A solid-state sodium-carbon dioxide battery is provided. The solid-state sodium-carbon dioxide battery comprises a positive electrode, a negative electrode, and an inorganic solid-state electrolyte disposed between the positive electrode and the negative electrode, wherein the positive electrode can catalyze the reaction of sodium ions and carbon dioxide, the negative electrode comprises sodium.

This electrically conductive composition includes a thermoplastic elastomer and flaky graphite, the melt viscosity of the thermoplastic elastomer at 200° C. in a low-shear zone with a shear rate of 60 s.sup.−1 to 200 s.sup.−1 being 50 Pa.Math.s to 1400 Pa.Math.s, and the roundness of the flaky graphite being 0.5 or less. This method for producing a sheet-form flexible electrode has a kneading step for kneading expanded graphite and a thermoplastic elastomer having a melt viscosity of 50 Pa.Math.s to 1400 Pa.Math.s at 200° C. in a low-shear zone with a shear rate of 60 s.sup.−1 to 200 s−.sup.1 to produce the electrically conductive composition, and a molding step for molding the electrically conductive composition into the form of a sheet by injection molding or extrusion molding.

This electrically conductive composition includes a thermoplastic elastomer and flaky graphite, the melt viscosity of the thermoplastic elastomer at 200° C. in a low-shear zone with a shear rate of 60 s.sup.−1 to 200 s.sup.−1 being 50 Pa.Math.s to 1400 Pa.Math.s, and the roundness of the flaky graphite being 0.5 or less. This method for producing a sheet-form flexible electrode has a kneading step for kneading expanded graphite and a thermoplastic elastomer having a melt viscosity of 50 Pa.Math.s to 1400 Pa.Math.s at 200° C. in a low-shear zone with a shear rate of 60 s.sup.−1 to 200 s−.sup.1 to produce the electrically conductive composition, and a molding step for molding the electrically conductive composition into the form of a sheet by injection molding or extrusion molding.

An electrode material useful as a dry in place deposit comprising at least one metal chelating polymer; an active material capable of reversibly intercalating lithium ions; a plurality of electrical conductor particles; a binder polymer. The electrode material is formed into a slurry using a non-aqueous solvent. The metal chelating polymer may be a reaction product of a polyphenolic polymer; an aldehyde, a ketone, or mixtures thereof; and an amine. The electrode material slurry is deposited on a current collector and dried to form a positive electrode in a secondary lithium ion battery. The deposited electrode material has high flexibility, adhesion to the current collector, resistance to electrolyte damage, and low electrical resistance. The electrode material forms a superior positive electrode at a relatively low additional cost and with no increase in process complexity.

An electrode material useful as a dry in place deposit comprising at least one metal chelating polymer; an active material capable of reversibly intercalating lithium ions; a plurality of electrical conductor particles; a binder polymer. The electrode material is formed into a slurry using a non-aqueous solvent. The metal chelating polymer may be a reaction product of a polyphenolic polymer; an aldehyde, a ketone, or mixtures thereof; and an amine. The electrode material slurry is deposited on a current collector and dried to form a positive electrode in a secondary lithium ion battery. The deposited electrode material has high flexibility, adhesion to the current collector, resistance to electrolyte damage, and low electrical resistance. The electrode material forms a superior positive electrode at a relatively low additional cost and with no increase in process complexity.

The present invention provides a high-performance lithium-containing organic sulfur electrode material and a preparation method of an integrated flexible electrode. According to the present invention, 1,3-diisopropenyl benzene with diene bonds and Li2S6 are used as precursors to react to generate the lithium-containing organic sulfide Poly (Li2S6-r-DIB) through an in-situ polymerization method. The synthesized lithium-containing organic sulfide Poly (Li2S6-r-DIB) can be directly attached to a flexible conductive carbon cloth to prepare the integrated flexible electrode due to its good viscosity when heated to a certain temperature. The obtained flexible electrode has the advantages of high capacity, high flexibility, stable structure and the like.

The present invention provides a high-performance lithium-containing organic sulfur electrode material and a preparation method of an integrated flexible electrode. According to the present invention, 1,3-diisopropenyl benzene with diene bonds and Li2S6 are used as precursors to react to generate the lithium-containing organic sulfide Poly (Li2S6-r-DIB) through an in-situ polymerization method. The synthesized lithium-containing organic sulfide Poly (Li2S6-r-DIB) can be directly attached to a flexible conductive carbon cloth to prepare the integrated flexible electrode due to its good viscosity when heated to a certain temperature. The obtained flexible electrode has the advantages of high capacity, high flexibility, stable structure and the like.

A method for producing nano-composites comprising graphitic carbon nitride reduced to nano size, having high electrical conductivity is provided. The method includes the steps of: producing graphitic carbon nitride (g-C.sub.3N.sub.4) having a chemical formula (C.sub.3N.sub.4).sub.m, applying an obtained g-C.sub.3N.sub.4 powder via an ultrasonic homogenization method on concentrations, obtaining a nano g-C.sub.3N.sub.4 suspension, wherein a size of the nano g-C.sub.3N.sub.4 suspension changes between 10-100 nm as a result of applying the ultrasonic homogenization method, obtaining polyaniline with a chemical formula (C.sub.6H.sub.7N).sub.n in an emeraldine salt form, obtaining a nano-composite, mixing in aniline or aniline-HCl water at concentrations of 0.1-1 mol/L, adding a nano graphitic carbon (nano g-C.sub.3N.sub.4) into a mixture and mixing between 10-60 minutes, carrying out a polymerization process by adding an oxidant to the mixture and obtaining the nano composite having the high electrical conductivity.

A positive electrode active material for an electrochemical device has a fiber shape or a grain-aggregate shape. The positive electrode active material includes an inner core part having a fiber shape or a grain-aggregate shape, and a superficial part covering at least part of the inner core part. The inner core part contains a first conductive polymer, and the superficial part contains a second conductive polymer that is different from the first conductive polymer.

A positive electrode active material for an electrochemical device has a fiber shape or a grain-aggregate shape. The positive electrode active material includes an inner core part having a fiber shape or a grain-aggregate shape, and a superficial part covering at least part of the inner core part. The inner core part contains a first conductive polymer, and the superficial part contains a second conductive polymer that is different from the first conductive polymer.