Preparation, characterization, and an electrochemical study of Mg.sub.0.1V.sub.2O.sub.5 prepared by a novel sol-gel method with no high-temperature post-processing are disclosed. Cyclic voltammetry showed the material to be quasi-reversible, with improved kinetics in an acetonitrile-, relative to a carbonate-, based electrolyte. Galvanostatic test data under a C/10 discharge showed a delivered capacity >250 mAh/g over several cycles. Based on these results, a magnesium anode battery, as disclosed, would yield an average operating voltage 3.2 Volts with an energy density 800 mWh/g for the cathode material, making the newly synthesized material a viable cathode material for secondary magnesium batteries.

Preparation, characterization, and an electrochemical study of Mg.sub.0.1V.sub.2O.sub.5 prepared by a novel sol-gel method with no high-temperature post-processing are disclosed. Cyclic voltammetry showed the material to be quasi-reversible, with improved kinetics in an acetonitrile-, relative to a carbonate-, based electrolyte. Galvanostatic test data under a C/10 discharge showed a delivered capacity >250 mAh/g over several cycles. Based on these results, a magnesium anode battery, as disclosed, would yield an average operating voltage 3.2 Volts with an energy density 800 mWh/g for the cathode material, making the newly synthesized material a viable cathode material for secondary magnesium batteries.

An alkaline battery is made by press-fitting a plurality of tubular positive electrode pellets inside of an open end of a cylindrical positive electrode can. The press-fitting is performed in such a manner as to stack the positive electrode pellets coaxially inside of and in contact with the positive electrode can, with gaps between adjacent positive electrode pellets. A separator is disposed inside of the tubular pellets, and a negative electrode mixture is placed inside of the separator. A negative electrode current collector is inserted into the negative electrode mixture, and the opening at the open end of the positive electrode can is sealed with a negative electrode terminal plate.

An alkaline battery is made by press-fitting a plurality of tubular positive electrode pellets inside of an open end of a cylindrical positive electrode can. The press-fitting is performed in such a manner as to stack the positive electrode pellets coaxially inside of and in contact with the positive electrode can, with gaps between adjacent positive electrode pellets. A separator is disposed inside of the tubular pellets, and a negative electrode mixture is placed inside of the separator. A negative electrode current collector is inserted into the negative electrode mixture, and the opening at the open end of the positive electrode can is sealed with a negative electrode terminal plate.

The present invention relates to a metal oxide powder, a method of preparing the same, and a lithium secondary battery using the same, which comprises: a metal oxide powder is represented by Formula (1),
Li.sub.x(M.sub.1-m-zA.sub.mD.sub.z)O.sub.tFormula (1) in the above Formula (1), 0.85x1.2, 0m0.01, 0<z0.04, 1.85t2.2, M is selected from the group consisting of Ni, Co, Mn and combinations thereof, A is selected from the group consisting of Mg, Ca, Sr, Ba and combinations thereof, D is selected from the group consisting of Ti, Zr, Ce, Ge, Sn and combinations thereof, and E is an average oxidation number of A and D, and E>3.5.

Systems and methods which provide a polyacrylamide (PAM) based flexible and rechargeable zinc-ion battery (ZIB) configuration are described. Embodiments of a ZIB configuration comprise a PAM based polymer electrolyte. For example, a ZIB configuration of embodiments may comprise a manganese-dioxide (MnO.sub.2) cathode, a zinc (Zn) anode, and a PAM based polymer electrolyte. The PAM based polymer electrolyte may comprise a PAM based polymer hosting one or more solutions to form a hydrogel electrolyte (e.g., crosslinked polyacrylamide hydrogel electrolyte). For example, the PAM based polymer electrolyte may be configured as a polyelectrolyte matrix host for the one or more solutions, such as may comprise a neutral solution of zinc sulfate and manganese sulfate, to achieve a stable electro chemical performance under the repetitive deformation conditions.

According to one embodiment, an electrode is provided. The active material-containing layer includes an active material, inorganic solid particles having lithium ion conductivity, and carbon fiber. A pore diameter D.sub.M at the first peak is 0.05 m to 10 m. A value SA-SB is 1.4 or more in a slope distribution curve of the active material-containing layer, where a vertical axis of the slope distribution curve represents a slope of a straight line passing through two adjacent measurement points on the log differential pore volume distribution curve and a horizontal axis of the slope distribution curve represents a smaller pore diameter of the two adjacent measurement points. The value SA-SB is obtained by subtracting a minimum slope value SB from a maximum slope value SA.

Systems, articles, and methods generally related to the electrochemical formation of layers comprising halogen ions on substrates are described.

Systems, articles, and methods generally related to the electrochemical formation of layers comprising halogen ions on substrates are described.

Provided are compositions, systems, and methods of making and using pre-lithiated cathodes for use in lithium ion secondary cells as the means of supplying extra lithium to the cell. The chemically or electrochemically pre-lithiated cathodes include cathode active material that is pre-lithiated prior to assembly into an electrochemical cell. The process of producing pre-lithiated cathodes includes contacting a cathode active material to an electrolyte, the electrolyte further contacting a counter electrode lithium source and applying an electric potential or current to the cathode active material and the lithium source thereby pre-lithiating the cathode active material with lithium. An electrochemical cell is also provided including the pre-lithiated cathode, an anode, a separator and an electrolyte.