This disclosure relates to improved electrolytes and electrode pastes that include ground state metal nanoparticles formed by laser ablation, improved rechargeable lithium-ion batteries made using the improved electrolytes and/or electrode pastes that include ground state metal nanoparticles formed by laser ablation, and methods for manufacturing rechargeable batteries of improved performance. The metal nanoparticles may comprise or consist of gold. The metal nanoparticles may by spherical-shaped and/or coral-shaped.

This disclosure relates to improved electrolytes and electrode pastes that include ground state metal nanoparticles formed by laser ablation, improved rechargeable lithium-ion batteries made using the improved electrolytes and/or electrode pastes that include ground state metal nanoparticles formed by laser ablation, and methods for manufacturing rechargeable batteries of improved performance. The metal nanoparticles may comprise or consist of gold. The metal nanoparticles may by spherical-shaped and/or coral-shaped.

Described is a lithium-sulfur electrochemical cell in which the anode and the cathode are each equipped with a respective solid-electrolyte interphase (SEI) layer that inhibits lithium side reactions. On the cathode side, the SEI layer inhibits the shuttle effect by retaining soluble polysulfides within a cathode active layer while releasing and admitting lithium ions to and from the electrolyte. The cathode SEI is deposited, during cell formation, by depositing a layer of an anode reductant (e.g., metallic lithium) on the surface of the cathode. The resultant electrically conductive layer allows electrons to reduce adjacent electrolyte and form the cathode SEI from electrolyte decomposition products.

Methods, systems, and compositions for the solution-phase deposition of thin films comprising one or more artificial solid-electrolyte interphase (SEI) layers. The thin films can be coated onto the surface of porous components of electrochemical devices, such as solid-state electrolytes employed in rechargeable batteries. The methods and systems provided herein involve exposing the component to be coated to different liquid reagents in sequential processing steps, with optional intervening rinsing and drying steps. Processing may occur in a single reaction chamber or multiple reaction chambers.

Methods, systems, and compositions for the solution-phase deposition of thin films comprising one or more artificial solid-electrolyte interphase (SEI) layers. The thin films can be coated onto the surface of porous components of electrochemical devices, such as solid-state electrolytes employed in rechargeable batteries. The methods and systems provided herein involve exposing the component to be coated to different liquid reagents in sequential processing steps, with optional intervening rinsing and drying steps. Processing may occur in a single reaction chamber or multiple reaction chambers.

A solid-state ion conductor includes a compound of Formula 1:
Li.sub.6+(5−a)x−b*y−z(c+2)wA.sub.1−x(M1).sup.a.sub.x(M2).sup.b.sub.yO.sub.5−z−wX.sub.1+zQ.sup.c.sub.w  Formula 1
wherein, in Formula 1, A is an element having an oxidation state of +5, M1 is an element having an oxidation state of a, wherein a is +2, +3, +4, +6, +7, or a combination thereof, M2 is an element having an oxidation state of b, wherein b is +1, +2, or a combination thereof, X is an element having an oxidation state of −1, Q is an element having an oxidation state of c, wherein c is less than −2, and wherein −2≤(5−a)x−b*y−z−(c+2)w≤2, 0≤x≤0.5, 0≤y≤0.5, −1≤z≤1, 0≤w≤0.5.

A solid-state ion conductor includes a compound of Formula 1:
Li.sub.6+(5−a)x−b*y−z(c+2)wA.sub.1−x(M1).sup.a.sub.x(M2).sup.b.sub.yO.sub.5−z−wX.sub.1+zQ.sup.c.sub.w  Formula 1
wherein, in Formula 1, A is an element having an oxidation state of +5, M1 is an element having an oxidation state of a, wherein a is +2, +3, +4, +6, +7, or a combination thereof, M2 is an element having an oxidation state of b, wherein b is +1, +2, or a combination thereof, X is an element having an oxidation state of −1, Q is an element having an oxidation state of c, wherein c is less than −2, and wherein −2≤(5−a)x−b*y−z−(c+2)w≤2, 0≤x≤0.5, 0≤y≤0.5, −1≤z≤1, 0≤w≤0.5.

A lithium-ion battery module includes a housing having a plurality of partitions configured to define a plurality of compartments within a housing. The battery module also includes a lithium-ion cell element provided in each of the compartments of the housing. The battery module further includes a cover coupled to the housing and configured to route electrolyte into each of the compartments. The cover is also configured to seal the compartments of the housing.

A lithium-ion battery module includes a housing having a plurality of partitions configured to define a plurality of compartments within a housing. The battery module also includes a lithium-ion cell element provided in each of the compartments of the housing. The battery module further includes a cover coupled to the housing and configured to route electrolyte into each of the compartments. The cover is also configured to seal the compartments of the housing.

A nonaqueous electrolyte secondary battery includes an electrode assembly including a positive electrode, a negative electrode, and a separator and a nonaqueous electrolyte. The separator includes a porous resin sheet having at least a three-layer structure consisting of an A-layer, a B-layer, and a C-layer stacked in that order. The average thermal expansion coefficient of each of the A-layer and the C-layer at a temperature of 0° C. to 50° C. is 100 ppm/K or more less than the average thermal expansion coefficient of the B-layer at a temperature of 0° C. to 50° C.