The present disclosure relates to electrodes comprising a polymer film and a substrate, wherein the polymer film has a thickness of about 5 nm to about 600 nm. The present disclosure also relates to electrochemical cells and batteries comprising the electrodes disclosed herein. The present disclosure also relates to methods of making the electrodes disclosed herein.

Systems and methods for managing flow batteries utilize a battery management controller (BMC) coupled between a flow battery and a DC/DC converter, which is coupled to an electrical grid or a photovoltaic device via an inverter. The inverter converts an AC voltage to a first DC voltage and the DC/DC converter steps down the first DC voltage to a second DC voltage. The BMC includes a first power route, a second power route, and a current source converter coupled to the second power route. The BMC initializes the flow battery with a third DC voltage using the current source converter until a sensing circuit senses that the voltage of the flow battery has reached a predetermined voltage. The sensing circuit may include a capacitor, which has a small capacitance and is coupled across each cell of the flow battery, coupled in series between two resistors having very large resistances.

A battery includes a fluid negative electrode and a fluid positive electrode separated by a solid electrolyte at least when the electrodes and electrolyte are at an operating temperature. The solid electrolyte includes ions of the negative electrode material forming the fluid negative electrode and has a softness less than beta-alumina solid electrolyte (BASE) ceramics. In one example, the fluid negative electrode comprises lithium (Li), the fluid positive electrode comprises sulfur (S) and the solid electrolyte comprises lithium iodide (LiI).

Methods and systems are provided for a redox flow battery system. In one example, the redox flow battery is adapted with an additive included in a battery electrolyte and an anion exchange membrane separator dividing positive electrolyte from negative electrolyte. An overall system cost of the battery system may be reduced while a storage capacity, energy density and performance may be increased.

A molten sodium-based battery comprises a robust, highly Na-ion conductive, zero-crossover separator and a fully inorganic, fully liquid, highly cyclable molten cathode that operates at low temperatures.

These present disclosure provides a flexible battery comprising a top layer and a bottom layer coupled at a number of attachment points to form chambers within the battery to retain a shape of the battery under an increase in internal pressure. The flexible battery can include an anode and separator and a cathode, where the separator is a flexible polymer.

A quinone derivative with a high redox potential that does not undergo Michael addition or proto-desulfonation. This molecule addresses the key issues faced with the positive side material of an aqueous all-organic flow battery. This new molecule is 2,5-dihydroxy-4,6-dimethylbenzene-1,3-disulfonic acid (or the disulfonate salt thereof). This quinone derivative offers good solubility, electrochemical reversibility, and robustness to charge/discharge cycling. Quinones with reduced crossover are also provided.

A flow battery includes a first liquid containing a redox mediator, a first electrode, a first active material, and a first circulator that circulates the first liquid between the first electrode and the first active material. The redox mediator contains a heteranthrene compound. The redox mediator contains a heteranthrene compound. The heteranthrene compound has a skeletal structure including a central ring structure, the central ring structure containing no nitrogen.

Square section liquid metal batteries (LMBs) with a grid device to suppress instabilities of fluids. The LMBs include a shell, negative current collector, negative material, metallic nets/plates, grid device, electrolyte, positive material, rectangular holes on partitions of grid device, and positive current collector. The positive material, electrolyte, and negative material are filled in the shell and automatically stratified from bottom to top according to the density from large to small. The negative current collector is linked with negative material, and the positive current collector is linked with positive material. The grid device is composed of partitions which cross each other and pass through the negative material, the electrolyte vertically in sequence, and extend inside the positive material. There are rectangular holes opened on the grid device, and the vertical height of each rectangular hole is larger than the biggest displacement of electrolyte during charging and discharging processes.

A redox flow battery system includes an anolyte having chromium ions in solution; a catholyte having iron ions in solution, where a molar ratio of chromium in the anolyte to iron in the catholyte is at least 1.25; a first electrode in contact with the anolyte; a second electrode in contact with the catholyte; and a separator separating the anolyte from the catholyte.