Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.

Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.

A method of providing an anode composed of a homogeneous solid metallic alloy is provided. The alloy includes 100 ppm to 1000 ppm Bi, 100 ppm to 1000 ppm In, and Zn. The method includes fabricating a cathode in a first cavity in a first dielectric element. The method further includes fabricating an anode in a second cavity in a second dielectric element. The method further includes joining the cathode and the anode in a complanate manner.

A method of providing an anode composed of a homogeneous solid metallic alloy is provided. The alloy includes 100 ppm to 1000 ppm Bi, 100 ppm to 1000 ppm In, and Zn. The method includes fabricating a cathode in a first cavity in a first dielectric element. The method further includes fabricating an anode in a second cavity in a second dielectric element. The method further includes joining the cathode and the anode in a complanate manner.

In the present invention there is provided an MnO.sub.2 electrode with improved electrochemical properties, and a method of preparation of an electrode, wherein there anode comprises a substrate at least partially coated with MnO.sub.2 nanosheets (MnNSs) forming additive free MnO.sub.2 thin films. The method includes providing MnO.sub.2 nanosheets (MnNSs) suspension with diameters less than 50 nm; printing the MnNSs suspension on substrates to form MnO.sub.2 thin films (MnTFs); and annealing the MnTFs at 260-320 C. for at least 100 minutes. Energy storage device comprising the MnO.sub.2 electrode such as a Na-ion cell, and a Li-ion cell are also described.

The present application relates to a method comprising: (a) providing a battery comprising a manganese oxide composition as a primary active material; and (b) cycling the battery by: (i) galvanostatically discharging the battery to a first V.sub.cell; (ii) galvanostatically charging the battery to a second V.sub.cell; and (iii) potentiostatically charging at the second V.sub.cell for a first defined period of time. The present application also relates to a chemical composition produced by the method above. The present application also relates to a battery comprising a chemical composition having an X-ray diffractogram pattern expressing a Bragg peak at about 26, said peak being of greatest intensity in comparison to other expressed Bragg peaks. The present application also relates to a battery comprising one or more chemical species, the one or more chemical species produced by cycling an activated composition.

The present application relates to a method comprising: (a) providing a battery comprising a manganese oxide composition as a primary active material; and (b) cycling the battery by: (i) galvanostatically discharging the battery to a first V.sub.cell; (ii) galvanostatically charging the battery to a second V.sub.cell; and (iii) potentiostatically charging at the second V.sub.cell for a first defined period of time. The present application also relates to a chemical composition produced by the method above. The present application also relates to a battery comprising a chemical composition having an X-ray diffractogram pattern expressing a Bragg peak at about 26, said peak being of greatest intensity in comparison to other expressed Bragg peaks. The present application also relates to a battery comprising one or more chemical species, the one or more chemical species produced by cycling an activated composition.

The present disclosure relates to a positive electrode active material which reduces lithium by-products and improves structural stability and includes a lithium-nickel based transition metal composite oxide in which an alkaline earth metal having oxidation number of +2 is doped and a phosphate coated layer formed on the outer surface of the composite oxide. Accordingly, a second battery including the positive electrode active material has excellent capacity characteristics, and also improves structural stability during charging/discharging and prevents swelling, thereby being capable of exhibiting excellent life characteristics. Therefore, the present invention may be easily applied to industry in need thereof, and particularly to electric vehicles industry requiring high capacity and long-term life characteristics.

Provided are a negative electrode for a rechargeable lithium battery including a negative active material and a conductive material wherein the negative active material includes graphite and an inorganic particle positioned on the surface of the graphite and having no reactivity with lithium, and the conductive material is included in an amount of greater than or equal to about 0.1 wt % and less than about 2 wt % based on the total amount of the negative active material and the conductive material, and a rechargeable lithium battery including the same.

Cell and batteries containing them employing a cathode having a intercalating metal oxide in combination with a sodium metal haloaluminate. At operating temperatures, the positive electrode (cathode) of the invention comprises electroactive cathode material permeated with and in physical and electrical contact with the sodium metal haloaluminate catholyte. The positive and negative electrodes are separated with a solid alkali metal conducting electrolyte. The intercalating metal oxice is not in direct physical contact with the solid electrolyte. Electric and ionic conductivity between the solid electrolyte and the positive electrode is mediated by the sodium haloaluminate catholyte. Batteries of the invention are useful for bulk energy storage, particularly for electric utility grid storage, as well as for electric vehicle propulsion.