Disclosed herein is a stabilised Na-ion oxide P3 phase of formula (I): P3-Na.sub.xM.sub.yO.sub.z Where, x>0.66, 0.8≤y≤1.0, z≤2; and M is selected from one or more of the group consisting of a 3d transition metal, a 4d transition metal, Al, Mg, B, Si, Sn, Sr and Ca. The stabilised Na-ion oxide P3 phase of formula (I) may be particularly useful as an active material in a Na-ion battery.

A discharge energy recovery and formation capacity grading apparatus for a soft-package power battery comprises a rack, a condition-variable charge and discharge power box arranged on the rack, a battery formation capacity-grading clamping movement mechanism for clamping positive and negative electrode lugs of the soft-package power battery, a battery tray for, a movement mechanism control assembly for controlling the movement of the battery formation and capacity grading clamping movement mechanism, a safety protection sensor assembly, and a battery formation capacity-grading control mechanism. The charge and discharge power box, the battery formation capacity-grading clamping movement mechanism, the battery tray, the movement mechanism control assembly, and the safety protection sensor assembly are all in signal connection with the battery formation capacity-grading control mechanism. The power transmission end of the charge and discharge power box is electrically connected with the power transmission end of the battery formation capacity-grading clamping movement mechanism.

Provided is a post-treatment method of a lithium secondary battery including: an activation step of charging a heated lithium secondary battery to an activation voltage and maintaining the battery at the voltage, in a state in which the lithium secondary battery including a positive electrode including a nickel-rich (Ni-rich) lithium-transition metal composite oxide having a layered structure containing 0.8 moles or more of Ni based on a total of 1 mole of transition metals as a positive electrode active material; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and an electrolyte solution, which are built in a battery case, is heated, the activation voltage being equal to or higher than a voltage generating phase transition of the lithium-transition metal composite oxide.

Methods for activating a secondary battery are provided, as well as methods for manufacturing a secondary battery, which include: providing a secondary battery including an electrode assembly and an electrolyte solution in a battery case, pre-aging the secondary battery at room temperature to provide a pre-aged secondary battery; initially charging the pre-aged secondary battery to provide an initially-charged secondary battery; aging the initially-charged secondary battery at room temperature to provide a room-temperature-aged secondary battery; fully charging the room-temperature-aged secondary battery to a voltage of 4.4V or more to provide a fully-charged secondary battery; and degassing the charged secondary battery to remove gas inside the fully-charged secondary battery. According to these methods, it is possible to increase the remaining amount of an electrolyte solution inside an electrode by fully charging a secondary battery.

A storage battery controlling device according to an embodiment of the present invention includes: a battery characteristic estimator configured to calculate an internal resistance of a secondary battery and a function indicating relationship between an open circuit voltage of the secondary battery and a state of charge or an amount of a charge charged of the secondary battery therein, on the basis of data of a temperature, a voltage and a current of the secondary battery which are measured in charging or discharging the secondary battery; and an input/output performance value calculator configured to calculate an inputtable/outputtable power amount of the secondary battery on the basis of the internal resistance and the function calculated by the battery characteristic estimator.

A method for determining a reference energy profile has comparing a first course and a second course. The first course describes an energy absorption of a first battery during a first charge cycle. The second course describes the energy absorption of the first or a second battery during a second charge cycle which follows after the first charge cycle. The comparison is performed for a plurality of time intervals. The method has determining a deviation between the first and the second course for each of the plurality of time intervals. In addition, the method has determining an amount of electrical energy based on the deviation for each of the time intervals, wherein the amount of electrical energy describes a preset default value of the reference energy profile for an amount of energy to be fed to a battery to be formed during a formation process of the battery to be formed for each of the time intervals.

Method for pre-lithiating an anode, wherein the method comprises the steps of: packing an anode sheet with a lithium-comprising sheet as a jelly roll or stack in an electrolyte; transferring lithium ions to the anode sheet to obtain a pre-lithiated anode sheet by direct contact between the anode sheet and the lithium-comprising sheet or by discharging or charging the anode sheet towards the lithium-comprising sheet; and dividing the pre-lithiated anode sheet into a plurality of pre-lithiated anodes of a desired size and shape. The invention further relates to an electrochemical cell comprising an an-ode which is pre-lithiated by the method.

A lithium-ion battery, including a battery cell, an electrolytic solution, and a packaging film. The battery cell is formed by winding a positive electrode plate and a negative electrode plate that are separated by a separator. The lithium-ion battery is half-charged to obtain a half-charged full battery. The half-charged full battery is stripped of the packaging film to obtain a half-charged cell. When a width of the half-charged full battery is w.sub.1, a width of the half-charged cell is w.sub.2, and g=w.sub.2/w.sub.1, the following conditional expression (1) is satisfied: 0.4<g<0.997. A negative active material of the negative electrode plate includes a silicon-based material. When a capacity per unit volume of the negative electrode plate is a, a and g satisfy the following conditional expression (2): 420 mAh/cm.sup.3<g×a<2300 mAh/cm.sup.3, where 619 mAh/cm.sup.3<a<3620 mAh/cm.sup.3. The present invention further provides an electronic device.

A method is provided for activating a secondary battery having a negative electrode, a positive electrode, and a microporous separator between the negative and positive electrodes permeated with carrier-ion containing electrolyte, the negative electrode having anodically active silicon or an alloy thereof. The method includes transferring carrier ions from the positive electrode to the negative electrode to at least partially charge the secondary battery, and transferring carrier ions from an auxiliary electrode to the positive electrode, to provide the secondary battery with a positive electrode end of discharge voltage V.sub.pos,eod and a negative electrode end of discharge voltage V.sub.neg,eod when the cell is at a predefined V.sub.cell,eod value, the value of V.sub.pos,eod corresponding to a voltage at which the state of charge of the positive electrode is at least 95% of its coulombic capacity and V.sub.neg,eod is at least 0.4 V (vs Li) but less than 0.9 V (vs Li).

The present invention relates to a method for manufacturing a secondary battery and a pre-degassing device for manufacturing a secondary battery. The method for manufacturing the secondary battery comprises: an accommodation process of accommodating an electrode assembly in an accommodation part formed inside a battery case to form a cell; an electrolyte injection process of injecting an electrolyte into the accommodation part of the battery case; a primary aging process of elapsing a predetermined time so that the electrode assembly is impregnated into the electrolyte; a primary charging process of primarily charging and discharging the cell; a pre-degassing process of pressing the battery case to discharge a gas inside the electrode assembly to the outside of the electrode assembly; and a secondary aging process of elapsing a predetermined time so that the electrode assembly is impregnated into the electrolyte, wherein, in the pre-degassing process, the battery case is pressed while applying heat to the battery case.