The present invention provides a high-performance lithium-containing organic sulfur electrode material and a preparation method of an integrated flexible electrode. According to the present invention, 1,3-diisopropenyl benzene with diene bonds and Li2S6 are used as precursors to react to generate the lithium-containing organic sulfide Poly (Li2S6-r-DIB) through an in-situ polymerization method. The synthesized lithium-containing organic sulfide Poly (Li2S6-r-DIB) can be directly attached to a flexible conductive carbon cloth to prepare the integrated flexible electrode due to its good viscosity when heated to a certain temperature. The obtained flexible electrode has the advantages of high capacity, high flexibility, stable structure and the like.

The present invention provides a high-performance lithium-containing organic sulfur electrode material and a preparation method of an integrated flexible electrode. According to the present invention, 1,3-diisopropenyl benzene with diene bonds and Li2S6 are used as precursors to react to generate the lithium-containing organic sulfide Poly (Li2S6-r-DIB) through an in-situ polymerization method. The synthesized lithium-containing organic sulfide Poly (Li2S6-r-DIB) can be directly attached to a flexible conductive carbon cloth to prepare the integrated flexible electrode due to its good viscosity when heated to a certain temperature. The obtained flexible electrode has the advantages of high capacity, high flexibility, stable structure and the like.

Provided is a composite layer of graphene sheets and anode particles being dispersed in a conducting polymer network for a lithium battery anode (negative electrode), the layer comprising a mixture of a conducting polymer network, multiple graphene sheets, and multiple particles of an anode active material, wherein the anode particles have a diameter or thickness from 0.5 nm to 20 μm and occupy from 30% to 98% by weight, the graphene sheets occupy from 0.01% to 25% by weight, and the conducting polymer network occupies from 1% to 30% by weight based on the total mixture weight and wherein the graphene sheets and the conducting polymer network together form dual conducting pathways for both electrons and lithium ions having an electron conductivity from 10.sup.−8 S/cm to 10.sup.3 S/cm and lithium ion conductivity from 10.sup.−8 to 5.0×10.sup.−3 S/cm when measured at room temperature.

Provided is a composite layer of graphene sheets and anode particles being dispersed in a conducting polymer network for a lithium battery anode (negative electrode), the layer comprising a mixture of a conducting polymer network, multiple graphene sheets, and multiple particles of an anode active material, wherein the anode particles have a diameter or thickness from 0.5 nm to 20 μm and occupy from 30% to 98% by weight, the graphene sheets occupy from 0.01% to 25% by weight, and the conducting polymer network occupies from 1% to 30% by weight based on the total mixture weight and wherein the graphene sheets and the conducting polymer network together form dual conducting pathways for both electrons and lithium ions having an electron conductivity from 10.sup.−8 S/cm to 10.sup.3 S/cm and lithium ion conductivity from 10.sup.−8 to 5.0×10.sup.−3 S/cm when measured at room temperature.

Disclosed is a sulfur-based electrode active material with which a nonaqueous electrolyte secondary battery that has a large capacity and exhibits less deterioration of the cycle characteristics can be obtained even when an electrode is employed in which the sulfur-based electrode active material is used as an electrode active material and an aluminum foil is used as a current collector. Also disclosed is a method for producing an organosulfur electrode active material, including a step of obtaining an organosulfur compound by heat-treating an organic compound and sulfur and a step of treating the organosulfur compound with a basic compound. The organosulfur compound is preferably sulfur-modified polyacrylonitrile, and the basic compound is preferably ammonia. The organosulfur compound may be treated with the basic compound after the organosulfur compound is ground, or may be ground in a medium that contains the basic compound.

A novel electrode material features improved capacity compared to conventional electrode materials. This electrode material includes an organic redox polymer non-conjugated in the main chain, a conductivity additive, and an ionic liquid. Also, a process is for producing an electrode from this novel electrode material. The electrode obtainable by the process also features improved capacity.

An electrode material useful as a dry in place deposit comprising at least one metal chelating polymer; an active material capable of reversibly intercalating lithium ions; a plurality of electrical conductor particles; a binder polymer. The electrode material is formed into a slurry using a non-aqueous solvent. The metal chelating polymer may be a reaction product of a polyphenolic polymer; an aldehyde, a ketone, or mixtures thereof; and an amine. The electrode material slurry is deposited on a current collector and dried to form a positive electrode in a secondary lithium ion battery. The deposited electrode material has high flexibility, adhesion to the current collector, resistance to electrolyte damage, and low electrical resistance. The electrode material forms a superior positive electrode at a relatively low additional cost and with no increase in process complexity.

An electrode material useful as a dry in place deposit comprising at least one metal chelating polymer; an active material capable of reversibly intercalating lithium ions; a plurality of electrical conductor particles; a binder polymer. The electrode material is formed into a slurry using a non-aqueous solvent. The metal chelating polymer may be a reaction product of a polyphenolic polymer; an aldehyde, a ketone, or mixtures thereof; and an amine. The electrode material slurry is deposited on a current collector and dried to form a positive electrode in a secondary lithium ion battery. The deposited electrode material has high flexibility, adhesion to the current collector, resistance to electrolyte damage, and low electrical resistance. The electrode material forms a superior positive electrode at a relatively low additional cost and with no increase in process complexity.

The present application relates to an electrode, a method for manufacturing the electrode, and a secondary battery comprising the electrode. The present application relates to an electrode comprising a current collector, an active material layer, and a thiophene polymer layer formed on the active material layer and can provide an electrode capable of ensuring a higher level of adhesion force between particles and adhesion force between the active material layer and the current collector relative to the binder content in the active material layer. In addition, the present application can provide a method for manufacturing the electrode, and a secondary battery comprising the same.

The present application relates to an electrode, a method for manufacturing the electrode, and a secondary battery comprising the electrode. The present application relates to an electrode comprising a current collector, an active material layer, and a thiophene polymer layer formed on the active material layer and can provide an electrode capable of ensuring a higher level of adhesion force between particles and adhesion force between the active material layer and the current collector relative to the binder content in the active material layer. In addition, the present application can provide a method for manufacturing the electrode, and a secondary battery comprising the same.