A photovoltaic device is presented. The photovoltaic device includes a buffer layer disposed on a transparent conductive oxide layer; a window layer disposed on the buffer layer; and an interlayer interposed between the transparent conductive oxide layer and the window layer. The interlayer includes a metal species, wherein the metal species includes gadolinium, beryllium, calcium, barium, strontium, scandium, yttrium, hafnium, cerium, lutetium, lanthanum, or combinations thereof. A method of making a photovoltaic device is also presented.

The present invention proposes a method to form a double-graded CdSeTe thin film. The method comprises providing a base substrate, forming a first CdSe.sub.wTe.sub.1-w layer having a first amount w1 of selenium in it, forming a second CdSe.sub.wTe.sub.1-w layer having a second amount w2 of selenium in it and forming a third CdSe.sub.wTe.sub.1-w layer having a third amount w3 of selenium in it. The second amount w2 lies in the range between 0.25 and 0.4, whereas each of the amounts w1 and w3 lies in the range extending from 0 to 1. According to the present invention, the energy gap in the first and the third CdSe.sub.wTe.sub.1-w layers is equal to or higher than 1.45 eV and the energy gap in the second CdSe.sub.wTe.sub.1-w layer lies in the range between 1.38 eV and 1.45 eV and is smaller than the energy gap in the first and the third CdSe.sub.wTe.sub.1-w layers.

According to the embodiments provided herein, back contacts for photovoltaic devices can include one or more metal oxynitride layers.

According to the embodiments provided herein, back contacts for photovoltaic devices can include one or more metal oxynitride layers.

A photovoltaic device includes an electron blocking layer (EBL) and an absorber layer. The EBL is positioned between the absorber layer and a back contact layer. A material of the EBL is a cadmium zinc telluride Cd.sub.(1-y)Zn.sub.(y)Te, and a material of the absorber layer is a cadmium telluride selenide CdTe.sub.(1-x)Se.sub.(x) producing a lattice mismatch between the materials of the EBL and between the materials of the absorber of less than about two tenths of a percent when x˜y and has a value less than about 0.4.

A photovoltaic device includes an electron blocking layer (EBL) and an absorber layer. The EBL is positioned between the absorber layer and a back contact layer. A material of the EBL is a cadmium zinc telluride Cd.sub.(1-y)Zn.sub.(y)Te, and a material of the absorber layer is a cadmium telluride selenide CdTe.sub.(1-x)Se.sub.(x) producing a lattice mismatch between the materials of the EBL and between the materials of the absorber of less than about two tenths of a percent when x˜y and has a value less than about 0.4.

Systems and methods of three-terminal tandem solar cells are described. Three-terminal metal electrodes can be formed to contact subcells of the tandem solar cell. The three-terminal tandem cell can improve the device efficiency to at least 30%.

Systems and methods of three-terminal tandem solar cells are described. Three-terminal metal electrodes can be formed to contact subcells of the tandem solar cell. The three-terminal tandem cell can improve the device efficiency to at least 30%.

A photovoltaic cell can include an interfacial layer in contact with a semiconductor layer.

A photovoltaic cell can include an interfacial layer in contact with a semiconductor layer.