A solid electrolyte interface is formed on a silicon monoxide electrode in a battery cell. While the solid electrolyte interface is being formed on the silicon monoxide electrode, the battery cell is charged for one or more initial cycles.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein about 2.2 wt %≤(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 6, 1 wt %≤Y<5 wt %, about 5 wt %≤Z≤about 50 wt %, and about 0.02<(Y/Z)≤about 0.3. The electrolyte further includes at least one selected from the group consisting of a cyclic carbonate ester having a carbon-carbon double bond, a fluorinated chain carbonate ester, a fluorinated cyclic carbonate ester, and a compound having a sulfur-oxygen double bond.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein about 2.2 wt %≤(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 6, 1 wt %≤Y<5 wt %, about 5 wt %≤Z≤about 50 wt %, and about 0.02<(Y/Z)≤about 0.3. The electrolyte further includes at least one selected from the group consisting of a cyclic carbonate ester having a carbon-carbon double bond, a fluorinated chain carbonate ester, a fluorinated cyclic carbonate ester, and a compound having a sulfur-oxygen double bond.

An aspect of the present invention is a nonaqueous electrolyte energy storage device including: a negative electrode including a negative active material layer with a thickness expansion rate of 10% or more due to charge; and a separator, in which the absolute value (|dR/dP|) of an increase in resistance (dR) to a change in pressure (dP) in pressurization is 0.15 Ω.Math.cm.sup.2/MPa or less in the separator impregnated with a measurement electrolyte solution, the measurement electrolyte solution contains an ethylene carbonate and an ethyl methyl carbonate as a solvent, and a lithium hexafluorophosphate as an electrolyte salt, the volume ratio between the ethylene carbonate and the ethyl methyl carbonate is 30:70, and the concentration of the lithium hexafluorophosphate is 1.0 mol/L.

The present disclosure is directed to providing an electrolyte solution with a long cycle life by suppressing degradation of the battery characteristics under the high temperature condition. There is provided a nonaqueous electrolyte solution comprising a compound comprising 5 to 20 mass % of nitrogen atoms and 25 to 70 mass % of sulfur atoms or oxygen atoms in a molecule and having no disulfide bond in the molecule, wherein the compound comprises at least two sulfur atoms or oxygen atoms in the molecule.

Solid-polymer electrolytes, methods of making solid-polymer electrolytes, and uses of solid-polymer electrolytes. A solid-polymer electrolyte comprises a cross-linked polymer network. A cross-linked polymer network may comprise a plurality of groups, which may be cross-linked groups, such as, for example, cross-linked difunctional polyether groups, cross-linked difunctional ionic groups, non-crosslinked groups, which may be referred to as “dangling” groups, or a combination thereof, and a plurality of cross-linked multifunctional crosslinker groups. A solid polymer electrolyte can be formed by polymerization. A solid polymer electrolyte can be formed in situ in a device. A solid polymer electrolyte can be used in devices such as, for example, batteries, supercapacitors, fuel cells, and the like.

Solid-polymer electrolytes, methods of making solid-polymer electrolytes, and uses of solid-polymer electrolytes. A solid-polymer electrolyte comprises a cross-linked polymer network. A cross-linked polymer network may comprise a plurality of groups, which may be cross-linked groups, such as, for example, cross-linked difunctional polyether groups, cross-linked difunctional ionic groups, non-crosslinked groups, which may be referred to as “dangling” groups, or a combination thereof, and a plurality of cross-linked multifunctional crosslinker groups. A solid polymer electrolyte can be formed by polymerization. A solid polymer electrolyte can be formed in situ in a device. A solid polymer electrolyte can be used in devices such as, for example, batteries, supercapacitors, fuel cells, and the like.

Provided are: a lithium-ion secondary battery electrode with which it is possible to realize a battery having high volume energy density and in which capacity reduction due to repeated charging and discharging is suppressed even when the amount of electrolytic solution held by the electrode is low; a lithium-ion secondary battery using said electrode; and a method for manufacturing the lithium-ion secondary battery electrode. A lithium-ion secondary battery electrode in which a highly dielectric oxide solid and the electrolytic solution are positioned in the gaps between active material particles of an electrode mixture layer, wherein: the electrode mixture layer is prepared without using water that is reactive with the highly dielectric oxide solid; and the arrangement of the highly dielectric oxide solid in the electrode mixture layer is specified.

A method for manufacturing a battery includes: accommodating a stacked electrode body, in which a separator that has an adhesive layer and an electrode plate are stacked and the electrode plate is bonded to the separator via the adhesive layer, in a case; injecting an electrolytic solution into the case; and reducing the adhesive strength between the electrode plate and the separator at the same time, or around the same time, as the injection of the electrolytic solution.

An electrolyte, an electrochemical device containing same, and an electronic device. Specifically, an electrolyte, including dimethyl carbonate, ethyl methyl carbonate, and lithium bis(oxalato)borate. The ethyl methyl carbonate and the lithium bis(oxalato)borate each account for a specified weight percent in the electrolyte, and the weight percent of the dimethyl carbonate and the weight percent of the ethyl methyl carbonate in the electrolyte meet a specified relationship. The electrolyte provides with balanced rate performance, the low-temperature discharge performance, and the high-temperature storage and cycle performance of the electrochemical device, and helps to achieve excellent comprehensive performance of the electrochemical device.