This application provides a mixed positive electrode material, a positive electrode plate and a preparation method thereof, a battery, and an apparatus. The mixed positive electrode material includes a mixed component consisting of a material of lithium iron phosphate chemical system and a material of ternary chemical system, where the material of lithium iron phosphate chemical system is secondary particles with an average specific surface area within 10 m.sup.2/g. In the mixed positive electrode material of this application, the introduction of lithium iron phosphate secondary particles having a low specific surface area improves ease of processing of the mixed positive electrode material, making a slurry less prone to agglomeration and the two materials highly miscible. When the positive electrode plate is prepared by using the mixed positive electrode material of this application, uniform distribution of the positive electrode material on the positive electrode plate can be effectively improved.

A positive electrode (1) for non-aqueous electrolyte secondary batteries, including collector (11) and active material layer (12), wherein: integrated value (a) is 3 to 15% (for frequency of diameters of 1 μm or less), and frequency (b) is 8 to 20% (for diameter with a maximum frequency). A positive electrode (1) for non-aqueous electrolyte secondary batteries, including collector (11) and active material layer (12), wherein assuming two directions perpendicular to thickness direction of collector (11) and mutually orthogonal as first and second directions, average thickness a1, maximum thickness b1, minimum thickness c1 in thickness distribution in the first direction, and thickness d1 (largest absolute value of difference from a1) satisfy 0.990≤(d1/a1)≤1.010 and (b1−c1)≤5.0 μm, and average thickness a2, maximum thickness b2, minimum thickness c2 in thickness distribution in the second direction, and thickness d2 (largest absolute value of difference from a2) satisfy 0.990≤(d2/a2)≤1.010 and (b2−c2)≤5.0 μm.

A method for producing an electrode material for a lithium-ion secondary battery. The method includes the following steps: (a) mixing components of a basic ingredient or active substance of electrode material and a conductive carbon material to obtain a conductive carbon material-composited material; (b) mixing the conductive carbon material-composited material and a surface layer-forming material; an (c) burning the mixture obtained at step (b) to obtain the electrode material. Also, a lithium-ion secondary battery including an electrode which includes the material.

The invention relates to composite multilayer lithium ion battery anodes that include a porous metal alloy foam, and a lithium ion conductor coating applied to the metal alloy foam. The metal alloy foam can include structurally isomorphous alloys of lithium and, optionally, lithium and magnesium. The lithium ion conductor coating can include ternary lithium silicate, such as, lithium orthosilicate. Lithium ions from the ternary lithium silicate may be deposited within the pores of the metal alloy foam. Optionally, the lithium ion conductor coating may include a dopant. The dopant can include one or more of magnesium, calcium, vanadium, niobium and fluorine, and mixtures and combinations thereof.

Provided are an electrolytic solution suitable for a lithium ion secondary battery that includes a positive electrode which has a positive electrode active material having an olivine structure, and includes a negative electrode having graphite as a negative electrode active material, and a superior lithium ion secondary battery having the electrolytic solution. The lithium ion secondary battery includes: a positive electrode that includes a positive electrode active material having an olivine structure; a negative electrode having graphite as a negative electrode active material; and an electrolytic solution. The electrolytic solution contains LiPF.sub.6, a cyclic alkylene carbonate selected from ethylene carbonate and propylene carbonate, methyl propionate, and an additive that starts reductive degradation at a potential higher than a potential at which the above components of the electrolytic solution start reductive degradation.

The present invention generally relates to electrolytes for use in various electrochemical devices. In some cases, the electrolytes are relatively safe to use; for example, the electrolytes may be resistant to overheating, catching on fire, burning, exploding, etc. In some embodiments, such electrolytes may be useful for certain types of high-voltage cathode materials. In some cases, the electrolytes may include ion dissociation compounds that can dissociate tight ion pairs. Non-limiting examples of ion dissociation compounds include trialkyl phosphates, sulfones, or the like. Other aspects of the invention are generally directed to devices including such electrolytes, methods of making or using such electrolytes, kits including such electrolytes, or the like.

The present disclosure relates to an anode electrode active material for a secondary battery containing nickel cobalt molybdenum oxide, an anode electrode for a secondary battery including the same, a secondary battery including the anode electrode for a secondary battery, and a method for manufacturing the same. The novel anode electrode material for a sodium secondary battery containing nickel cobalt molybdenum oxide according to the present disclosure allows intercalation/deintercalation reaction of sodium ion during charge/discharge and does not undergo significant volume change during the intercalation reaction because structure is maintained stably during repeated charge/discharge. As a result, electrode damage and electric short circuit are decreased and, thus, improved electrochemical characteristics can be achieved in long-life and high-rate capability.

Lithium ion batteries and electrolytes therefor are provided, which include electrolyte additives having dithioester functional group(s) that stabilize the SEI (solid-electrolyte interface) at the surfaces of the anode material particles, and/or stabilize the CEI (cathode electrolyte interface) at the surfaces of the cathode material particles, and/or act as oxygen scavengers to prevent cell degradation. The electrolyte additives having dithioester functional group(s) may function as polymerization controlling and/or chain transfer agents that regulate the level of polymerization of other electrolyte components, such as VC (vinyl carbonate) and improve the formation and operation of the batteries. The lithium ion batteries may have metalloid-based anodes including mostly Si, Ge and/or Sn as anode active material particles.

The present technology relates to a positive electrode for a lithium secondary battery and a lithium secondary battery including the positive electrode. The positive electrode includes: a safety function layer arranged on a positive electrode current collector; and a positive electrode mixture layer arranged on the safety function layer. Herein, the safety function layer is formed of a multi-layer structure of two or more layers including a first safety function layer contacting the positive electrode current collector, and a second safety function layer arranged on the first safety function layer, and the second safety function layer is obtained by mixing a composition of the first safety function layer with a composition of the positive electrode mixture layer.

A rechargeable lithium battery includes a positive electrode including a positive active material layer; a negative electrode including a negative active material layer;

and an electrolyte solution including a non-aqueous organic solvent, a lithium salt, and an additive, wherein the positive active material layer includes a positive active material and carbon nanotubes, the carbon nanotubes are greater than about 0.1 wt % and less than about 3.0 wt % in amount based on a total weight of the positive active material layer, and the additive includes a compound represented by Chemical Formula 1.

##STR00001##

Details of Chemical Formula 1 are as described in the specification.