This invention relates to a double layer composite-coated nano-silicon negative electrode material, and its preparation methods and use, the negative electrode material comprising: a silicon-based nanoparticle, a copper layer coated on the surface of the silicon-based nanoparticle, and a conductive protective layer coated on the surface of the copper layer. Nano-copper has superplastic ductility and conductivity, and the prior art has proved that lithium ions can penetrate nano-copper; therefore, the copper coating layer has effects of inhibiting the volume expansion of the silicon-based nanoparticle and keeping the silicon-based nanoparticle from cracking so that direct contact between the silicon-based nanoparticle and an electrolyte is effectively avoided and a stable SEI is formed, and increasing the conductivity of the electrode. The surface of the nano-copper is coated with a further conductive protective layer to effectively inhibit the oxidation of the nano-copper, thereby improving the electrochemical performance.

An anode for a lithium-based energy storage device such as a lithium-ion battery is disclosed. The anode includes an electrically conductive current collector comprising an electrically conductive layer and a transition metal oxide layer overlaying the electrically conductive layer. The anode may include a continuous porous lithium storage layer provided over the transition metal oxide layer. The continuous porous lithium storage layer may include at least 40 atomic % silicon. A method of making the anode may include providing an electrically conductive current collector having an electrically conductive layer and a transition metal oxide layer provided over the electrically conductive layer. The transition metal oxide layer may have an average thickness of at least 0.05 μm. A continuous porous lithium storage layer is deposited over the transition metal oxide layer by PECVD.

An electrode structure, a positive electrode and an electrochemical device including the same, and a method of preparing the electrode structure. The electrode structure includes a current collector; and an electrode active material layer on a surface of the current collector, wherein the electrode active material layer includes an electrode active material and an opening penetrating through the electrode active material layer; and a conductive layer comprising a conductive material and a binder on an inner surface of the opening, and wherein the content of the conductive material and the binder is 0.05% to 3% by weight on the basis of the total weight of the electrode active material layer.

The present disclosure relates to an electrochemical cell having an elastic binding polymer that improves long-term performance of the electrochemical cell, particularly when the electrochemical cell includes an electroactive material that undergoes volumetric expansion and contraction during cycling of the electrochemical cell (such as, silicon-containing electroactive materials). The electrochemical cell can include the elastic binding polymer as an electrode additive and/or a coating layer disposed adjacent to an exposed surface of an electrode that includes an electroactive material that undergoes volumetric expansion and contraction and/or a gel layer disposed adjacent to an electrode that includes an electroactive material that undergoes volumetric expansion and contraction. The elastic binding polymer may include one or more alginates or alginate derivatives and at least one crosslinker.

An asymmetric hybrid electrode for a capacitor-assisted battery includes a current and first and second electroactive portions. The first electroactive portion is on a first surface of the current collector. The first electroactive portion includes a first battery layer. The first battery layer includes a first battery electroactive material and a first binder. The second electroactive portion is on a second surface of the current collector opposite the first surface. The second electroactive portion includes a second battery layer and a capacitive layer. The second battery layer includes a second battery electroactive material and a second binder. The capacitive layer includes a capacitive electroactive material and a third binder. The first and second electroactive portions are asymmetric. The first and second battery electroactive materials are both positive electroactive materials or both negative electroactive materials. The asymmetric hybrid electrode has a capacitor hybridization ratio of 0.01-1%.

Influence of expansion and shrinkage of an electrode of an electrical storage device can be reduced, and battery characteristics thereof are maintained. The electrode of the electrical storage device contains: a metal fiber; an adsorbing substance powder or an active substance powder contacted with the metal fiber, the adsorbing substance powder being an adsorbing substance powder which adsorbs electrolyte ions during charging and discharging, and the active substance powder being an active substance powder which is subjected to a chemical reaction during charging and discharging; and a powdery solid electrolyte contacted with the metal fiber.

The present application relates to a positive electrode plate, an electrochemical device and a safety coating. The positive electrode plate comprises a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, the safety coating comprising a fluorinated polyolefin and/or chlorinated polyolefin polymer matrix, a conductive material and an inorganic filler. The positive electrode plate can quickly disconnect circuit when the electrochemical device (such as a capacitor, primary battery, or secondary battery, and the like) is in a high temperature condition or an internal short circuit occurs, thereby improving high temperature safety performance of the electrochemical device.

Electroactive materials having a nitrogen-containing carbon coating and composite materials for a high-energy-density lithium-based, as well as methods of formation relating thereto, are provided. The composite electrode material includes a silicon-containing electroactive material having a substantially continuous nitrogen-containing carbon coating formed thereon. The method includes contacting the silicon-containing electroactive material and one or more nitrogen-containing precursor materials and heating the mixture. The one or more nitrogen-containing precursor materials include one or more nitrogen-carbon bonds and during heating the nitrogen of the one or more nitrogen-carbon bonds with silicon in the silicon-containing electroactive material to form the nitrogen-containing carbon coating on exposed surfaces of the silicon-containing electroactive material.

A negative electrode and an electrochemical cell are provided herein. The negative electrode and the electrochemical cell include a protective coating for preventing and inhibiting growth of lithium dendrite on the negative electrode and growth into a separator. The protective coating includes a first layer and second layer. The first layer includes a first polymeric binder and an optional insulating material. The second layer includes a dendrite consuming material and a second polymeric binder.

The present application relates to an anode, and an electrochemical device and an electronic device comprising the same. Embodiments of the present application provided an anode comprising: a current collector, a first anode structure layer and a second anode structure layer. The first anode structure layer comprises a first framework material and the second anode structure layer comprises a second framework material, wherein the first anode structure layer is disposed between the current collector and the second anode structure layer, and the first framework material has a higher oxidation-reduction potential for lithium ion or electronic conductivity than the second framework material. When the anode with double-layer structure provided by the present application is charged, the space utilization ratio of the anode can be enhanced, the rate capability of the electrochemical device can be enhanced, the formation of lithium dendrites may be inhibited, and the volume change amount of the anode can be reduced, thereby enhancing the safety performance and cycle performance of the electrochemical device.