The present invention aims to provide a lithium ion-conducting oxide capable of providing a solid electrolyte with an excellent ion conductivity, and a solid electrolyte, a sintered body, an electrode material or an electrode and an all-solid-state battery using the same. The lithium ion-conducting oxide of the present invention includes at least lithium, tantalum, phosphorus, silicon, and oxygen as constituent elements, has a peak in a region of −20.0 ppm to 0.0 ppm on the solid-state .sup.31P-NMR spectrum, and has a peak in a range of −80.0 ppm to −100.0 ppm on the solid-state .sup.29Si-NMR spectrum.

The present invention aims to provide a lithium ion-conducting oxide capable of providing a solid electrolyte with an excellent ion conductivity, and a solid electrolyte, a sintered body, an electrode material or an electrode and an all-solid-state battery using the same. The lithium ion-conducting oxide of the present invention includes at least lithium, tantalum, phosphorus, silicon, and oxygen as constituent elements, has a peak in a region of −20.0 ppm to 0.0 ppm on the solid-state .sup.31P-NMR spectrum, and has a peak in a range of −80.0 ppm to −100.0 ppm on the solid-state .sup.29Si-NMR spectrum.

This application relates to secondary lithium-sulfur batteries with electrolyte comprising a metal di-cation.

The present invention provides a solid-state battery with high energy density and excellent cycle property, and a production method therefor. The production method for this solid-state battery, which contains a positive electrode, a solid electrolyte, and a negative electrode, comprises the steps of: preparing a negative electrode that is free of a negative-electrode active material; and forming, on at least one surface of the negative electrode, a solid electrolyte interface layer including a lithium-containing organic compound and a lithium-containing inorganic compound by immersing the negative electrode in a layer forming solution containing a lithium salt and a precursor and thereafter causing a reduction reaction on the surface of the negative electrode.

A solid electrolyte material according to the present disclosure is represented by the following composition formula (1), Li.sub.aAl.sub.bO.sub.cX.sub.d . . . Formula (1) where values a, b, c, and d are each greater than 0, and X is at least one selected from the group consisting of CI and Br. A battery according to the present disclosure includes a positive electrode, a negative electrode and an electrolyte layer disposed between the positive electrode and the negative electrode. At least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer includes the solid electrolyte material according to the present disclosure.

A solid electrolyte material according to the present disclosure is represented by the following composition formula (1), Li.sub.aAl.sub.bO.sub.cX.sub.d . . . Formula (1) where values a, b, c, and d are each greater than 0, and X is at least one selected from the group consisting of CI and Br. A battery according to the present disclosure includes a positive electrode, a negative electrode and an electrolyte layer disposed between the positive electrode and the negative electrode. At least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer includes the solid electrolyte material according to the present disclosure.

The solid electrolyte material of the present disclosure is made of Li, Ca, Y, Gd, X, and O, where X is at least one selected from the group consisting of F, Cl, Br, and I; and the molar ratio of O to the sum of Y and Gd is greater than O and 0.51 or less.

The solid electrolyte material of the present disclosure is made of Li, Ca, Y, Gd, X, and O, where X is at least one selected from the group consisting of F, Cl, Br, and I; and the molar ratio of O to the sum of Y and Gd is greater than O and 0.51 or less.

A battery includes an electrode layer, a counter-electrode layer placed opposite to the electrode layer, and a solid electrolyte layer located between the electrode layer and the counter-electrode layer. The electrode layer includes a collector, an electrode active material layer located between the collector and the solid electrolyte layer, and an insulating layer located between the collector and the solid electrolyte layer and bonded to the collector at ends of the electrode layer. The electrode active material layer has a region that does not overlap the insulating layer in plan view. The battery has an air gap, the air gap being located between the collector and the solid electrolyte layer and being contact with the insulating layer.

A solid electrolyte (10) of the present disclosure includes porous silica (11) having a plurality of pores (12) interconnected mutually and an electrolyte (13) coating inner surfaces of the plurality of pores (12). The electrolyte (13) includes 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide represented by EMI-TFSI and a lithium salt dissolved in the EMI-TFSI. A molar ratio of the EMI-TFSI to the porous silica (11) is larger than 1.5 and less than 2.0.