When a layered rock-salt type cathode active material and a sulfide solid electrolyte are mixed to be a cathode mixture, and an all solid-state battery is obtained using this mixture, oxygen is released from the cathode active material when the battery is charged, and the sulfide solid electrolyte is oxidized, increasing the battery internal resistance. To increase the concentration of cobalt inside the active material, and at the same time to lower the concentration of cobalt of the surface of the cathode active material, to suppress oxygen release in charging, specifically, a cathode mixture includes: a cathode active material; and a sulfide solid electrolyte, wherein the cathode active material has a layered rock-salt crystal phase, and is made of a composite oxide containing Li, Ni, Co, and Mn, and the concentration of cobalt inside the cathode active material is higher than that of a surface of the cathode active material.

Disclosed are an all-solid-state battery having high energy density and a method for manufacturing the same. One battery structure is pressed instead of pressing each cell unit, an amount of first or second electrode current collectors consumed is reduced, and insulating members are used, thereby simplifying a manufacturing process of the all-solid-state battery and allowing the all-solid-state battery to have high energy density and a stable structure.

Disclosed are an all-solid-state battery having high energy density and a method for manufacturing the same. One battery structure is pressed instead of pressing each cell unit, an amount of first or second electrode current collectors consumed is reduced, and insulating members are used, thereby simplifying a manufacturing process of the all-solid-state battery and allowing the all-solid-state battery to have high energy density and a stable structure.

A diagnostic device for a secondary battery which is an all-solid-state battery containing a solid electrolyte transporting lithium ions, in which the diagnostic device includes: an interruption means configured to interrupt a charging current or a discharging current of the secondary battery connected to a circuit; a measuring means configured to measure over time a variation characteristic of a terminal voltage of the secondary battery after the current is interrupted by the interruption means; and a diagnostic means configured to diagnose the cause of the degradation of the secondary battery by comparing a change rate or a change amount in voltage between a charging characteristic specified from measured values of a terminal voltage of the secondary battery measured by the measuring means, a charging/discharging characteristic specified from the measured values of the terminal voltage measured by the measuring means, and a reference characteristic of the secondary battery.

A diagnostic device for a secondary battery which is an all-solid-state battery containing a solid electrolyte transporting lithium ions, in which the diagnostic device includes: an interruption means configured to interrupt a charging current or a discharging current of the secondary battery connected to a circuit; a measuring means configured to measure over time a variation characteristic of a terminal voltage of the secondary battery after the current is interrupted by the interruption means; and a diagnostic means configured to diagnose the cause of the degradation of the secondary battery by comparing a change rate or a change amount in voltage between a charging characteristic specified from measured values of a terminal voltage of the secondary battery measured by the measuring means, a charging/discharging characteristic specified from the measured values of the terminal voltage measured by the measuring means, and a reference characteristic of the secondary battery.

A method of preparing an elongate web of sheet material for dividing into discrete stacks of web portions after reeling the web onto a drum is provided. The method includes forming transverse discontinuities in the web at spaced intervals corresponding to edges of the discrete stacks to be formed, the intervals progressively increasing along the web so that the discontinuities form angularly-aligned groups when reeled onto the drum.

Thin-film batteries that include a novel encapsulation system.

Disclosed are a solid electrolyte material including a naturally abundant element as a base, having lithium ion conductivity equal or superior to those of conventional sulfide solid electrolyte materials, being relatively inexpensive, and having a crystal structure, a manufacturing method thereof, and a battery using the same. The solid electrolyte material may include a naturally abundant element as a base, have lithium ion conductivity equal or superior to those of conventional sulfide solid electrolyte materials, be relatively inexpensive, and have a crystal structure. The sulfide solid electrolyte material includes a sulfide compound represented by a formula of Li.sub.2−4x−ySi.sub.1+x−yP.sub.yS.sub.3, and x and y satisfy conditions −0.040≤x≤0.095 and 0.036≤y≤0.192.

Disclosed are a solid electrolyte material including a naturally abundant element as a base, having lithium ion conductivity equal or superior to those of conventional sulfide solid electrolyte materials, being relatively inexpensive, and having a crystal structure, a manufacturing method thereof, and a battery using the same. The solid electrolyte material may include a naturally abundant element as a base, have lithium ion conductivity equal or superior to those of conventional sulfide solid electrolyte materials, be relatively inexpensive, and have a crystal structure. The sulfide solid electrolyte material includes a sulfide compound represented by a formula of Li.sub.2−4x−ySi.sub.1+x−yP.sub.yS.sub.3, and x and y satisfy conditions −0.040≤x≤0.095 and 0.036≤y≤0.192.

A hybrid solid electrolyte particulate for use in a rechargeable lithium battery cell, wherein said particulate comprises one or more than one inorganic solid electrolyte particles encapsulated by a shell of elastic polymer electrolyte wherein (i) the hybrid solid electrolyte particulate has a lithium-ion conductivity from 10.sup.−6 S/cm to 5×10.sup.−2 S/cm and both the inorganic solid electrolyte and the elastic polymer electrolyte individually have a lithium-ion conductivity no less than 10.sup.−6 S/cm; (ii) the elastic polymer electrolyte-to-inorganic solid electrolyte ratio is from 1/100 to 100/1 or the elastic polymer electrolyte shell has a thickness from 1 nm to 10 μm; and (iii) the elastic polymer electrolyte has a recoverable elastic tensile strain from 5% to 1,000%. Also provided is a lithium-ion or lithium metal cell containing multiple hybrid solid electrolyte particulates in the anode, cathode and/or the separator. Processes for producing hybrid solid electrolyte particulates are also disclosed.