Patent classifications
G03G9/08708
TONER FOR DEVELOPING ELECTROSTATIC IMAGES
Provided are a toner for developing electrostatic images excellent in low-temperature fusing property, gloss and carrier contamination resistance, and a wax dispersant. [1] A toner for developing electrostatic images, containing an amorphous composite resin (A), an amorphous polyester resin (B), and a wax, wherein the amorphous composite resin (A) contains a polyester resin segment which is a polycondensate of an alcohol component containing an aromatic diol and a carboxylic acid component containing an aliphatic dicarboxylic acid whose main chain has 8 or more and 14 or less carbon atoms, a vinylic resin segment of an addition polymer of a raw material monomer containing a styrenic compound, and a constitutional unit derived from a bireactive monomer, the constitutional unit bonding to the polyester resin segment and the vinylic resin segment each via a covalent bond; and has a glass transition temperature not lower than 45 C., and the ratio by mass of the amorphous composite resin (A) to the amorphous polyester resin (B) [(A)/(B)] is 1/99 or more and 60/40 or less; and [2] a wax dispersant containing the amorphous composite resin (A).
TONER AND IMAGE FORMING METHOD
A toner comprises a toner particle including a binder resin, and inorganic fine particles A and silica particles B, wherein the inorganic fine particle A has a rectangular parallelepiped shape; an amount of the inorganic fine particles A is 0.3 to 3.0 mass parts per 100 mass parts of the toner particles; a number average particle diameter of the silica particles B is 80 to 200 nm; a fixing ratio of the inorganic fine particle A is 25% to 70%; where a separation amount of the inorganic fine particles A is denoted by YA (mg), and a separation amount of the silica particles is denoted by YB (mg), YA is 3.00 to 18.0, YA and YB satisfy the following formula,
YA/YB>0.75, and a surface potential difference C in a rubbing test using the inorganic fine particle A and the binder resin is 70 V to +70 V.
TONER COMPOSITIONS
The present disclosure provides toners and toner processes. In embodiments, a toner is provided which comprises a first resin having a weight average molecular weight of no more than about 28,000 and an onset second heat T.sub.g of no more than about 50 C.; a second resin having a weight average molecular weight greater than that of the first resin; and a paraffin wax having a melting point in the range of from about 65 C. to about 95 C.
TONER AND METHOD FOR PRODUCING TONER
A toner has a toner particle including a binder resin, the binder resin includes a polymer A, the polymer A contains a first monomer unit derived from a first polymerizable monomer and a second monomer unit derived from a second polymerizable monomer, the first polymerizable monomer is selected from (meth)acrylic acid esters having an alkyl group having 18 to 36 carbon atoms, the content of the first monomer unit in the polymer A is 5.0 mol % to 60.0 mol %, the content of the second monomer unit in the polymer A is 20.0 mol % to 95.0 mol %, the SP value of the first monomer unit and the SP value of the second monomer unit satisfy a predetermined relationship, the polymer A includes a predetermined polyvalent metal, and the content of the polyvalent metal is 25 ppm to 500 ppm.
TONER AND METHOD FOR PRODUCING TONER
Provided is a toner has a toner particle containing a binder resin and is characterized in that the binder resin contains a polymer A, which is a polymer of a composition containing a first polymerizable monomer, a second polymerizable monomer and a crosslinking agent, the first polymerizable monomer is at least one monomer selected from the group consisting of (meth)acrylic acid esters having an alkyl group with 18 to 36 carbon atoms, the crosslinking agent has two or more polymerizable double bonds, a content of the first polymerizable monomer in the composition is 5.0 to 60.0 mol %, a content of the second polymerizable monomer is 20.0 to 95.0 mol %, and when the SP values of the first polymerizable monomer, the second polymerizable monomer and the crosslinking agent are denoted by SP.sub.12, SP.sub.22 and SP.sub.C2, respectively, the formulae 0.60(SP.sub.22SP.sub.12)15.00 and SP.sub.12<SP.sub.C2<(SP.sub.22+3.00) are satisfied.
POSITIVE-CHARGING TONER
Provided is a positive-charging toner having a toner particle that contains a binder resin, the binder resin contains a polymer A having a first monomer unit derived from a first polymerizable monomer, and a second monomer unit derived from a second polymerizable monomer, the first polymerizable monomer is at least one selected from the group consisting of (meth)acrylic acid esters having a C18 to C36 alkyl group, the content of the first monomer unit in the polymer A is 5.0 to 60.0 mol % and the content of the second monomer unit is 20.0 to 95.0 mol %, SP.sub.11 of the first monomer unit and SP.sub.21 of the second monomer unit satisfy 3.00(SP.sub.21SP.sub.11)25.00, and the work function of the toner is 5.0 to 5.4 V.
TONER AND TONER MANUFACTURING METHOD
A toner comprising a toner particle containing a binder resin, the storage elastic modulus Gt (150) of the toner at 150 C. is at least 1.010.sup.4 Pa, the binder resin contains a polymer A having a first monomer unit derived from a first polymerizable monomer and a second monomer unit derived from a second polymerizable monomer different from the first polymerizable monomer, the first polymerizable monomer is selected from specific (meth)acrylic acid esters, the contents of the first monomer unit and second monomer unit in the polymer A are within specific ranges, and the SP values of the first monomer unit and second monomer unit are within specific ranges.
TWO-COMPONENT DEVELOPER
Provided is a two-component developer has a toner including a toner particle including a binder resin, and a magnetic carrier, wherein the binder resin includes a polymer A having a first monomer unit derived from a first polymerizable monomer, and a second monomer unit derived from a second polymerizable monomer different from the first polymerizable monomer, the first polymerizable monomer is a specific (meth)acrylic acid ester, a content and an SP value of the first and second monomer units in the polymer A fall within respective specific ranges, the magnetic carrier has a magnetic core and a coating resin of the surface of the magnetic core, the coating resin includes a polymer B having monomer units (a) and (b), each SP value of the monomer units (a) and (b) is a specific value.
TONER AND METHOD FOR PRODUCING TONER
A toner comprising a toner particle comprising a resin A and a resin B; wherein: the resin A is a vinyl resin having a sulfonic acid-type group, the resin B is a polyester resin; and when in analysis of the toner particle using time-of-flight secondary ion mass spectrometry, DA (nm) is defined as a depth at which an abundance of the resin A in a depth of 10 nm from a toner particle surface is a maximum, CA.sub.S (%) is defined as an abundance of the resin A at the depth DA, CB.sub.S (%) is defined as an abundance of the resin B at the depth DA, CA.sub.75 (%) is defined as an abundance of the resin A at a depth of 75 nm and CB.sub.75 (%) is defined as an abundance of the resin B at a depth of 75 nm, CA.sub.S, CA.sub.75, CB.sub.S and CB.sub.75 satisfy specific relationships.
Toner, image forming apparatus, and image forming method
A toner includes a plurality of toner particles and a plurality of lubricant particles. The lubricant particles each include a core and a coat layer covering a surface of the core. The core contains stearic acid, palmitic acid, or a combination thereof. The coat layer has a thickness of at least 10 nm and no greater than 50 nm.