An immersion sensor is configured to determine the content of a chemical element in molten metal. The immersion sensor has an auxiliary electrochemical cell extending from an interior surface into the internal volume of a sampling chamber. The sampling chamber can be integrally-formed in a sensor head or in a separate refractory structure. The immersion sensor may be configured for the flow of molten metal into the internal volume of the sampling chamber and into contact with the auxiliary electrochemical cell.

A device for measuring pH levels and contaminant concentration includes an electrode assembly that is electrically coupled to a control unit. The electrode assembly includes a first contact electrically coupled to a reference electrode, a second contact electrically coupled to a working electrode, and a third contact electrically coupled to a counter electrode. The working electrode may be modified to include a cysteine functionalized graphene oxide with polypyrrole nanocomposite. In operation, the control unit may apply a complex signal to the working electrode via the second contact in order to adhere and subsequently strip contaminant ions from the fluid sample to the working electrode. During this process, a current may be measured across the working electrode and the counter electrode to measure contaminant ion concentration. The pH of the fluid sample may also be determined by a current measured across the reference electrode and the counter electrode. In some examples, the pH may be used to calibrate the measured levels of the contaminant ions.

A sensor for the detection of lead includes a substrate, a working electrode formed on a surface of the substrate, a counter electrode formed on the surface of the substrate, a dielectric layer covering a portion of the working electrode and counter electrode and defining an aperture exposing other portions of the working electrode and counter electrode. The working electrode includes a metalized film with working surface and a monolayer (or bilayer) of bismuth deposited on the working surface by underpotential deposition.

A sensor for the detection of lead includes a substrate, a working electrode formed on a surface of the substrate, a counter electrode formed on the surface of the substrate, a dielectric layer covering a portion of the working electrode and counter electrode and defining an aperture exposing other portions of the working electrode and counter electrode. The working electrode includes a metalized film with working surface and a monolayer (or bilayer) of bismuth deposited on the working surface by underpotential deposition.

A reference electrode which is stable over a wide range of temperatures, pressures and chemical conditions is provided. The subject reference electrode according to the present invention comprises a tubular enclosure composed of quartz having a distal, closed end and a proximal, open end. An insulating ceramic rod is seemingly connected to the opening in the closed distal end of the enclosure to form micro-cracks between the ceramic rod and the quartz enclosure (called a cracked junction, CJ). The CJ gives a very tortuous path for ion conduction from inside the reference electrode (RE) to a working electrode (WE). Inside the tubular enclosure is an electrical lead (e.g., a silver wire) disposed in an electrolyte comprising a mixture of alkaline metal salts (e.g., AgCl and KCl), extending from the electrolyte upward through a sealing means at the proximal end of the quartz enclosure.

A sensor and a measurement method for measuring hydrogen content in metal melt. The sensor has a solid proton conductor element, a reference electrode, a quasi-electrode to be measured, a reference compound, a through pipe and an insulating ceramic adhesive. The measurement method has the steps of: (1) inserting the sensor and a corrosion-resistant electrode into the metal melt, and making sure that the solid proton conductor element is fully immersed into the metal melt, the quasi-electrode to be measured is in direct contact with the metal melt and the contact surface is the electrode to be measured; (2) connecting a potentiometer and the reference electrode cable or the metal gas guide pipe to the corrosion-resistant electrode, and measuring a potential difference between the reference electrode and the electrode to be measured; and (3) calculating the hydrogen content S of the metal melt.

Problem Provided is an electrolyte analyzer that allows reducing a load of a user in a replacement work compared with conventional one.

Solution An electrolyte analyzer includes an ISE electrode 1 that includes at least one electrode, a reference electrode 2 that includes at least one electrode different from the ISE electrode 1, and a housing 200 that houses the electrodes of the ISE electrode 1 and the reference electrode 2. The housing 200 includes a pressing unit that presses the electrodes to one another, a first press switching unit 210 that switches the ISE electrode 1 between a secured state and a released state, and a second press switching unit 215 that switches the reference electrode 2 between a secured state and a released state. The ISE electrode 1 and the reference electrode 2 are each switched between the secured state and the released state. Selected Drawing: FIG. 3

The present application refers to a method for the reduction of the corrosiveness of a heat storage or heat transfer fluid material for the high-temperature range and a device for said method. The respective heat storage or heat transfer fluid material obtained by the method may be used in solar thermal power plants, conventional fossil power plants with higher flexibility, pumped thermal energy storage, combined heat and power plants, intermediate storage of high-temperature process heat, or in sensible heat storage with molten salts.

The present invention relates to an analyte sensor comprising a substrate, at least one first electrode, at least one second electrode and at least one protective layer covering the at least one second electrode. The present invention further relates to a process for manufacturing the inventive analyte sensor as well as to an analyte sensor system comprising an analyte sensor according to the present invention and an electronics unit. The analyte sensor according to the present invention may mainly be used for conducting analyte measurements in a body fluid of a user.

The control system of an internal combustion engine controls an internal combustion engine comprising an exhaust sensor. The control system comprises a motoring device driving rotation of a crankshaft of the internal combustion engine, a motoring control part configured to control the motoring device, a heater control part configured to control supply of electric power to the heater, and a temperature estimating part configured to estimate a temperature of the sensor element. The motoring control part is configured to drive the motoring device for a predetermined time when the temperature of the sensor element estimated by the temperature estimating part is outside a predetermined cracked element temperature region while the heater control part is supplying electric power to the heater, and stop driving the motoring device when the temperature of the sensor element is within the cracked element temperature region.