In an aspect, provided is an alkaline rechargeable battery comprising: i) a battery container sealed against the release of gas up to at least a threshold gas pressure, ii) a volume of an aqueous alkaline electrolyte at least partially filling the container to an electrolyte level; iii) a positive electrode containing positive active material and at least partially submerged in the electrolyte; iv) an iron negative electrode at least partially submerged in the electrolyte, the iron negative electrode comprising iron active material; v) a separator at least partially submerged in the electrolyte provided between the positive electrode and the negative electrode; vi) an auxiliary oxygen gas recombination electrode electrically connected to the iron negative electrode by a first electronic component, ionically connected to the electrolyte by a first ionic pathway, and exposed to a gas headspace above the electrolyte level by a first gas pathway.

Alkaline electrochemical cells are provided, containing cathodes with a nickel compound active material, wherein active material particles are coated with at least one of a number of materials so as to improve the shelf life of the electrochemical cell. Methods of preparing such cathodes and electrochemical cells are also provided.

A method of operating a battery comprises discharging a cathode comprising manganese dioxide to within a 2.sup.nd electron capacity of the manganese dioxide at a C-rate of equal to or slower than C/10, recharging the battery, and cycling the battery during use a plurality of times. The cathode is in a battery, and the battery comprises the cathode, an anode, a separator disposed between the anode and the cathode, and an electrolyte. The cathode comprises the manganese dioxide and a conductive carbon. The anode comprises: a metal component and a conductive carbon. The metal component can be a metal, metal oxide, or metal hydroxide, and the metal of the metal component can be zinc, lithium, aluminum, magnesium, iron, cadmium and a combination thereof.

A battery, having polyvalent aluminum metal as the electrochemically active anode material and also including a solid ionically conducting polymer material.

A battery, having polyvalent aluminum metal as the electrochemically active anode material and also including a solid ionically conducting polymer material.

Provided is a high quality and high performance nickel-iron battery comprising an iron electrode which is prepared by a continuous process. The process comprises preparing a formulation comprising an iron active material and a binder, and continuously coating a continuous substrate material on at least one side with the formulation. The coated continuous substrate material is dried, compacted and blanked. In one embodiment, the iron electrode comprises a PVA binder.

Provided is a high quality and high performance nickel-iron battery comprising an iron electrode which is prepared by a continuous process. The process comprises preparing a formulation comprising an iron active material and a binder, and continuously coating a continuous substrate material on at least one side with the formulation. The coated continuous substrate material is dried, compacted and blanked. In one embodiment, the iron electrode comprises a PVA binder.

A main object of the present disclosure is to provide an anode active material with excellent capacity properties. The present disclosure achieves the object by providing an anode active material to be used in an alkaline storage battery, the anode active material including: a base material containing Ti and Cr, and including a BCC structure as a metastable phase; and a coating layer that coats the base material, and contains a catalyst metal and a metal with oxygen affinity that is more than oxygen affinity of Ti; wherein an oxide film is present in an interface between the coating layer and the base material; and when a first thickness T.sub.A (nm) and a second thickness T.sub.B(nm) of the oxide film are determined by Auger electron spectroscopy, a rate of the T.sub.A with respect to the T.sub.B, which is T.sub.A/T.sub.B is, for example, 1.50 or more.

A main object of the present disclosure is to provide an anode active material with excellent capacity properties. The present disclosure achieves the object by providing an anode active material to be used in an alkaline storage battery, the anode active material including: a base material containing Ti and Cr, and including a BCC structure as a metastable phase; and a coating layer that coats the base material, and contains a catalyst metal and a metal with oxygen affinity that is more than oxygen affinity of Ti; wherein an oxide film is present in an interface between the coating layer and the base material; and when a first thickness T.sub.A (nm) and a second thickness T.sub.B(nm) of the oxide film are determined by Auger electron spectroscopy, a rate of the T.sub.A with respect to the T.sub.B, which is T.sub.A/T.sub.B is, for example, 1.50 or more.

Provided is a Ni—Fe battery comprising a high quality, high performance iron electrode. In one embodiment the iron electrode comprises a polyvinyl alcohol binder. The iron electrode of the Ni—Fe battery comprises a single conductive substrate coated on one or both sides with an iron active material.