Patent classifications
G03G5/0525
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, METHOD OF MANUFACTURING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°.
##STR00001##
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, METHOD OF MANUFACTURING THE PHOTORECEPTOR, AND ELECTROPHOTOGRAPHIC DEVICE
An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer formed on the conductive substrate. The photosensitive layer contains a cross-linked structure derived from a first hole transport material represented by the following general formula (1):
##STR00001##
Za is a polymerizable functional group with structural formula (2), (3), or (4), Zb is a divalent group with structural formula (5), (6), or (7), Ra, Rb, Rc and Rd each are one of a branched or unbranched alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted styryl group, l is an integer of 0 or 1, m is an integer from 0 to 5, n, o, and p are each integer from 0 to 4, q is an integer from 1 to 3.
##STR00002##
SHAPED CHARGE GENERATION LAYER FOR PHOTOCONDUCTIVE DRUM
Shaping a photoconductive drum includes preparing a dispersion having a charge generation composition and dipping an elongated support element into the dispersion. Withdrawing from the dispersion portions of the support element at different speeds results in different thicknesses of charge generation composition on the support element. Faster withdrawal results in thicker charge generation composition than does slower withdrawal. Portions with thicker composition provide denser optical densities compared to thinner composition allowing tailoring the photoconductive drum to compensate for imperfect optical scanning systems. Coating the support element with a charge transport layer occurs next, then curing. Oxidation of the support element may occur prior to application of the charge generation composition. A protective overcoat may also exist over the charge transport layer.
SHAPED CHARGE GENERATION LAYER FOR A PHOTOCONDUCTIVE DRUM
A photoconductive drum includes an elongated support element with a shaped charge generation layer. The layer extends from the support element at various thicknesses along a length thereof. Thicker charge generation portions provides denser optical densities compared to thinner portions allowing tailoring the photoconductive drum to compensate for imperfect optical scanning systems. A charge transport layer overcoats the charge generation layer. Optionally, an oxidation layer underlies the charge generation layer as does a protective overcoat overlying the charge transport layer. Various thicknesses and shapes of the charge generation layer are also disclosed.
Method for manufacturing electrophotographic photoconductor
A method for manufacturing an electrophotographic photoconductor including a charge generating layer and a charge transport layer in this order on a cylindrical electrically-conductive support including the steps of: (i) immersing the support in a charge generating layer coating liquid, (ii) pulling the support out of the coating liquid, (iii) heat drying the support coated with the coating liquid to form the charge generating layer, (iv) cooling the charge generating layer, and (v) immersing the support on which the charge generating layer has been formed in a charge transport layer coating liquid while retaining gas inside of the support. The charge transport layer coating liquid contains a solvent having a boiling point of 34° C. or more and 85° C. or less, and the step (v) satisfies two specific conditions.
CONSUMABLE COMPONENT IDENTIFIERS
An example consumable print device component may comprise a surface and a human-indiscernible hardware-based identifier arranged on the surface.
Photosensitive body for electrophotography, method for producing same and electrophotographic apparatus
An electrophotographic photoreceptor includes a conductive substrate; and a photosensitive layer arranged on the conductive substrate and containing, as a charge generating material, any one material selected from the group consisting of titanyl phthalocyanines, metal-free phthalocyanines, chlorogallium phthalocyanines and hydroxygallium phthalocyanines; and, as an electron transporting material, a naphthalene tetracarboxylic acid diimide compound represented by Formula (1) below, where R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkylene group, an alkoxy group, an alkyl ester group, a phenyl group optionally having a substituent, a naphthyl group optionally having a substituent, or a halogen element; and R.sup.1 and R.sup.2 are optionally the same or different: ##STR00001##
The photoreceptor realizes a stable print density even in a low-temperature environment by suppressing a reduction in print density that is caused by potential fluctuation of the photoreceptor in the low-temperature environment.
Tubular metal body and electrophotographic photoreceptor
A tubular metal body includes a tubular part having an opening at one end in an axis direction; and a bottom part disposed at another end of the tubular part in the axis direction. The ratio (Rz1/Rz2) of a surface roughness Rz1 of an outer peripheral surface of the bottom part to a surface roughness Rz2 of an outer peripheral surface of a center portion of the tubular part in the axis direction is in a range of 2 or more and 4000 or less. A Vickers hardness HV1 of the outer peripheral surface of the bottom part is 5 HV or more and 27 HV or less smaller than a Vickers hardness HV2 of the outer peripheral surface of the center portion of the tubular part in the axis direction.
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, METHOD OF MANUFACTURING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE INCLUDING THE SAME
An electrophotographic photoconductor includes a conductive substrate; and a photosensitive layer provided on the conductive substrate and containing a charge generation material, a hole transport material, a first electron transport material, from 3% by mass to 40% by mass of a second electron transport material, a resin binder, and an inorganic oxide filler surface-treated with a silane coupling agent. In a dipole-dipole force component (a Hansen solubility parameter), the first electron transport material and the silane coupling agent have a difference of SPa<2.50; the second electron transport material and the silane coupling agent have a difference of SPb<2.50; and the first electron transport material and the second electron transport material have a difference of 0.30<SPc<1.00. In a London dispersion force component (a Hansen solubility parameter), the resin binder and the silane coupling agent have a difference of SPd<2.00.
Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus
Provided is a cylindrical electrophotographic photosensitive member, including a concave/convex portion forming region in which at least one of concave portions and convex portions are formed on a surface of the electrophotographic photosensitive member from a central portion to both end portions in an axial direction of the electrophotographic photosensitive member, wherein a maximum value Lmax and a minimum value Lmin of a distance L from the central portion to one end portion of the concave/convex portion forming region in the axial direction of the surface of the electrophotographic photosensitive member satisfy a specific relation.