Disclosed is a novel compound represented by formula (1) below. In the formula, A represents an optionally substituted aromatic hydrocarbon ring or aromatic heterocyclic group, B represents a group including a chain of one to four pieces of one or more groups selected from groups represented by specific formulae (B-1) to (B-13) (such as —C═C— or —N═N—, specifically see the description), R1 to R3 each represent an optionally substituted hydrocarbon or hydrocarbonoxy group, at least one of R1 to R3 represents an optionally substituted hydrocarbonoxy group, R4 and R5 each represent an optionally substituted hydrocarbon group, R4 and R5 may be linked together to form a ring, and R4 and R5 may be each independently linked with A to form a ring ##STR00001##

The present invention relates to compounds of formula (I) ##STR00001##
based on a porphyrin core and a π-conjugated linker or acceptor introduced between the porphyrin core and an anchoring group having a high absorption coefficient covering the whole UV-Visible and near-infrared spectral response, and their use as sensitizer or dye and an electrochemical or optoelectronic device including a compound of the invention.

Disclosed is an electrolyte for dye-sensitized solar cell element, which contains a halogen, a halide salt, and a basic substance and in which a redox pair is formed by the halogen and the halide salt, the halogen and the halide salt have the same halogen atom, and the basic substance contains a first imidazole compound constituted by a benzimidazole compound and a second imidazole compound represented by the following formula (1), in which a volume molar concentration C.sub.2 of the second imidazole compound is lower than a volume molar concentration C.sub.1 of the first imidazole compound:

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(in the formula (1), R.sup.1 to R.sup.4 each independently represent a hydrogen atom, a hydrocarbon group having from 1 to 6 carbon atoms or the like. R.sup.5 and R.sup.6 each independently represent an aliphatic hydrocarbon group or the like).

The invention provides an optoelectronic device comprising a mixed-anion perovskite, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions. The invention further provides a mixed-halide perovskite of the formula (I) [A][B][X].sub.3 wherein: [A] is at least one organic cation; [B] is at least one divalent metal cation; and [X] is said two or more different halide anions. In another aspect, the invention provides the use of a mixed-anion perovskite as a sensitizer in an optoelectronic device, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions. The invention also provides a photosensitizing material for an optoelectronic device comprising a mixed-anion perovskite wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions.

The present invention provides a novel method for producing a laminate to be used as a light-transmissive electrode layer and an N-type semiconductor layer of a wet or solid-state dye-sensitized solar cell comprising a light-transmissive electrode layer, an N-type semiconductor layer, a P-type semiconductor layer, and a facing electrode in this order. In said method, a member to be used as the light-transmissive electrode layer is cathode-polarized in a treatment solution containing a Ti component so as to form a titanium oxide layer to be used as the N-type semiconductor layer on said member.

The present invention relates to an unsymmetrical squaraine dye of formula (I) and process for the preparation thereof. Further, the present invention relates to an electronic device with an enhanced device efficiency containing a dye of formula (I) co-sensitized with a sqaurine dye.

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The disclosure provides an efficient and stable inorganic lead-free perovskite solar cell and a method for preparing the same. The solar cell includes a conductive substrate, a PEDOT: PSS layer, an inorganic lead-free CsSnI.sub.3 perovskite layer, a C60 layer, a BCP layer, and a metal counter electrode layer arranged in order from bottom to top, wherein the inorganic lead-free CsSnI.sub.3 perovskite layer is a CsSnI.sub.3 perovskite layer passivated by a thioureas small-molecule organic compound.

Platinum films can be obtained by aerosol assisted chemical vapor deposition (AACVD) using one or more Pt-dialkyldithiocarbamate complexes of formula Pt(S.sub.2CNR.sub.2), wherein R is independently alkyl, aryl, or alkaryl, particularly as single source precursors. Such methods may include heating a substrate to a deposition temperature above 150° C. in a reactor; and introducing into the reactor, at the deposition temperature, an aerosol including a platinum dithiocarbamate compound, salt, and/or solvate thereof, to thereby deposit the platinum layer on the substrate. The Pt(S.sub.2CNR.sub.2)-derived films have well-connected and defect-free surface topography and better catalytic performance, likely due to their high conductivity and reflectivity.

A solar cell includes a porous light absorbing layer, a first porous conducting layer, a second conducting layer, a porous substrate between the conducting layers, the porous substrate includes a catalytic conducting portion in electrical contact with the second conducting layer and an insulating portion between the first porous conducting layer and the conducting portion, and a conducting medium for transporting charges between the conducting portion and the light absorbing layer. The conducting medium is located in the light absorbing layer, the first porous conducting layer, and partly the porous substrate so that the insulating portion and a first part of the conducting portion has the conducting medium and a second part of the conducting portion is free of conducting medium.

The present invention provides compositions comprising a metal oxide electrode, a passivating agent on its surface, and a hybrid organic-inorganic perovskite active layer in contact with the metal oxide electrode surface. The presence of a passivating agent on the metal oxide surface increases stability and/or photovoltaic power conversion efficiency of the electronic component comprising a composition of the invention.