A solid electrolyte represented by general formula Li.sub.ySiR.sub.x(MO.sub.4), where x is an integer from 1 to 3 inclusive, y=4−x, each R present is independently C1-C3 alkyl or C1-C3 alkoxy, and M is sulfur, selenium, or tellurium. Methods of making the solid electrolyte include combining a phenylsilane and a first acid to yield mixture including benzene and a second acid, and combining at least one of an alkali halide, and alkali amide, and an alkali alkoxide with the second acid to yield a product d represented by general formula Li.sub.ySiR.sub.x(MO.sub.4).sub.y. The second acid may be in the form of a liquid or a solid. The phenylsilane includes at least one C1-C3 alkyl substituent or at least one C1-C3 alkoxy substituent, and the first acid includes at least one of sulfuric acid, selenic acid, and telluric acid.

A solid electrolyte represented by general formula Li.sub.ySiR.sub.x(MO.sub.4), where x is an integer from 1 to 3 inclusive, y=4−x, each R present is independently C1-C3 alkyl or C1-C3 alkoxy, and M is sulfur, selenium, or tellurium. Methods of making the solid electrolyte include combining a phenylsilane and a first acid to yield mixture including benzene and a second acid, and combining at least one of an alkali halide, and alkali amide, and an alkali alkoxide with the second acid to yield a product d represented by general formula Li.sub.ySiR.sub.x(MO.sub.4).sub.y. The second acid may be in the form of a liquid or a solid. The phenylsilane includes at least one C1-C3 alkyl substituent or at least one C1-C3 alkoxy substituent, and the first acid includes at least one of sulfuric acid, selenic acid, and telluric acid.

A composite membrane with nanostructured inorganic and organic phases is applied as an ion-selective layer to prove processability, prevent dendrite shorting, and increase power output of lithium-metal anodes through better Li-ion conductivity. Nanoconfinement, as opposed to macroscale confinement, is known to dramatically alter the properties of bulk materials. Control over a ceramic's size, shape, and properties is achieved with polymer templates. This is a new composition of matter and unique approach to composite membrane design.

What is provided is a solid state battery and a solid state battery manufacturing method capable of more reliably preventing short-circuiting. A solid state battery includes: a first electrode piece in which a first electrode active material layer is formed on a first current collector layer; a second electrode piece in which a second electrode active material layer is formed on a second current collector layer; and a bag-shaped solid electrolyte layer which accommodates the first electrode piece, wherein the first electrode piece accommodated in the bag-shaped solid electrolyte layer and the second electrode piece are laminated so as to overlap each other in a plan view so that the first electrode active material layer and the second electrode active material layer are disposed so as to face each other with the solid electrolyte layer interposed therebetween.

What is provided is a solid state battery and a solid state battery manufacturing method capable of more reliably preventing short-circuiting. A solid state battery includes: a first electrode piece in which a first electrode active material layer is formed on a first current collector layer; a second electrode piece in which a second electrode active material layer is formed on a second current collector layer; and a bag-shaped solid electrolyte layer which accommodates the first electrode piece, wherein the first electrode piece accommodated in the bag-shaped solid electrolyte layer and the second electrode piece are laminated so as to overlap each other in a plan view so that the first electrode active material layer and the second electrode active material layer are disposed so as to face each other with the solid electrolyte layer interposed therebetween.

A sulfide-impregnated solid-state battery is provided. The battery comprises a cell core constructed by basic cell units. Each unit comprises a positive electrode comprising a cathode layer and a positive meshed current collector comprising a conductive material which is further coated by oxide-based solid-state electrolyte. The cell unit further comprises a negative electrode comprising an anode layer and a negative meshed current collector comprising a conductive material which is further coated by oxide-based solid-state electrolyte. The positive and negative electrodes are stacked together to form the cell unit. The two coated oxide-based solid electrolyte layers are disposed between the positive and negative electrode as dual separators. Such a cell unit may be repeated or connected in parallel or bipolar stacking to form the cell core to achieve a desired battery voltage, power and energy. The cell core comprises a sulfide-based solid-state electrolyte dispersed in the pore structures of cell core.

An electrochemical cell and a method of preparing the electrochemical cell are provided. The electrochemical cell, such as a lithium battery or a solid-state lithium ion battery, includes a first electrode having a solid polymer electrolyte deposited thereon, wherein the solid polymer electrolyte comprises a microporous polymer swollen with an organic carbonate liquid and a dissociable lithium salt, and a second electrode. The method of preparing an electrochemical cell includes providing the first electrode, immersing the first electrode in an electrolyte solution, depositing the solid polymer electrolyte on the immersed first electrode, and attaching the second electrode to an exposed surface of the solid polymer electrolyte, thereby forming the electrochemical cell. During operation, the solid polymer electrolyte is capable of growing a passivating polymer layer at an interface between the first electrode and the solid polymer electrolyte.

A composite electrolyte including a lithium salt; a solid electrolyte wherein the solid electrolyte is a sulfide solid electrolyte, an oxide solid electrolyte, or a combination thereof; and an ionic liquid, wherein a mixture of the ionic liquid and the lithium salt has a dielectric constant of from about 4 to about 12, and an amount of halogen ions eluted from the composite electrolyte after immersion of the solid electrolyte in the ionic liquid for 24 hours is less than about 25 parts per million by weight, based on the total weight of the composite electrolyte, as measured by ion chromatography.

A composite membrane includes: an organic layer including a plurality of through holes; and ion conductive inorganic particles disposed in the plurality of through holes, wherein the ion conductive inorganic particles each include at least one recess, at least one protrusion, or a combination thereof on a surface thereof, and wherein the surface of the ion conductive inorganic particles which comprises the at least one recess, the at least one protrusion, or the combination thereof faces a surface of the organic layer.

A composite membrane includes: an organic layer including a plurality of through holes; and ion conductive inorganic particles disposed in the plurality of through holes, wherein the ion conductive inorganic particles each include at least one recess, at least one protrusion, or a combination thereof on a surface thereof, and wherein the surface of the ion conductive inorganic particles which comprises the at least one recess, the at least one protrusion, or the combination thereof faces a surface of the organic layer.