An optical article, such as a spectacle lens, includes, on a substrate, a photochromic layer containing a photochromic dye and a resin component, and a protective layer. The indentation hardness of the photochromic layer in the thickness direction is in a range from 0.1 to 10 mgf/μm2. The value defined by the indentation hardness of the protective layer in the thickness direction multiplied by the thickness of the protective layer is five or more times and nine thousand or less times the value defined by the indentation hardness of the photochromic layer in the thickness direction multiplied by the thickness of the photochromic layer.

A photochromic compound including a core skeletal structure represented by the following Formula (I), ##STR00001## wherein D is oxygen or sulfur; E is oxygen, sulfur, or NR.sup.2′; a is 0 or 1; R.sup.1 is hydrogen, or substituted or unsubstituted alkyl; R.sup.2 and R.sup.2′ are each independently selected from hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, or substituted or unsubstituted heterocycloalkyl; and the photochromic compound is a thermally reversible photochromic compound.

A photochromic compound including a core skeletal structure represented by the following Formula (I), ##STR00001## wherein D is oxygen or sulfur; E is oxygen, sulfur, or NR.sup.2′; a is 0 or 1; R.sup.1 is hydrogen, or substituted or unsubstituted alkyl; R.sup.2 and R.sup.2′ are each independently selected from hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, or substituted or unsubstituted heterocycloalkyl; and the photochromic compound is a thermally reversible photochromic compound.

A scleral contact lens has a core containing an optical filter. The core and/or the optical filter may comprise oxygen impermeable material, such that an overall oxygen permeability of the core is insufficient to oxygenate a user's cornea when wearing the contact lens. To provide oxygenation to the user's cornea, the contact lens further comprises an outer covering, and an inner covering, each corresponding to a thin layer of gas-permeable material shaped to form a respective manifold between the covering and the core. Oxygen from an outside environment passes through the outer covering to reach the outer manifold, through an air path formed within the core to the inner manifold, and through the inner covering to reach the cornea of the user's eye.

A scleral contact lens has a core containing an optical filter. The core and/or the optical filter may comprise oxygen impermeable material, such that an overall oxygen permeability of the core is insufficient to oxygenate a user's cornea when wearing the contact lens. To provide oxygenation to the user's cornea, the contact lens further comprises an outer covering, and an inner covering, each corresponding to a thin layer of gas-permeable material shaped to form a respective manifold between the covering and the core. Oxygen from an outside environment passes through the outer covering to reach the outer manifold, through an air path formed within the core to the inner manifold, and through the inner covering to reach the cornea of the user's eye.

An apparatus comprising a switchable optical filter comprising a layer of switchable material, the switchable material comprising a photochromic/thermochromic, a photochromic/photochromic, or a photochromic/electrochromic compound; a first light source providing light of a wavelength that causes the switchable material to transition from a faded state to a dark state, or a dark state to a faded state; and a switch for controlling activation of the first light source.

An apparatus comprising a switchable optical filter comprising a layer of switchable material, the switchable material comprising a photochromic/thermochromic, a photochromic/photochromic, or a photochromic/electrochromic compound; a first light source providing light of a wavelength that causes the switchable material to transition from a faded state to a dark state, or a dark state to a faded state; and a switch for controlling activation of the first light source.

Embodiments described include bus bars for electrochromic or other optical state changing devices. The bus bars are configured to color match and/or provide minimal optical contrast with their surrounding environment in the optical device. Such bus bars may be transparent bus bars.

The present invention relates to a method for producing a photochromic oxy-hydride material as well as a photochromic component. The method comprising the steps of: —first the formation on a substrate of a layer of an essentially oxygen free rare earth metal hydride with a predetermined thickness using a physical vapor deposition process; and—second exposing the metal hydride layer to oxygen where the oxygen reacts with the metal hydride, said second step being performed in an environment having a water content defined by a water amount in air at sea level pressure with RH between >0% and 100% RH for temperatures between 0° C. and 40° C., preferably 25° Celsius.

The present invention relates to a method for producing a photochromic oxy-hydride material as well as a photochromic component. The method comprising the steps of: —first the formation on a substrate of a layer of an essentially oxygen free rare earth metal hydride with a predetermined thickness using a physical vapor deposition process; and—second exposing the metal hydride layer to oxygen where the oxygen reacts with the metal hydride, said second step being performed in an environment having a water content defined by a water amount in air at sea level pressure with RH between >0% and 100% RH for temperatures between 0° C. and 40° C., preferably 25° Celsius.