Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials, a film of solid electrolyte materials and a film of cathode materials, in which: each of these three films is deposited using an electrophoresis process, the anode film and the cathode film are each deposited on a conducting substrate, preferably a thin metal sheet or band, or a metalized insulating sheet or band or film, said conducting substrates or their conducting elements being useable as battery current collectors, the electrolyte film is deposited on the anode and/or cathode film,
and in which said process also comprises at least one step in which said sheets or bands are stacked so as to form at least one battery with a collector/anode/electrolyte/cathode/collector type of stacked structure.

A positive electrode active material for a non-aqueous electrolyte secondary battery includes secondary particles of a lithium transition metal complex oxide as a main component. The main component is represented by a formula: Li.sub.t(Ni.sub.1-xCo.sub.x).sub.1-yMn.sub.yB.sub.P.sub.S.sub.O.sub.2, where t, x, y, , , and satisfy inequalities of 0x1, 0.00y0.50, (1x).Math.(1y)y, 0.0000.020, 0.0000.030, 0.0000.030, and 1+3+3+2t1.30, and satisfy at least one of inequalities of 0.002, 0.006, and 0.004. The secondary particles exhibit a pore distribution, where a pore volume Vp(1) having a pore diameter of not less than 0.01 m and not more than 0.15 m satisfies an inequality of 0.035 cm.sup.3/gVp(1) and where a pore volume Vp(2) having a pore diameter of not less than 0.01 m and not more than 10 m satisfies an inequality of Vp(2)0.450 cm.sup.3/g.

A positive electrode active material for a non-aqueous electrolyte secondary battery includes secondary particles of a lithium transition metal complex oxide as a main component. The main component is represented by a formula: Li.sub.t(Ni.sub.1-xCo.sub.x).sub.1-yMn.sub.yB.sub.P.sub.S.sub.O.sub.2, where t, x, y, , , and satisfy inequalities of 0x1, 0.00y0.50, (1x).Math.(1y)y, 0.0000.020, 0.0000.030, 0.0000.030, and 1+3+3+2t1.30, and satisfy at least one of inequalities of 0.002, 0.006, and 0.004. The secondary particles exhibit a pore distribution, where a pore volume Vp(1) having a pore diameter of not less than 0.01 m and not more than 0.15 m satisfies an inequality of 0.035 cm.sup.3/gVp(1) and where a pore volume Vp(2) having a pore diameter of not less than 0.01 m and not more than 10 m satisfies an inequality of Vp(2)0.450 cm.sup.3/g.

A method of producing an electrode for a lithium ion battery is disclosed in which an electrically conductive substrate is immersed into an electrodepositable composition, the substrate serving as the electrode in an electrical circuit comprising the electrode and a counter-electrode immersed in the composition, a coating being applied onto or over at least a portion of the substrate as electric current is passed between the electrodes. The electrodepositable composition comprises: (a) an aqueous medium; (b) an ionic (meth)acrylic polymer; and (c) solid particles comprising: (i) lithium-containing particles, and (ii) electrically conductive particles, wherein the composition has a weight ratio of solid particles to ionic (meth)acrylic polymer of at least 4:1.

A method of producing an electrode for a lithium ion battery is disclosed in which an electrically conductive substrate is immersed into an electrodepositable composition, the substrate serving as the electrode in an electrical circuit comprising the electrode and a counter-electrode immersed in the composition, a coating being applied onto or over at least a portion of the substrate as electric current is passed between the electrodes. The electrodepositable composition comprises: (a) an aqueous medium; (b) an ionic (meth)acrylic polymer; and (c) solid particles comprising: (i) lithium-containing particles, and (ii) electrically conductive particles, wherein the composition has a weight ratio of solid particles to ionic (meth)acrylic polymer of at least 4:1.

A method for preparing an electrode for use in lithium batteries and the resulting electrodes are described The method comprises coating a slurry of silicon, sulfur doped graphene and polyacrylonitrile on a current collector followed by sluggish heat treatment.

A method for preparing an electrode for use in lithium batteries and the resulting electrodes are described The method comprises coating a slurry of silicon, sulfur doped graphene and polyacrylonitrile on a current collector followed by sluggish heat treatment.

A positive electrode for an all-solid secondary battery, comprising a positive electrode active material expressed by A.sub.2S.AX, wherein A is an alkali metal; and X is selected from I, Br, Cl, F, BF.sub.4, BH.sub.4, SO.sub.4, BO.sub.3, PO.sub.4, O, Se, N, P, As, Sb, PF.sub.6, AsF.sub.6, ClO.sub.4, NO.sub.3, CO.sub.3, CF.sub.3SO.sub.3, CF.sub.3COO, N(SO.sub.2F).sub.2 and N(CF.sub.3SO.sub.2).sub.2.

A positive electrode for an all-solid secondary battery, comprising a positive electrode active material expressed by A.sub.2S.AX, wherein A is an alkali metal; and X is selected from I, Br, Cl, F, BF.sub.4, BH.sub.4, SO.sub.4, BO.sub.3, PO.sub.4, O, Se, N, P, As, Sb, PF.sub.6, AsF.sub.6, ClO.sub.4, NO.sub.3, CO.sub.3, CF.sub.3SO.sub.3, CF.sub.3COO, N(SO.sub.2F).sub.2 and N(CF.sub.3SO.sub.2).sub.2.

An immobilized selenium body, made from carbon and selenium and optionally sulfur, makes selenium more stable, requiring a higher temperature or an increase in kinetic energy for selenium to escape from the immobilized selenium body and enter a gas system, as compared to selenium alone. Immobilized selenium localized in a carbon skeleton can be utilized in a rechargeable battery. Immobilization of the selenium can impart compression stress on both the carbon skeleton and the selenium. Such compression stress enhances the electrical conductivity in the carbon skeleton and among the selenium particles and creates an interface for electrons to be delivered and or harvested in use of the battery. A rechargeable battery made from immobilized selenium can be charged or discharged at a faster rate over conventional batteries and can demonstrate excellent cycling stability.