A lithium transition metal oxide electrode including an additional metal is provided herein as well electrochemical cells including the lithium transition metal oxide electrode and methods of making the lithium transition metal oxide electrode. The lithium transition metal oxide electrode includes a first electroactive material including Li.sub.1+aNi.sub.bMn.sub.cM.sub.dO.sub.2, where 0.05≤a≤0.6; 0.01≤b≤0.5; 0.1≤c≤0.9; zero (0)≤d≤0.3; b+c+d=1 or a+b+c+d=1; and M represents an additional metal, such as W, Mo, V, Zr, Nb, Ta, Fe, Al, Mg, Si, or a combination thereof.

The present application provides an organic-inorganic hybrid complex which can be used in a coating of a separator for a secondary battery, wherein the organic-inorganic hybrid complex is formed from basic units represented by formula (I) being periodically assembled in at least one spatial direction: [L.sub.x-i□i][M.sub.aC.sub.b].A.sub.z (I), wherein a defect percentage expressed in i/x*100% is 1% to 30%. The present application further provides a coating composition comprising the organic-inorganic hybrid complex, a coating formed from the coating composition, a separator comprising the coating for a secondary battery, a secondary battery comprising the separator, a battery module, a battery pack and a device. By applying the organic-inorganic hybrid complex of the present application in a coating, the electrolyte infiltration of a separator for a secondary battery is improved while increasing the electrolyte retention rate, thereby improving the rate capability and cycling life of the secondary battery.

The present disclosure belongs to the technical field of lithium battery cathode materials, and discloses a preparation method of multiple carbon-coated high-compaction lithium iron manganese phosphate, comprising the following steps: (1) synthesizing a carbon and vanadium co-doped ferromanganese phosphate precursor through a co-precipitation method, sintering, and removing crystal water to obtain an anhydrous ferromanganese phosphate precursor; (2) adding lithium phosphate, a supplemental phosphorus source, an organic carbon source, a dopant and deionized water, and performing ball milling, wet sanding, spray drying and sintering to obtain an intermediate material; and (3) adding deionized water and the organic carbon source, then performing ball milling, sanding, spray drying, sintering and air jet pulverization to obtain multiple carbon-coated high-compaction lithium iron manganese phosphate.

This application provides embodiments including a connection member and a rechargeable battery. The connection member includes a guide plate and a first connecting plate integrally formed on the guide plate, where the first connecting plate is disposed in a bendable manner relative to the guide plate, and at least one indentation is present between the first connecting plate and the guide plate. In the embodiments, a bending position is more accurate when the first connecting plate is bent relative to the guide plate. This is conducive to an accurate size of the connection member being bent, and is also helpful for the rechargeable battery to successfully assemble a battery core, the connection member, and a housing.

The energy storage system includes battery cells, a subrack, a backplane, and a battery management system BMS. The subrack reserves a plurality of battery cell slots, the battery cells are connected to the backplane through the battery cell slots. The backplane is installed in the subrack, a first power terminal is reserved at a position corresponding to the battery cell slot on the backplane, and a plug-in power terminal is formed by a second power terminal of the battery cell together with the first power terminal. A power circuit, a sampling circuit, and an equalizer circuit are integrated into the backplane, and the power circuit, the sampling circuit, and the equalizer circuit are connected after the second power terminal is plugged and docked with the first power terminal. The BMS is connected to the backplane for managing the energy storage system.

Articles and methods including layers for protection of electrodes in electrochemical cells are provided. As described herein, a layer, such as a protective layer for an electrode, may comprise a plurality of particles (e.g., crystalline inorganic particles, amorphous inorganic particles). In some aspects, at least a portion of the plurality of particles (e.g., inorganic particles) are fused to one another. For instance, in some aspects, the layer may be formed by aerosol deposition or another suitable process that involves subjecting the particles to a relatively high velocity such that fusion of particles occurs during deposition. In some cases, the protective layer may be porous.

Articles and methods including layers for protection of electrodes in electrochemical cells are provided. As described herein, a layer, such as a protective layer for an electrode, may comprise a plurality of particles (e.g., crystalline inorganic particles, amorphous inorganic particles). In some aspects, at least a portion of the plurality of particles (e.g., inorganic particles) are fused to one another. For instance, in some aspects, the layer may be formed by aerosol deposition or another suitable process that involves subjecting the particles to a relatively high velocity such that fusion of particles occurs during deposition. In some cases, the protective layer may be porous.

The present disclosure relates to a lithium-sulfur battery cathode. The lithium-sulfur battery cathode comprises a carbon nanotube sponge and a plurality of sulfur nanoparticles. Wherein the carbon nanotube sponge comprises a plurality of micropores. The plurality of sulfur nanoparticles are uniformly distributed in the plurality of micropores. The present disclosure also relates a method for making the lithium-sulfur battery cathode and a lithium-sulfur battery using the lithium-sulfur battery cathode.

The present disclosure relates to a lithium-sulfur battery cathode. The lithium-sulfur battery cathode comprises a carbon nanotube sponge and a plurality of sulfur nanoparticles. Wherein the carbon nanotube sponge comprises a plurality of micropores. The plurality of sulfur nanoparticles are uniformly distributed in the plurality of micropores. The present disclosure also relates a method for making the lithium-sulfur battery cathode and a lithium-sulfur battery using the lithium-sulfur battery cathode.

A lithium secondary battery includes a cathode formed of a cathode active material including a lithium metal oxide particle having a concentration gradient, and a coating formed on the lithium metal oxide particle, the coating including aluminum, titanium and zirconium, an anode, and a separator interposed between the cathode and the anode. The cathode active material includes 2,000 ppm to 4,000 ppm of aluminum, 4,000 ppm to 9,000 ppm of titanium and 400 ppm to 700 ppm of zirconium, based on the total weight of the cathode active material. The performance of the secondary battery may be maintained under a high temperature condition.