The patent provides a method for preparing titanium-based active electrodes with high stability coating layer, which belongs to the field of electrochemistry. The patent describes the active electrode is used titanium as the substrate, multi-metal oxides as the activated catalytic layer, and dense oxides as the protective layer. The multi-metal catalytic layer is formed by pyrolysis method to form the main body of titanium-based catalytic layer, and the dense oxide protective layer is combined with Sol-gel method and electrochemical deposition method to form a dense protective layer of titanium base. It can be widely used in chlor-alkali industry, paper industry, sewage treatment and other fields.

This application proposes the use of rechargeable and replaceable zinc cartridges to expand cycle life and lifetime of nickel-zinc and silver-zinc batteries. Two types of possible battery cell assemblies are demonstrated: a battery that includes face-to-back arrangement of cells, and side-by-side linked flat batteries that can be used as wall mounted batteries. An improved composition of the replaceable zinc electrode is suggested.

This application proposes the use of rechargeable and replaceable zinc cartridges to expand cycle life and lifetime of nickel-zinc and silver-zinc batteries. Two types of possible battery cell assemblies are demonstrated: a battery that includes face-to-back arrangement of cells, and side-by-side linked flat batteries that can be used as wall mounted batteries. An improved composition of the replaceable zinc electrode is suggested.

Provided is an electrolyte solution for a lithium secondary battery and a lithium secondary battery having the same, the electrolyte solution further including an expressed solid salt which has an ammonium-based cation and a cyanide anion (CN.sup.). According to an embodiment of the present invention, an electrolyte solution including the solid salt may be provided, and thus the problem of decrease in stability of a negative electrode due to copper ions that are dissolved from a copper current collector in a high-temperature environment may be resolved. Therefore, a lithium secondary battery having excellent battery performance such as battery capacity, charging and discharging efficiency, and cycle characteristics even under a high-temperature condition may be provided.

An alkaline secondary battery having excellent charge-discharge cycle characteristics is provided. The alkaline secondary battery includes a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode. The positive electrode contains a silver oxide. The negative electrode contains zinc-based particles selected from the group consisting of zinc particles and zinc alloy particles. The separator holds an alkaline electrolyte solution. An anion conductive membrane is disposed between the negative electrode and the separator. The anion conductive membrane includes a polymer as a matrix and particles of at least one metal compound selected from the group consisting of metal oxides, metal hydroxides, metal carbonates, metal sulfates, metal phosphates, metal borates, and metal silicates, which are dispersed in the matrix.

The technology described in this document can be embodied in a method of using a silver-zinc rechargeable battery to power a device. The method includes drawing, in a first mode of operation of a power management circuit, a first current from the battery to power the device. The first current is selected such that a target percentage of a capacity of the battery is discharged in a predetermined time of use of the device. The method also includes switching to a second mode of operation after the target percentage of the capacity of the battery is discharged. In the second mode of operation, a second current is drawn from the battery, wherein the second current is less than the first current. The method further includes powering the device using the second current.

The present invention relates to a secondary cell in the form of a hybrid system of a zinc-air battery and a silver oxide-zinc battery, comprising an anode, a cathode, and an electrolyte. The anode contains zinc (Zn) and/or zinc oxide (ZnO2), and the cathode is configured as a gas diffusion electrode which contains a mixture of silver (Ag) and/or silver oxide (Ag2O/AgO) with a catalyst for the electrochemical oxygen evolution, wherein the catalyst is selected from cobalt oxide Co3O4), manganese oxide (Mn3O4 or MnO2), cobalt-nickel oxide (CoNiO2), lanthanum-calcium-cobalt oxide (LaxCa1-xCoO3), ruthenium oxide (RuO2), iridium oxide (IrO2), platinum (Pt), palladium (Pd), and mixtures thereof.

The invention further relates to an accumulator which comprises one or a plurality of secondary cells, as well as a method for charging and a method for discharging a secondary cell or an accumulator.

The present invention relates to a secondary cell in the form of a hybrid system of a zinc-air battery and a silver oxide-zinc battery, comprising an anode, a cathode, and an electrolyte. The anode contains zinc (Zn) and/or zinc oxide (ZnO2), and the cathode is configured as a gas diffusion electrode which contains a mixture of silver (Ag) and/or silver oxide (Ag2O/AgO) with a catalyst for the electrochemical oxygen evolution, wherein the catalyst is selected from cobalt oxide Co3O4), manganese oxide (Mn3O4 or MnO2), cobalt-nickel oxide (CoNiO2), lanthanum-calcium-cobalt oxide (LaxCa1-xCoO3), ruthenium oxide (RuO2), iridium oxide (IrO2), platinum (Pt), palladium (Pd), and mixtures thereof.

The invention further relates to an accumulator which comprises one or a plurality of secondary cells, as well as a method for charging and a method for discharging a secondary cell or an accumulator.

An alkaline secondary battery disclosed in the present application includes a positive electrode containing a positive electrode active material, a negative electrode, and a separator. The positive electrode active material contains a mixture of a silver oxide and a silver-bismuth complex oxide. A discharge curve is obtained when the battery that is fully charged is discharged with a constant current until a battery voltage drops to 1.0 V. The battery voltage at a point on the discharge curve where x (%) of a total discharge capacity has been discharged from the battery since start of discharge is represented by V.sub.x (V). The discharge curve satisfies V.sub.10V.sub.700.08, has a step in the range of 70x90, and shows that a size of the step represented by V.sub.70V.sub.90 is 0.04 or more and 0.15 or less.

The technology described in this document can be embodied in a method of using a silver-zinc rechargeable battery to power a device. The method includes drawing, in a first mode of operation of a power management circuit, a first current from the battery to power the device. The first current is selected such that a target percentage of a capacity of the battery is discharged in a predetermined time of use of the device. The method also includes switching to a second mode of operation after the target percentage of the capacity of the battery is discharged. In the second mode of operation, a second current is drawn from the battery, wherein the second current is less than the first current. The method further includes powering the device using the second current.