphate amount of the fluid sample using a colorimetric reagent; measuring a pH of the fluid sample, wherein the pH of the fluid sample correlates to a hydroxide amount of the fluid sample; introducing an acid to convert all the inorganic carbon to carbon dioxide; applying a positive potential to the SP3 substituted carbon electrode; introducing, prior to or substantially simultaneously during the application of the positive potential to the SP3 substituted carbon electrode and in the reaction chamber, at least one acid reagent comprising a metallic catalyst that converts the carbonate and the partially oxidized species to carbon dioxide; determining total organic carbon by detecting an amount of carbon dioxide produced by the oxidation; determining the total organic carbon from the oxidation of the organic carbon species, and determining a derived alkalinity based upon the phosphate amount, the hydroxide amount, and the amount of carbon dioxide generated from the inorganic carbon. Other aspects are described and claimed.

Provided is method of detecting presence or absence of a liquid suctioned by a syringe pump. The method includes, in a following order: a step of detecting a change in electrostatic capacitance between a pair of electrodes provided to a syringe, having a tubular shape in which a piston is moved in an axial direction of the syringe, of a syringe pump; and a step of detecting that liquid suction has been performed by the syringe pump based on the change in the electrostatic capacitance.

A method for measuring TOC in test water is disclosed. Test water is injected into a combustion tube, which is controlled to be heated in a state of flowing carrier air generated by discharging stored water filled in a combustion gas or carrier air storage tank. After the drying process, temperature in the combustion tube is increased, and the dried organic carbon is burned. Combustion gas is guided to the combustion gas storage tank. An inside of the combustion tube is purified due to high pressure steam generated by injecting pure water and organic carbon removed in the purification process is burned and oxidized. The generated combustion gas is guided to the combustion gas storage tank and is pushed into an infrared meter to measure a carbon dioxide gas concentration. Otherwise, the generated combustion gas is guided to the infrared meter to measure the carbon dioxide gas concentration.

A water quality analyzer includes: a sample reservoir (20) including a first storage container (22) configured to temporarily store sample water supplied from a sample water source, and a discharge mechanism (24) configured to discharge the sample water to an outside of the first storage container (22); at least one second storage container (32) provided as a container different from the first storage container (22) for storing the sample water; a measurement device (10) including a measurement cell (12) for accommodating sample water, the measurement device (12) being configured to obtain a measured value of a physical quantity related to the sample water accommodated in the measurement cell (12); a pump (2) configured to suction and discharge a liquid, wherein the pump (2) is fluidly connected to any one of the first storage container (22), the second storage container (32), and the measurement cell (12) selectively; a switching device (4;6) configured to switch fluidly connection of the pump (2) with the first storage container (22), the second storage container (22) and the measurement cell (12); a determination part (40) configured to determine whether the measured value is normal or abnormal by comparing the measured value with a preset threshold; a measurement controller (38) configured to transfer the sample water stored in the first storage container (22) to the measurement cell (12) using the pump (2) by controlling an operation of the pump (2) and an operation of the switching device (4;6); a first storage controller (42) configured to control an operation of the sample reservoir (20), wherein the first storage controller (42) is configured, after a portion of the sample water stored in the first storage container (22) is supplied to the measurement cell (12) by the pump (2), to make the sample water in the first storage container (22) to remain in the first storage container (22) until the determination part determines the measured value of the sample water which has supplied to the measurement cell (12), and wherein the first storage controller (42) is configured to discharge the sample water remaining in the first storage container (22) to the outside of the first storage container (22) in a case where the determination part (40) determines that the measured value obtained by the measurement device (10) is normal; and a second storage controller (44) con

An automated total organic carbon analyzer is described. Embodiments of the system include two features, namely the development of a selective oxidation reactor to oxidize organic contaminants to their corresponding organic acids, and the measurement of the organic acids individually by chain length using an electroanalytical detector. Combining this electroanalytical approach with sequential detection capabilities (such as spectrophotometry) can expand the instrument capabilities by providing organic contaminant speciation. The described reactor performs selective oxidation of organic carbon to organic acids followed by complexation with a proprietary ligand, then selective detection using electroanalytical accumulation and desorption of organic acids performed at an electrode surface.

A furnace system features a combination of a furnace, a main combustion furnace tube and a disposable guard tube. The main combustion furnace tube is configured to couple and extend from the furnace, made of a quartz tube material, and has a zone for a combustion catalyst or high temperature support configured or formed therein. The disposable guard tube is coupled to the main combustion furnace tube, has a top opening configured to receive and have direct exposure to a liquid sample being injected into the main combustion furnace tube, and also has a bottom opening to provide the liquid sample to the main combustion furnace tube for processing in the zone for the combustion catalyst or high temperature support.

A measuring apparatus for determining the total organic carbon of a sample in a liquid medium includes a reactor block made of a metallic, electrically conductive, and corrosion-resistant material, the reactor block including a housing wall for accommodating a light source, the housing wall including an inlet into and an outlet from the reactor block and a flow chamber in which digestion of the sample for determining the total organic carbon occurs, the flow chamber configured to accommodate the light source and to route the sample to be irradiated with light, wherein the measuring apparatus further includes at least one conductivity measurement device, wherein the reactor block is an external electrode of the conductivity measurement device. A method for determining the total organic carbon of the sample using the measuring apparatus is disclosed.

An embodiment provides a method for measuring at least one characteristic of an aqueous sample, including: introducing an aqueous sample into a measurement device comprising one or more electrodes; oxidizing a transition metal to produce a higher valent metal by applying an electrical potential between an anode and a cathode of the measurement device; oxidizing, using the higher valent metal as a catalyst, a material within the aqueous sample; measuring a characteristic of the aqueous sample based upon the oxidized material, using a measurement device selected from the group consisting of: an electrochemical measurement device and an optical measurement device; and optimizing the electrical potential and at least one reagent delivered to the measurement device based on the measurement of the characteristic. Other aspects are described and claimed.

An automated total organic carbon analyzer is described. Embodiments of the system include two features, namely the development of a selective oxidation reactor to oxidize organic contaminants to their corresponding organic acids, and the measurement of the organic acids individually by chain length using an electroanalytical detector. Combining this electroanalytical approach with sequential detection capabilities (such as spectrophotometry) can expand the instrument capabilities by providing organic contaminant speciation. The described reactor performs selective oxidation of organic carbon to organic acids followed by complexation with a proprietary ligand, then selective detection using electroanalytical accumulation and desorption of organic acids performed at an electrode surface.

A device for analyzing total organic carbon (TOC) within a fluid at a desired temperature can include one or more transfer modules, each including a first and second transfer plate. A first fluid channel is formed in the first transfer plate and a second fluid channel is formed in the second transfer plate. A CO.sub.2 permeable membrane is disposed between the first fluid channel and the second fluid channel and a temperature measurement device measures a temperature of a fluid within the first and/or second fluid channel. A temperature control system is configured to heat or cool the transfer plates. Heating or cooling the transfer plates heats or cools the fluid within the first and/or second fluid channel to the desired temperature. One or more conductivity sensors are configured to measure a conductivity of the fluid within the first and/or second fluid channel.