An electrochemical sensor for potentiometric measurements in a measurement medium has a sensor head (201) at an end of a longitudinal sensor body (203). A sensing electrode (210) and a reference electrode (220) are disposed within the longitudinal sensor body. A liquid junction (223) is established between the reference electrode and the sensing electrode. The sensor is characterized by a protective outer shaft (250) with a polymeric sensor sleeve (230), which is electrically isolating, disposed within the protective outer shaft.

A measuring device 1 according to the present disclosure measures a state of a solution L. The measuring device 1 includes a measuring unit 10 that outputs a measurement signal associated with the state of the solution L, a protection unit 20 attached to the measuring unit 10, and a controller 40 that obtains the information on the state of the solution L on the basis of a measurement signal output from the measuring unit 10. The measuring unit 10 has a first part P1 in a usable state that contributes to output of the measurement signal by coming into contact with the solution L, and a second part that is isolated from the solution L by the protection unit 20 and is in a standby state for measurement.

A measuring device 1 according to the present disclosure measures a state of a solution L. The measuring device 1 includes a measuring unit 10 that outputs a measurement signal associated with the state of the solution L, a protection unit 20 attached to the measuring unit 10, and a controller 40 that obtains the information on the state of the solution L on the basis of a measurement signal output from the measuring unit 10. The measuring unit 10 has a first part P1 in a usable state that contributes to output of the measurement signal by coming into contact with the solution L, and a second part that is isolated from the solution L by the protection unit 20 and is in a standby state for measurement.

The potentiometric sensor element comprises a measuring element and a shield housing permanently bonded to the measuring element, in which housing an electronic sensor unit is accommodated and which is sealed off against external influences. The electronic sensor unit is connected to a contactless interface adapted to exchange energy and signals with a corresponding contactless interface in an electronic base unit. The shield housing comprises an outer sleeve and an inner sleeve, accommodated within the outer sleeve, wherein the electronic sensor unit is accommodated in the inner sleeve and is surrounded there by a first casting compound. The filled inner sleeve is in turn bonded permanently to the outer sleeve by means of a second casting compound, which is different from the first casting compound.

The potentiometric sensor element comprises a measuring element and a shield housing permanently bonded to the measuring element, in which housing an electronic sensor unit is accommodated and which is sealed off against external influences. The electronic sensor unit is connected to a contactless interface adapted to exchange energy and signals with a corresponding contactless interface in an electronic base unit. The shield housing comprises an outer sleeve and an inner sleeve, accommodated within the outer sleeve, wherein the electronic sensor unit is accommodated in the inner sleeve and is surrounded there by a first casting compound. The filled inner sleeve is in turn bonded permanently to the outer sleeve by means of a second casting compound, which is different from the first casting compound.

A calibration electrode for calibrating a reference system of an electrochemical sensor, such as a potentiometric sensor or an ion selective electrode. The calibration electrode has an active surface comprising redox functionalities. The redox functionalities set the pH of a reference solution proximal to the calibration electrode. A voltammetric signal is applied to the calibration electrode to produce a response that is determined by the set pH. The response of the calibration electrode to the voltammetric signal is used to calibrate/adjust a reference potential produced by a reference electrode of the reference system of the electrochemical sensor. This calibration corrects the detrimental effect of reference electrode drift.

A calibration electrode for calibrating a reference system of an electrochemical sensor, such as a potentiometric sensor or an ion selective electrode. The calibration electrode has an active surface comprising redox functionalities. The redox functionalities set the pH of a reference solution proximal to the calibration electrode. A voltammetric signal is applied to the calibration electrode to produce a response that is determined by the set pH. The response of the calibration electrode to the voltammetric signal is used to calibrate/adjust a reference potential produced by a reference electrode of the reference system of the electrochemical sensor. This calibration corrects the detrimental effect of reference electrode drift.

An electrochemical sensor for potentiometric measurements in a measurement medium has a sensor head (201) at an end of a longitudinal sensor body (203). A sensing electrode (210) and a reference electrode (220) are disposed within the longitudinal sensor body. A liquid junction (223) is established between the reference electrode and the sensing electrode. The sensor is characterized by a protective outer shaft (250) with a polymeric sensor sleeve (230), which is electrically isolating, disposed within the protective outer shaft.

An electrochemical sensor for potentiometric measurements in a measurement medium has a sensor head (201) at an end of a longitudinal sensor body (203). A sensing electrode (210) and a reference electrode (220) are disposed within the longitudinal sensor body. A liquid junction (223) is established between the reference electrode and the sensing electrode. The sensor is characterized by a protective outer shaft (250) with a polymeric sensor sleeve (230), which is electrically isolating, disposed within the protective outer shaft.

According to at least one aspect of the present disclosure, a reference half-cell for an electrochemical sensor for measuring a medium is disclosed. The reference half-cell includes a housing defining a chamber containing an electrolyte, the housing including a wall having an aperture therethrough, and an electrode disposed in the electrolyte in the chamber. The reference half-cell further includes a reference junction disposed in the aperture such that an interface between the reference junction and the housing wall is impermeable. The reference junction is electrically or ionically conductive and impermeable to the measured medium and the electrolyte, and the reference junction enables a constant potential at the electrode. An electrochemical sensor and oxidation-reduction potential sensor employing the reference junction are also disclosed.