A non-aqueous electrolyte secondary battery including a positive electrode, a separator, a negative electrode facing the positive electrode, with the separator interposed; and a liquid electrolyte. The positive electrode includes a composite oxide containing lithium as a first metal, and a second metal other than lithium. In the composite oxide, the second metal contains Ni, a content of Ni in the second metal is 90 at % or more, and a content of Co in the second metal is 10 at % or less. The liquid electrolyte contains at least one cation X selected from the group consisting of Na.sup.+, K.sup.+, Rb.sup.+, Cs.sup.+, Fe, Mg.sup.2+, Ca.sup.2+, Sr.sup.2+, Ba.sup.2+, and Al.sup.3+, and an oxalate complex anion Y.

A non-aqueous electrolyte secondary battery including a positive electrode, a separator, a negative electrode facing the positive electrode, with the separator interposed; and a liquid electrolyte. The positive electrode includes a composite oxide containing lithium as a first metal, and a second metal other than lithium. In the composite oxide, the second metal contains Ni, a content of Ni in the second metal is 90 at % or more, and a content of Co in the second metal is 10 at % or less. The liquid electrolyte contains at least one cation X selected from the group consisting of Na.sup.+, K.sup.+, Rb.sup.+, Cs.sup.+, Fe, Mg.sup.2+, Ca.sup.2+, Sr.sup.2+, Ba.sup.2+, and Al.sup.3+, and an oxalate complex anion Y.

The application relates to a battery module, a manufacturing method and a manufacturing device thereof, a battery pack and a power consumption apparatus. The battery module includes a first-type battery cell and a second-type battery cell having different chemical systems and being electrically connected at least in series, where under the conditions of 25° C. and 100% state of charge (SOC), specific power density P.sub.2 of the second-type battery cell is higher than specific power density P.sub.1 of the first-type battery cell. Satisfying: 0.04≤(r.sub.1/m)/(r.sub.2/n)≤14, where, r.sub.1 and r.sub.2 are resistances per unit area of a positive electrode plate of the first-type battery cell and a positive electrode plate of the second-type battery cell respectively, and m and n are numbers of laminations of the positive electrode plate of the first-type battery cell and the positive electrode plate of the second-type battery cell.

A non-aqueous electrolyte secondary cell according to the present invention comprises: an electrode body constituted by a plurality of positive electrodes and a plurality of negative electrodes alternately layered one by one with separators interposed therebetween; a non-aqueous electrolyte solution; and a case that houses the electrode body and the non-aqueous electrolyte solution. A solution injection port for injecting the electrolyte solution is provided in the case. The density of a first region separated from the solution injection port is less than the density of a second region, which is near the solution injection port, in positive electrode compound layers of the positive electrodes and/or negative electrode compound layers of the negative electrodes constituting the electrode body.

Provided is a battery pack having excellent energy density and durability. A battery pack 100 includes solid-state battery modules 102 each configured such that a plurality of solid-state battery cells containing a solid electrolyte is stacked and electrolytic solution-based battery modules 32 each configured such that a plurality of electrolytic solution-based battery cells containing an electrolytic solution is stacked, the solid-state battery modules 102 and the electrolytic solution-based battery modules 32 being combined and housed in the pack. The solid-state battery modules 102 are arranged to surround the electrolytic solution-based battery modules 32.

Improved electrolytes for lithium-based cells can include a dual salt combination of lithium hexafluorophosphate and lithium bis(fluorosulfonyl)imide or lithium bis(trifluoro-methanesulfonyl)imide, and a solvent that includes dimethyl carbonate, ethylmethyl carbonate and 5 to 25 volume percent of fluoroethylene carbonate. The improved electrolytes can include additives triethyl phosphate, ethoxy(pentafluoro)cyclotriphosphazene, 1,3-propane sultone, or mixtures thereof, and have small limited amounts of additional cosolvents and/or lithium-free organic additives. The improved electrolytes can be used to prepare lithium-based cells with silicon-based active materials as negative electrodes and nickel rich lithium metal oxides as positive electrodes. The lithium-based cells can achieve high energy, high power, fast charge and long cycle life along with good thermal stability.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the content X of the nitrile compound and the content Y of the trinitrile compound meet the conditions represented by Formula (1) and Formula (2): {about 2 wt %≤(X+Y)≤about 11 wt % . . . (1), about 0.1≤(X/Y)≤about 8 . . . (2)}. The electrolyte further includes at least one selected from the group consisting of a cyclic carbonate ester having a carbon-carbon double bond, a fluorinated chain carbonate ester, a fluorinated cyclic carbonate ester, and a compound having a sulfur-oxygen double bond. The electrolyte is capable of effectively inhibiting the increase in DC internal resistance of an electrochemical device so that the electrochemical device has excellent cycle and storage performance.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the content X of the nitrile compound and the content Y of the trinitrile compound meet the conditions represented by Formula (1) and Formula (2): {about 2 wt %≤(X+Y)≤about 11 wt % . . . (1), about 0.1≤(X/Y)≤about 8 . . . (2)}. The electrolyte further includes at least one selected from the group consisting of a cyclic carbonate ester having a carbon-carbon double bond, a fluorinated chain carbonate ester, a fluorinated cyclic carbonate ester, and a compound having a sulfur-oxygen double bond. The electrolyte is capable of effectively inhibiting the increase in DC internal resistance of an electrochemical device so that the electrochemical device has excellent cycle and storage performance.

Provided is a secondary battery comprising: an electrode assembly; a battery case which accommodates the electrode assembly; a first electrolyte which is accommodated in the battery case and primarily impregnates the electrode assembly; and a reinforcement electrolyte member which comprises a packaging material and a second electrolyte, wherein the packaging material is accommodated in the battery case and provided with an oxidation part which is oxidized and decomposed at a set voltage, and the second electrolyte is stored in the packaging material, released to the outside of the packaging material due to the decomposition of the oxidation part, and secondarily impregnates the electrode assembly.

An electrochemical apparatus includes an electrode plate, where the electrode plate has a current collector and an active material layer disposed on at least one surface of the current collector, the active material layer has at least one pore, and an included angle between an axial direction of the at least one pore and a plane on which a surface of the active material layer lies is θ, where θ°≤θ<90°. This improves efficiency of the electrode plate in infiltration and absorption of the electrolyte, thereby improving rate performance, cycling performance, safety, stability, and other qualities of the electrochemical apparatus.