An electrode for a power storage device includes a non-woven fabric current collector that comprises short fibers of aluminum or copper having an average length of 25 mm or less; and adsorbent material powder on which electrolyte ions are adsorbed during charging or active material powder which chemically react during charging and discharging, where the powder exists in the gaps formed between the short fibers of the non-woven fabric current collector.

An electrochemical apparatus includes a first electrode plate, a second electrode plate, a first separator, and a second separator, the first separator includes a first porous substrate, the second electrode plate includes a second porous substrate, and the first electrode plate, the first separator, the second electrode plate and the second separator are stacked in sequence to form an electrode assembly; and at least one surface of the first porous substrate is provided with a polymer bonding layer, and at least one surface of the second porous substrate is provided with no polymer bonding layer. A new electrode assembly structure separate a positive electrode plate and a negative electrode plate through a first separator provided with a polymer binder, which is beneficial to shape the electrode assembly and release a stress at corner, thereby inhibiting deformation of the electrochemical apparatus.

Electrodes and methods of creating co-continuous composite electrodes based on a highly porous current collector are provided. In one embodiment, a method for creating an electrode includes depositing a thin layer of material on the polymer template, removing polymer material of the polymer template and depositing a second material. The method may also include controlling internal surface area per unit volume and the active material thickness of at least the second material to tune the electrochemical performance of the electrode. In one embodiment, a composite electrode is provided including interpenetrating phases of a metal current collector, electrolytically active phase, and electrolyte.

Electrodes and methods of creating co-continuous composite electrodes based on a highly porous current collector are provided. In one embodiment, a method for creating an electrode includes depositing a thin layer of material on the polymer template, removing polymer material of the polymer template and depositing a second material. The method may also include controlling internal surface area per unit volume and the active material thickness of at least the second material to tune the electrochemical performance of the electrode. In one embodiment, a composite electrode is provided including interpenetrating phases of a metal current collector, electrolytically active phase, and electrolyte.

Provided are an electrode for lithium ion secondary batteries which can prevent cracking of the electrode, and a lithium ion secondary battery made using the same. An electrode (1, 2) for a lithium ion secondary battery (100) includes a collector (10, 20) of a metal porous body having a predetermined thickness, and having a corner of at least one location in a stereoscopic view; and an electrode mixture (18, 28) filled into these pores. The collector has a mixture filled region (11, 21) in which the electrode mixture is filled, and a mixture non-filled region (15, 25) in which the electrode mixture is not filled, or a high modulus filler having smaller elastic modulus than the electrode mixture is filled, existing at a corner of the collector.

To provide a lithium ion secondary battery that allows the cell state to be monitored by arranging a reference electrode, even in a solid-state battery. In a lithium ion secondary battery 50, a positive electrode 1, a reference electrode 3, and a negative electrode 2 are arranged in this sequence. The positive electrode 1 includes a first current collector 11 including a metal porous body, and a first electrode material mixture 15 with which pores of the first current collector 11 are filled. The negative electrode 2 includes a second current collector 21 including a metal porous body, and a second electrode material mixture 25 with which pores of the second current collector 21 are filled. The reference electrode 3 includes a third current collector 31 including a metal porous body, and a solid electrolyte 35 with which pores of the third current collector 31 are filled.

To provide a lithium ion secondary battery that allows the cell state to be monitored by arranging a reference electrode, even in a solid-state battery. In a lithium ion secondary battery 50, a positive electrode 1, a reference electrode 3, and a negative electrode 2 are arranged in this sequence. The positive electrode 1 includes a first current collector 11 including a metal porous body, and a first electrode material mixture 15 with which pores of the first current collector 11 are filled. The negative electrode 2 includes a second current collector 21 including a metal porous body, and a second electrode material mixture 25 with which pores of the second current collector 21 are filled. The reference electrode 3 includes a third current collector 31 including a metal porous body, and a solid electrolyte 35 with which pores of the third current collector 31 are filled.

The present disclosure provides a solid-state bipolar battery that includes negative and positive electrodes having thicknesses between about 100 μm and about 3000 μm, and a solid-state electrolyte layer disposed between the negative electrode and the positive electrode and having a thickness between about 5 μm and about 100 μm. The first electrode includes a plurality of negative solid-state electroactive particles embedded on or disposed within a first porous material. The second electrode includes plurality of positive solid-state electroactive particles embedded on or disposed within a second porous material that is the same or different from the first porous material. The solid-state bipolar battery includes a first current collector foil disposed on the first porous material, and a second current collector foil disposed on the second porous material. The first and second current collector foils may each have a thickness less than or equal to about 10 μm.

An electrode includes a soft substrate, a metal layer in direct contact with the soft substrate, and a lithium layer formed directly on the metal layer, wherein the metal layer comprises wrinkles. The wrinkles are of a substantially uniform height, and the height is in a range of 100 nm to 20 μm. The wrinkles are typically separated by a substantially uniform distance, and the distance is in a range of 100 nm to 1000 μm. The wrinkles may be one dimensional or two dimensional. Fabricating an electrode includes forming a metal layer on a soft substrate, and forming a lithium layer on the metal layer. Forming the lithium layer on the metal layer yields uniform wrinkles in the metal layer. A battery may include the electrode as described.

An assembly of lithium-based solid anodes to be formed into a lithium-ion battery. The anodes are formed with a fibrous ceramic or polymer framework having open spaces and an active surface material having lithiophilic properties. Open spaces within the fibrous framework and lithiophilic coatings deposited upon the surface of the fibrous framework allow for the free transport of solid lithium-ions within the anodes. In solid-state, lithium batteries can achieve higher capacity per weight, charge faster, and be more durable to extreme handling and temperature. A method for manufacturing a solid-state lithium battery having such an anode.