This present patent application discloses is a battery with improved bromide sequestration wherein the battery includes parts such as an anode, which comprised of an electrically conductive material; a cathode that comprised of an electrically conductive carbon-based material; an electrolyte and a liquid used for bromine sequestration. The bromine sequestration liquid is nonpolar, immiscible, or virtually immiscible in water or aqueous-based gel and has a density greater than that of water. The bromine sequestration agent is selected from tetrabromoethane, tetrachloroethylene, carbon tetrachloride, tetrachloroethane, trichloroethane, tribromoethane, or a combination thereof. However, tetrabromoethane or tetrachloroethylene are preferred.

An electrode plate, method for manufacturing an electrode plate, and method of testing an electrode plate enable efficient production of robust flowing electrolyte batteries. The method of testing an electrode plate includes forming a frangible portion in the electrode plate; providing a seal around a periphery of the electrode plate, wherein the periphery extends across the frangible portion; applying a gas adjacent a surface on a first side of the electrode plate; and detecting whether there is a presence of the gas adjacent a surface on a second side of the electrode plate, if the electrode plate passes testing, the frangible portion is removed from the electrode plate to define a cut-away region. The electrode plate is then positioned in a battery cell stack including a plurality of other electrode plates. A manifold is then attached to the cell stack adjacent the cut-away region of the electrode plate.

The present invention provides a bipolar electrode that is useful in zinc-halide electrochemical cells or battery stacks. The bipolar electrode comprises a titanium bipolar electrode plate wherein a cathode assembly is disposed on a front surface of the electrode plate. The cathode assembly comprises a titanium cathode cage, a separator, and carbon material, wherein the cathode cage holds the carbon material in electrical communication with the front surface of the electrode plate.

Provided is a layered double hydroxide (LDH) separator including a porous substrate made of a polymeric material, and LDH with which pores of the porous substrate are plugged. The LDH separator has a plurality of remaining flattened pores, longitudinal directions of the pores being non-parallel to a thickness direction of the LDH separator.

A battery module that is a static, open pool single cell battery which may have electrode elements of the same polarity spaced apart but electrically connected in parallel to one another and suspended from a common bus into a common electrolyte pool, in addition to a battery box that receives a plurality of electrode elements into the common electrolyte pool for the open pool battery. The electrode elements are alternating cathode elements and anode elements. A method for manufacture of the battery module is also described.

The present invention provides a terminal assembly, and storage batteries comprising a terminal assembly, wherein the terminal assembly comprises a conductive cup-shaped member comprising a terminal wall in electric communication with a terminal of the electrochemical cell when the terminal wall is in contact with the terminal; a sidewall; and a rim separated from the terminal wall by the sidewall; and a bipolar endplate having first and second surfaces coplanar with the terminal wall and joining to the rim at the first surface, the joining enabling bi-directional uniform current flow through the cup-shaped member between the terminal and the endplate when the terminal wall is in contact with the terminal, the endplate having an electrochemically active region comprising a first surface area enclosed by the rim and a remaining second surface area outside an outer periphery of the rim, the first and second surface areas being substantially equal.

An electrolyte system is provided for a rechargeable electrode zinc-halogen flow battery that utilizes a highly similar or identical electrolyte positioned on both sides of an ion-conducting membrane. The electrolyte system containing zinc salts, electrolyte conductivity enhancer, and an appropriate amount of bromine complexing agent achieves significant improvements on battery energy efficiency, self-discharge rate, and electrolyte level cycle stability over the prior art electrolyte systems.

The present invention provides an aqueous electrolyte for use in rechargeable zinc-halide storage batteries that possesses improved stability and durability and improves zinc-halide battery performance. One aspect of the present invention provides an electrolyte for use in a secondary zinc bromine electrochemical cell comprising from about 30 wt % to about 40 wt % of ZnBr.sub.2 by weight of the electrolyte; from about 5 wt % to about 15 wt % of KBr; from about 5 wt % to about 15 wt % of KCl; and one or more quaternary ammonium agents, wherein the electrolyte comprises from about 0.5 wt % to about 10 wt % of the one or more quaternary ammonium agents.

A separator for a flowing electrolyte battery, and a method of forming such a separator, enable improved efficiency in a flowing electrolyte battery. The separator includes a sheet having a first surface and a second surface opposing the first surface. A first spacer element is disposed on the first surface, and a second spacer element is disposed on the second surface. The first spacer element is wider than the second spacer element in a direction that is both parallel to the first and second surfaces and perpendicular to longitudinal axes of the first and second spacer elements.

An electrolyte solution and a flow cell battery are included herein. The electrolyte solution generally includes a electrolyte solution including one or more class A quat halides. The flow cell battery includes an electrolyte solution including one or more class A quat halides.