This negative electrode for nonaqueous electrolyte secondary batteries is provided with a negative electrode mixture layer that contains a negative electrode active material and carbon nanotubes. The negative electrode active material contains a first negative electrode active material and a second negative electrode active material; the first negative electrode active material and the second negative electrode active material contain lithium silicate phases, each of which contains lithium, silicon and oxygen, and silicon particles that are dispersed in the lithium silicate phases; the molar ratios of oxygen to silicon (O/Si) in the lithium silicate phases are different from each other; the carbon nanotubes have a diameter of from 1 nm to 5 nm; and the ratio of the mass of the first negative electrode active material relative to the total mass of the first negative electrode active material and the second negative electrode active material is 60% or less.

This negative electrode for nonaqueous electrolyte secondary batteries is provided with a negative electrode mixture layer that contains a negative electrode active material and carbon nanotubes. The negative electrode active material contains a first negative electrode active material and a second negative electrode active material; the first negative electrode active material and the second negative electrode active material contain lithium silicate phases, each of which contains lithium, silicon and oxygen, and silicon particles that are dispersed in the lithium silicate phases; the molar ratios of oxygen to silicon (O/Si) in the lithium silicate phases are different from each other; the carbon nanotubes have a diameter of from 1 nm to 5 nm; and the ratio of the mass of the first negative electrode active material relative to the total mass of the first negative electrode active material and the second negative electrode active material is 60% or less.

A negative electrode active material particle with little deterioration is provided. Alternatively, a novel negative electrode active material particle is provided. Alternatively, a power storage device with little deterioration is provided. Alternatively, a highly safe power storage device is provided. Alternatively, a novel power storage device is provided. The electrode includes an active material and a conductive additive; the active material contains a metal or a compound including one or more elements selected from silicon, tin, gallium, aluminum, germanium, lead, antimony, bismuth, silver, zinc, cadmium, and indium; the conductive additive contains a graphene compound; and the graphene compound contains fluorine.

The invention relates to a positive plate for a lithium battery, preparation method thereof and use in semi-solid state battery. The positive plate for a lithium battery comprises a current collector and an active material layer arranged on a surface of the current collector; and the active material layer comprises a positive electrode active material, a conductive agent, a binder, an oxide solid-state electrolyte and a polymer obtained by in-situ polymerization. The oxide solid-state electrolyte and polymer are evenly distributed in the active material layer; wherein the oxide solid-state electrolyte can effectively improve the safety performance of the positive plate; and the polymer obtained by in situ polymerization can effectively improve the contact between the oxide solid-state electrolyte and the material in the positive plate, thereby reducing the impedance of the positive plate and improving the electrochemical performance of the positive plate. The combination of the oxide solid-state electrolyte and polymer in the present application enables the positive plate of the present application to possess excellent electrochemical performance, in addition to excellent safety performance.

The invention relates to a positive plate for a lithium battery, preparation method thereof and use in semi-solid state battery. The positive plate for a lithium battery comprises a current collector and an active material layer arranged on a surface of the current collector; and the active material layer comprises a positive electrode active material, a conductive agent, a binder, an oxide solid-state electrolyte and a polymer obtained by in-situ polymerization. The oxide solid-state electrolyte and polymer are evenly distributed in the active material layer; wherein the oxide solid-state electrolyte can effectively improve the safety performance of the positive plate; and the polymer obtained by in situ polymerization can effectively improve the contact between the oxide solid-state electrolyte and the material in the positive plate, thereby reducing the impedance of the positive plate and improving the electrochemical performance of the positive plate. The combination of the oxide solid-state electrolyte and polymer in the present application enables the positive plate of the present application to possess excellent electrochemical performance, in addition to excellent safety performance.

An object of the present invention is to provide composite particles capable of suppressing oxidation over time of a Si—C composite material. Composite particles (B) of the present invention contains composite particles (A) containing carbon and silicon; and amorphous layers coating surfaces thereof, where the composite particles (B) have I.sub.Si/I.sub.G of 0.10 or more and 0.65 or less, and have R value (I.sub.D/I.sub.G) of 1.00 or more and 1.30 or less, when a peak due to silicon is present at 450 to 495 cm.sup.−1, an intensity of the peak is defined as I.sub.Si, an intensity of a G band (peak intensity in the vicinity of 1600 cm.sup.−1) is defined as I.sub.G, and an intensity of a D band (peak intensity in the vicinity of 1360 cm.sup.−1) is defined as I.sub.D in a Raman spectrum, and where the composite particles (B) have a full width at half maximum of a peak of a 111 plane of Si of 3.0 deg. or more using a Cu-Kα ray in an XRD pattern.

A negative electrode for an all-solid-state secondary battery according to the present invention includes a molded body made of a negative electrode mixture containing a solid electrolyte and a negative-electrode material that contains a negative-electrode active material, in which the negative-electrode material contains a carbon material as the negative-electrode active material, a layer containing an oxide having lithium-ion conductivity is formed on a surface of the negative-electrode material, the amount of the oxide is 1 part by mass or more with respect to 100 parts by mass of the carbon material, and the negative electrode contains a sulfide-based solid electrolyte as the solid electrolyte. Also, an all-solid-state secondary battery according to the present invention includes the negative electrode for an all-solid-state secondary battery according to the present invention as the negative electrode.

A negative electrode for an all-solid-state secondary battery according to the present invention includes a molded body made of a negative electrode mixture containing a solid electrolyte and a negative-electrode material that contains a negative-electrode active material, in which the negative-electrode material contains a carbon material as the negative-electrode active material, a layer containing an oxide having lithium-ion conductivity is formed on a surface of the negative-electrode material, the amount of the oxide is 1 part by mass or more with respect to 100 parts by mass of the carbon material, and the negative electrode contains a sulfide-based solid electrolyte as the solid electrolyte. Also, an all-solid-state secondary battery according to the present invention includes the negative electrode for an all-solid-state secondary battery according to the present invention as the negative electrode.

An anode piece for a lithium battery having both high safety and high capacity, and a preparation method and a use therefor, the anode piece being mixed with a lithium-rich compound, the lithium-rich compound being at least one selected from lithium-rich manganese-based solid solution, a lithium-rich solid electrolyte or a lithium-separated silicon oxide. Li ions can be pulled away from the lithium-rich compound in extreme conditions such as overcharging, internal short circuiting, external short circuiting, thermal abuse, piercing, compressing or overheating, thereby filling in lithium vacancies in the anode material, stabilizing the crystal lattice structure of the anode material, improving safety performance in a battery manufactured by using the material, and allowing the anode piece to maintain excellent cycle performance at higher area capacities.

One embodiment of the present invention relates to a solid electrolyte material, a solid electrolyte, a method for producing the solid electrolyte, or an all-solid-state battery, and the solid electrolyte material includes lithium, tantalum, boron, phosphorus, and oxygen as constituent elements, wherein a peak position of a peak having the maximum peak intensity among an .sup.11B-NMR peak is in the range of -15.0 to -5.0 ppm.