The present disclosure relates to an apparatus the for verification, calibration, and/or adjustment of a measuring instrument. The apparatus includes the measuring instrument, a reference measuring instrument, and a smart device. The apparatus performs a measuring operation in which the measuring instrument determines a value of a variable of the medium and the reference instrument determines a reference value of the variable from a sample of the medium. The measuring instrument communicates wirelessly and performs the verification, calibration, and/or adjustment on the basis of the measured value and the associated reference value. The reference measuring instrument is portable and communicates wirelessly with the smart device and the measuring instrument. An application executed on the smart device controls a data transfer between the measuring instrument, the reference measuring device, and/or the device that is required for executing the verification, calibration, and/or adjustment.

A sensor is configured to sense a parameter of an aqueous liquid. The sensor has an analog output port configured to provide an analog signal indicative of a sensed parameter, and a calibration memory device storing individual digital information indicative of a calibration of the sensor. A digital output port provides a digital signal indicative of the digital information. A treatment system and method is matched to the sensor.

A sensor service prediction system and method are provided for a sensor. The system monitors sensor operations of the sensor, and provides a calendar age odometer which increments a calendar age of the sensor by a first time interval as the sensor operates. The system further provides an accelerated age odometer which increments an accelerated age of the sensor by a second time interval according to the increment of the calendar age and a sensor temperature or other measurable environmental condition associated therewith. The system obtains a value of a sensor property at different calendar ages or accelerated ages of the sensor over time, and predicts and outputs when the sensor property of the sensor is anticipated to reach a sensor property threshold based on the values of the sensor property in relations to the accelerated age.

An embodiment provides a method for modifying a carbon region on a boron-doped diamond electrode surface, comprising: placing a boron-doped diamond electrode surface in an aqueous solution, wherein the aqueous solution comprises an ionic treatment solution; applying a voltage difference across the boron-doped diamond electrode surface; and modifying a carbon region on an area of the boron-doped diamond electrode surface, wherein the modifying is responsive to application of the voltage while the boron-doped diamond electrode surface is in the aqueous solution, wherein the modification continues until a desired signal of the carbon region is reached. Other aspects are described and claimed.

A pH sensing that is configured to be exposed to a process fluid is provided. The pH sensing probe includes a sensor body and a pH glass electrode mounted to the sensor body. A reference electrode has a junction mounted to the sensor body that is configured to be exposed to the process fluid. A backup pH electrode is mounted to the sensor body and configured to be exposed to the process fluid. A pH sensing system and a method of operating a pH sensing system are also provided. In one example, the backup pH electrode is an ISFET electrode that can be automatically switched to when the pH glass electrode is compromised.

An embodiment provides a method for modifying a carbon region on a boron-doped diamond electrode surface, comprising: placing a boron-doped diamond electrode surface in an aqueous solution, wherein the aqueous solution comprises an ionic treatment solution; applying a voltage difference across the boron-doped diamond electrode surface; and modifying a carbon region on an area of the boron-doped diamond electrode surface, wherein the modifying is responsive to application of the voltage while the boron-doped diamond electrode surface is in the aqueous solution, wherein the modification continues until a desired signal of the carbon region is reached. Other aspects are described and claimed.

A self-vibrating pH probe comprise a housing containing an electronic assembly to which is coupled a vibration source element so that at least a portion of vibrations caused by the vibration source element propagate to the electronic assembly, the vibration source element being controllable for at least on/off operation. The self-vibrating pH probe further comprising a pH probe member having a probe tip at a first end, the probe member extending from the housing and mechanically and electrically coupled by a second end to the electronic assembly so that at least a portion of vibrations propagating to the electronic assembly further propagate to the probe tip; and further including a processor coupled to the electronic assembly for coordinating operation of the vibration source element and operation of the pH probe member.

Disclosed is a food wash sensor system that includes a sensor disposed along a fluid flow path that can circulate a wash fluid through the food wash sensor system. The sensor can detect a concentration of an analyte in the wash fluid. The system also includes a reference fluid reservoir including a reference fluid, the reference fluid including a predetermined concentration of the analyte in solution, a delivery system fluidly coupled to the fluid flow path and operable to supply the reference fluid to the fluid flow path upstream from the sensor while maintaining the sensor in place along the fluid flow path, and a control and monitoring system configured to receive a signal from the sensor, the signal indicating the concentration of the analyte in the reference fluid at a first time, and control calibrating the sensor and validating the sensor over time based on the received signal.

The invention relates to a comparison unit (130) configured for determining if a first pH measuring device of a first tank (104; 106) is affected by a pH-measuring problem, the comparison unit being configured for: receiving a first CO2 concentration and a first pH value, the first CO2 concentration being a CO2 concentration of a first gas volume above a medium in a first tank, the first CO2 concentration and the first pH value being measured at a first time when the medium in the first tank is in pH-CO2 equilibrium state with the first gas volume and before said equilibrium state is modified by the metabolism of a cell culture in the first tank, the first pH value being a measured value provided by a first pH measuring device operatively coupled to the first tank (102); receiving a second CO2 concentration and a second pH value, the second CO2 concentration being a CO2 concentration of a second gas volume above a medium in a second tank, the second CO2 concentration and the second pH value being measured at a second time when the medium in the second tank is in pH-CO2 equilibrium state with the second gas volume and before said equilibrium state is modified by the metabolism of a cell culture, the second pH value being a measured value provided by a second pH measuring device; comparing the first and second pH values and CO2 concentrations for determining if comparing (206), by the comparison unit, the first and second pH values and comparing the first and second CO2 concentrations for determining if the first pH measuring device is affected by the pH-measuring problem.

A smart sensor system is provided which uses a monitoring electrode to produce a calibration output that can be used in-situ and in real-time to monitor and address reference electrode drift and to provide information regarding sensor operation. The monitoring electrode uses a redox chemistry that is either a non-active redox species that is not sensitive to changes in a solution being tested/monitored or a redox active species that sets a pH of the local environment proximal to the electrode when the electrode is contacted with a test and/or reference solution. The smart sensor system includes at least one of a solid-state electrochemical sensor; a glass electrode, a reduction oxidation sensor; and/or a glucose sensor and/or a sensor to monitor constituent parts of the solution composition.