An electrochemical metal alloy identification device employing electrolytes to measure and identify different potentials of alloys is presented. This includes physical structure, disposables, electrical systems, control circuitry, and algorithms to identify alloys.

An electrochemical sensor device to measure the level of the interface between the pulp and froth in a flotation process is disclosed, as is a related system and method. The device may be used relative to flotation of minerals, and comprises a sensor rod and a housing, wherein the sensor rod is the element inserted into the interior of a flotation cell and/or column, formed by a central carrier, made of electrically insulating material, onto which conducting electrodes are fixed, in the form of rings, arranged alternately with insulating rings, wherein said electrodes are connected to an electrical conductor that extracts the signals from each electrode. Each conducting ring represents a measurement level.

An electrolytic copper plating solution analyzer comprises an analysis container for accommodating a part of an electrolytic copper plating solution containing additives including a promoter, an inhibitor and a leveler, a working electrode immersed in the electrolytic copper plating solution accommodated in the analysis container, a reference electrode immersed in the electrolytic copper plating solution and used as a reference when a potential of the working electrode is determined, a counter electrode immersed in the electrolytic copper plating solution, a rotation drive unit for rotating the working electrode at a given speed, a current generation unit passing an electric current with a given current density between the working electrode and the counter electrode, a potential measurement unit for measuring the potential between the working electrode and the reference electrode, and an analysis unit for analyzing the relationship between an elapsed time after the current passage and the potential.

Method and system for detection and quantification of oxidizable organics in water. The method involves the partial electrolytic decomposition of the oxidizable organics in a short time frame, preferably less than five seconds, and does not involve the use of toxic reagents. The system includes an electrochemical sensor probe that, in turn, includes a boron-doped diamond microelectrode array. The system additionally includes an electronic transducer and a computing device. The system utilizes an analysis technique to convert sensor signal to a result that can be correlated with COD or BOD values obtained by standard methods. The method and system are particularly suitable for, but not limited to, use in monitoring of water quality at wastewater treatment plants. By employing the method before and after adding aerobic microorganisms to the sample, the method may be used to distinguish biologically oxidizable organics from total oxidizable organics.

A method for determination of an unknown analyte using quantitative electrochemical generation of a detectable species, which provides specified quantities of the species, is described. As an example, free chlorine concentration measurements may be performed using N,N-Diethyl-p-phenylenediamine (DPD), or N,N-bis(2,4-di-sulfobenzyl)toluidinetetrasodium salt (SBT), for obtaining an in-situ calibration curve, whereby matrix effects are eliminated.

An embodiment provides a method for stirring a sample in a cell, including: providing a cell comprising a sample chamber; placing a boron-doped diamond electrode on an inner surface of the sample chamber, placing a removable stir bar in the sample chamber, the removable stir bar directly contacting and touching the boron-doped diamond electrode; and wherein the stir bar can be operated to rotate within the sample chamber upon the boron-doped diamond electrode. Other aspects are described and claimed.

A silanized ITO electrode modified with ITO nanoparticles is described. ITO nanoparticles of cubic and semispherical shapes are immobilized on a silanized ITO film. The electrode may be used in an electrolytic cell to detect aqueous sulfide with a 0.5-1.4 M limit of detection. The electrode shows high specificity towards aqueous sulfide and a high reproducibility in measurement.

A method, a system and a computer program product for changing an electrical state of charge of an electrical energy storage: a) stipulating at least one target value for a target state of charge of the electrical storage device, b) determining at least one actual value of an actual state of charge of the electrical storage device, c) extrapolating the actual value of the actual state of charge of the energy storage device to an extrapolation value of an extrapolation state of charge of the energy storage device, taking into account at least one charging parameter of the charging process, and d) comparing the target value of the target state of charge with the extrapolation value of the extrapolation state of charge and starting or interrupting the charging process if the extrapolation value deviates from the target value by more than 2%.

A silanized ITO electrode modified with ITO nanoparticles is described. ITO nanoparticles of cubic and semispherical shapes are immobilized on a silanized ITO film. The electrode may be used in an electrolytic cell to detect aqueous sulfide with a 0.5-1.4 M limit of detection. The electrode shows high specificity towards aqueous sulfide and a high reproducibility in measurement.

A method is provided for measuring an electrolytically-active species concentration in an aqueous or non-aqueous solution for use in providing control of the concentration of the species in a source solution thereof based on the measurements. In the method, a sample containing an electrolytically-active species is added into a measurement cell that has a working electrode and an auxiliary electrode, and a constant current is applied to the measurement cell while the working and auxiliary electrodes are in contact with the sample with monitoring of voltage difference across the electrodes until a change in the voltage difference is detected. A feedback signal is generated based on a parameter of the change in the voltage difference that is directly proportional to the amount of the electrolytically-active species in the sample, which can be used for process control. An apparatus is also described.