Provided is an anode material for a secondary battery which reduces and inhibits swelling of a high-capacity silicon-containing alloy material to realize excellent charge/discharge cycle characteristics. The anode material includes alloy particles containing a transition metal which has electron conductivity, is difficult to react with lithium atoms and is at least one selected from the group of metals that belong to transition metals, and silicon, wherein the alloy particles include amorphous silicon, and silicide microcrystals formed by silicon and the transition metal, and the silicide microcrystals are scattered in amorphous silicon.

A method for preparing a lithium alloy as an anode material includes the following steps: heating lithium metal into a molten state in an environment with a dew point not higher than 50 C. and an oxygen content not higher than 10 ppm; adding a transition metal to the molten lithium metal, maintaining the temperature for 5-15 minutes, and uniformly mixing to form a molten alloy; cooling the molten alloy to room temperature to obtain the lithium alloy as the anode material. The preparation method of the present invention is simple and feasible with less cost. The prepared lithium alloy as the anode material can effectively improve the coulombic efficiency and cycle lifespan of the lithium battery.

Disclosed herein are multiphase metal anodes useful in non-aqueous batteries. The anodes include at least one active metal and at least one conductive metal.

A negative electrode for a lithium secondary battery contains a lithium-magnesium-aluminum alloy. A method for preparing the same and a lithium secondary battery, such as a lithium sulfur battery, containing the same are also provided.

A negative electrode includes a lithium-alkaline earth metal alloy, and can be used in a lithium-sulfur battery. Furthermore, a method to obtain said negative electrode, and a lithium-sulfur battery containing the negative electrode.

A negative electrode includes a lithium-lanthanum alloy. The negative electrode can be applied to a negative electrode for a lithium-sulfur battery. The lithium-sulfur battery including the alloy negative electrode has improved life characteristics and improved electrochemical efficiency.

An anode active material and a method for preparing the same, wherein the anode active material has a core-shell structure having formula (MOx-Liy)-C (here, M is a metal (or metalloid), x is greater than 0 and less than 1.5, and y is greater than 0 and less than 4) and including a core part containing an alloy of a metal (or metalloid) oxide-Li (MOx-Liy) and a shell part containing a carbon material coated on a surface of the core part, wherein the shell part contains lithium in an amount less than 5 atm % in the surface and the inner portion thereof. The anode active material can provide high capacity, excellent cycle characteristics, excellent volume expansion control capability, and high initial efficiency.

The anode active material of the present invention comprises silicon-based particles obtained from at least one of silicon, a silicon oxide and a silicon alloy, and the silicon-based particles have a faceted shape, thereby providing high capacity and good life characteristics without causing any deterioration which has been generated in the use of conventional silicon-based particles, and eventually providing a lithium secondary battery having such characteristics.

Metal alloy layers on substrates. The metal-alloy layers (e.g., lithium-metal layers, sodium-metal layers, and magnesium-metal layers) can be disposed on, for example, a solid-state electrolyte material. The metal-alloy layers can be used in, for example, solid-state batteries. A metal alloy layer can be an anode or part of an anode of a solid state battery.

A method for preparing a lithium alloy as an anode material includes the following steps: heating lithium metal into a molten state in an environment with a dew point not higher than ?50? C. and an oxygen content not higher than 10 ppm; adding a transition metal to the molten lithium metal, maintaining the temperature for 5-15 minutes, and uniformly mixing to form a molten alloy; cooling the molten alloy to room temperature to obtain the lithium alloy as the anode material. The preparation method of the present invention is simple and feasible with less cost. The prepared lithium alloy as the anode material can effectively improve the coulombic efficiency and cycle lifespan of the lithium battery.