A nanocomposite is provided. The nanocomposite includes an electrically conductive nanostructured material; and metal fluoride nanostructures having the general formula M.sup.(I).sub.xM.sup.(II).sub.1−xF.sub.2+y−zn arranged on the electrically conductive nanostructured material, wherein M.sup.(I) and M.sup.(II) are independently transition metals, n is a stoichiometric coefficient, and wherein i) x=0, 0<y≦2, and z=0; or ii) 0<x<1, 0≦y≦2, z≧0, and M.sup.(I) and M.sup.(II) are different transition metals. An electrode including the nanocomposite and method of preparing the nanocomposite are also provided.

An all-solid-state battery including a cathode layer, an anode layer, and an electrolyte layer arranged between the cathode layer and the anode layer, the electrolyte layer including a first solid electrolyte layer including a sulfide solid electrolyte, and a second solid electrolyte layer other than the first solid electrolyte layer, the electrolyte layer including the sulfide solid electrolyte. Also provided is a method for manufacturing an all-solid-state battery including the steps of (a) making a cathode layer, (b) making an anode layer, (c) making an electrolyte layer including a first solid electrolyte layer including a sulfide solid electrolyte and a second solid electrolyte including the sulfide solid electrolyte, and (d) layering the cathode layer, the electrolyte layer, and the anode layer, such that the electrolyte layer is arranged between the cathode layer and the anode layer.

A cathode active material for a lithium secondary battery according to an embodiment of the present invention includes a lithium composite oxide, and a lithium-aluminum-sulfur-boron oxide formed on a surface of the lithium composite oxide. A lithium secondary battery including the cathode active material and having improved stability and electrical properties is provided.

An all-solid secondary battery, including: a first current collector; a pair of first active material layers disposed on opposite sides of the first current collector; a pair of solid electrolyte layers disposed on surfaces of the pair of first active material layers; a pair of second active material layers disposed on surfaces of the pair of solid electrolyte layers; and a pair of second current collectors disposed on surfaces of the pair of second active material layers, wherein a surface of one of the pair of second current collectors opposite to a surface of one of the pair of second active material layers does not comprise protrusions having a height of greater than about 8 micrometers.

The present disclosure relates to a delithiation solution and a method for forming an anode active material or an anode using the same. By chemically extracting reactive lithium from a high-capacity anode active material or anode, which has high initial coulombic efficiency due to high lithium content but exhibits decreased stability in dry air or in a solvent for preparation of a slurry, stability can be improve and initial coulombic efficiency can be maintained high. In addition, the method for forming an anode active material or an anode according to the present disclosure can greatly reduce the cost and time required for delivery after production of a lithium-ion battery.

Embodiments of the present disclosure are a pitch-based negative electrode material for a sodium-ion battery and related methods and applications. The method comprises: placing a pitch recursor into a muffle furnace to allow the pitch precursor to experience pre-oxidation for 2 to 6 hours at a temperature ranging from 200° C. to 350° C., to obtain pre-oxidized pitch; placing the pre-oxidized pitch into a high-temperature carbonization furnace, and increasing the temperature to 1300° C. to 1600° C. at a temperature increase speed of 0.5° C./min to 5° C./min, and carrying out thermal treatment on the pre-oxidized pitch in an inert atmosphere for 1 to 10 hours, to allow the pre-oxidized pitch to experience carbonization reactions, oxygen in the pre-oxidized pitch being used for breaking an ordered structure of the pitch during the carbonization of the pre-oxidized pitch, so as to form a wedge-shaped voids disordered structure.

A method for forming a rough silicon wafer including the successive steps of: performing a plasma etching of a surface of the wafer in conditions suitable to obtain a rough structure, and performing two successive ion milling steps, one at an incidence in the range of 0 to 10°, the other at an incidence in the range of 40 to 60° relative to the normal to the wafer.

Disclosed herein are methods of making an electrode. The method includes contacting an electrode material with a mixture that includes an alkali metal, an organic solvent, and an aromatic compound. Also disclosed herein are methods of making a battery that includes an electrode provided by the disclosed methods.

Methods for fabricating triazene-based graphitic carbon nitride films are provided. A substrate can be coated with silk fibroin, submerged in the central zone of plasma, and provided with microwave power. The substrate can then be dried to give a triazene-based graphitic carbon nitride film. Methods of the subject invention can be easily scaled up to industrial levels and produce triazene-based graphitic carbon nitride films that show excellent electrical properties as anodes in lithium-ion batteries.

Methods and systems are provided for salt-rinse surface doping of electrode materials for lithium-ion batteries. In one example, a method may include dissolving a dopant salt in a solvent to form a dopant salt rinse solution, rinsing an electrode active material with the dopant salt rinse solution to form a coated electrode active material, and heating the coated electrode active material to form a doped electrode active material. In some examples, a surface region of the doped electrode active material may include a uniform distribution of dopants from the dopant salt rinse solution. In this way, the electrode active material may be rinsed and doped via the dopant salt rinse solution in a single-stage process.