G03G9/08755

BINDER RESIN COMPOSITION FOR TONER
20220382179 · 2022-12-01 · ·

A resin binder composition for toners, containing a polyester resin A which is a polycondensate A of raw materials A containing an alkylene oxide adduct of bisphenol A, an aromatic dicarboxylic acid compound, a trivalent or higher polyvalent raw material monomer which is at least any one members of a trihydric or higher polyhydric alcohol and a tricarboxylic or higher polycarboxylic acid compound, and an amorphous acid modified product A of an α-olefin polymer having 4 or more carbon atoms and 18 or less carbon atoms, the polyester resin A having a softening point of 120° C. or more and 150° C. or less; and a toner for electrostatic image development, containing these resin binder composition for toners. The resin binder composition for toners of the present invention is suitably used for a toner for electrostatic image development which is usable in development of latent images formed in, for example, electrostatic image development method, electrostatic recording method, electrostatic printing method or the like.

ELECTROSTATIC IMAGE DEVELOPING TONER, ELECTROSTATIC IMAGE DEVELOPER, AND TONER CARTRIDGE

An electrostatic image developing toner includes a toner particle including an amorphous resin, a crystalline resin, and a release agent. When a cross section of the toner particle is observed, the toner particle satisfies conditions (A1) and (B1) below: Condition (A1): one or more domains of the crystalline resin, the domains having a diameter equal to 10% or more and 40% or less of the maximum diameter of the toner particle, are present in the toner particle, and Condition (B1): one or more domains of the release agent, the domains having a diameter equal to 10% or more and 40% or less of the maximum diameter of the toner particle, are present in the toner particle.

ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER AND ELECTROSTATIC CHARGE IMAGE DEVELOPER

An electrostatic charge image developing toner includes a toner particle that contains a binder resin having an acid value of 5 mgKOH/g or more and 25 mgKOH/g or less, and a pigment having an isoindoline skeleton, in which a total Net intensity N.sub.A of an alkali metal and an alkaline earth metal, which is measured by fluorescent X-ray analysis, in the toner particle is 1.50 kcps or more and 4.00 kcps or less.

RESIN FINE PARTICLE, THERMOPLASTIC RESIN PARTICLE, AND METHOD FOR PRODUCING RESIN FINE PARTICLE

A method for producing a resin fine particle includes dissolving or melting an oily mixture containing at least a polyester resin, a base, and a basic dye while applying a shearing force to the oily mixture, and emulsifying the dissolved or molten oily mixture by adding a surfactant and an aqueous medium while applying a shearing force to the dissolved or molten oily mixture to prepare a dispersion liquid of the resin fine particle. The resin fine particle includes the polyester resin and the basic dye, has a volume average particle diameter of 0.05 μm or more and 1 μm or less, and has a ratio of a concentration of the basic dye in a center of gravity portion of the resin fine particle to a concentration of the basic dye in a surface layer portion having a depth of 10 nm or less from a surface of the resin fine particle of 0.8 or more.

BINDER RESIN COMPOSITIONS FOR TONER

A resin binder composition for toners, containing a polyester resin A having a constituting unit derived from an alcohol component containing an alkylene oxide adduct of bisphenol A and a constituting unit derived from a carboxylic acid component containing an amorphous acid modified product A of an α-olefin polymer having 4 or more carbon atoms and 18 or less carbon atoms; a resin binder composition for toners containing a polyester resin A which is a polycondensate of an alcohol component containing an alkylene oxide adduct of bisphenol A and a carboxylic acid component containing an amorphous acid modified product A of an α-olefin polymer having 4 or more carbon atoms and 18 or less carbon atoms; and a toner for electrostatic image development, containing these resin binder composition for toners. The resin binder composition for toners of the present invention is suitably used for a toner for electrostatic image development which is usable in development of latent images formed in, for example, electrostatic image development method, electrostatic recording method, electrostatic printing method or the like.

ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER, ELECTROSTATIC CHARGE IMAGE DEVELOPER, TONER CARTRIDGE, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS

An electrostatic charge image developing toner includes: a toner particle containing a binder resin; and an external additive containing alumina particles having a volume average particle diameter of more than 5 nm and 80 nm or less and silica particles having a volume average particle diameter of 10 nm or more and 90 nm or less, and in the toner particle, a Net intensity N.sub.A of a total of an alkali metal element and an alkaline earth metal element, measured by fluorescence X-ray analysis, is 0.10 kcps or more and 1.30 kcps or less, and a ratio (Ws/Wa) of a content Ws of the silica particles to a content Wa of the alumina particles is more than 0.5 and less than 35.

ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER, ELECTROSTATIC CHARGE IMAGE DEVELOPER, METHOD FOR PRODUCING ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER, TONER CARTRIDGE, PROCESS CARTRIDGE, IMAGE FORMING APPARATUS, AND IMAGE FORMING METHOD

An electrostatic charge image developing toner includes a toner particle containing a binder resin and a releasing agent, and the following requirement (1) is satisfied in cross section observation of the toner particle: requirement (1): the number of a releasing agent domain having a long diameter of 500 nm or more and 1,000 nm or less is 7 or more on average per toner particle.

ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER, ELECTROSTATIC CHARGE IMAGE DEVELOPER, TONER CARTRIDGE, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS

An electrostatic charge image developing toner includes: a toner particle containing a binder resin; and an external additive including a silica particle having a circularity of more than 0.5 and. 0.9 or less and a volume average particle diameter of more than 100 nm and 300 nm or less, in which a total Net intensity N.sub.A of an alkali metal element and an alkaline earth metal element in the toner particle measured by fluorescence X-ray analysis is 0.10 kcps or more and 1.20 kcps or less.

TONER

A toner is provided that comprises a toner particle comprising a binder resin and a wax, and an inorganic fine particle on a surface of the toner particle, wherein the binder resin comprises a resin A; the toner satisfies 2.50≤SPa−SPw≤4.50, where SPa (cal/cm.sup.3).sup.0.5 is the SP value of the resin A, and SPw (cal/cm.sup.3).sup.0.5 is the SP value of the wax; the inorganic fine particle comprises a silica fine particle whose surface has been treated with a silicone oil; in a .sup.29Si solid-state NMR measurement of the silica fine particle, 30≤B≤60 and 4.0≤A/B≤6.0 are satisfied, taking A as an integration value of a D unit obtained by taking an integration value of a Q unit in a CP/MAS measurement as 100, and taking B as an integration value of a D unit obtained by taking an integration value of a Q unit in a DD/MAS measurement as 100.

TONER
20220373906 · 2022-11-24 ·

A toner comprising: a toner particle comprising a binder resin and a hydrocarbon wax; and inorganic fine particles, wherein the inorganic fine particles include silica fine particles surface-treated with specific polydimethylsiloxanes, a total amount of trimethylsilanol in the silica fine particles is from 1.0 ppm to 5.0 ppm, where a standard value of an amount of ions of an ester group is measured by time-of-flight secondary ion mass spectrometry, one or more peaks of the standard value are present within a range of 100 nm from the surface of the toner particle, and the maximum value A(d max) among the peaks of the standard value and the standard value A(0) on the surface of the toner particle satisfy the following relationships:


1.05≤A(d max)/A(0)≤5.00,


A(0)≥0.010.