An ion-selective electrode includes: an ion-sensitive layer containing an ion-sensitive substance; and a solid, in which at least a part of a surface of the solid is coated with the ion-sensitive layer, the ion-sensitive substance has a crown ether structure formed of at least two or more repeating units represented by Formula (a):

—CR.sup.1R.sup.2—CR.sup.3X—O—  (a) where X is an organic group having an alkoxysilyl group at a terminal, R.sup.1, R.sup.2, and R.sup.3 are each a hydrogen atom or a hydrocarbon group, and R.sup.1 or R.sup.2 may be bonded to X, and at least one of the alkoxysilyl groups of the crown ether structure reacts to be bonded to at least a part of the surface of the solid.

An ion-selective electrode includes: an ion-sensitive layer containing an ion-sensitive substance; and a solid, in which at least a part of a surface of the solid is coated with the ion-sensitive layer, the ion-sensitive substance has a crown ether structure formed of at least two or more repeating units represented by Formula (a):

—CR.sup.1R.sup.2—CR.sup.3X—O—  (a) where X is an organic group having an alkoxysilyl group at a terminal, R.sup.1, R.sup.2, and R.sup.3 are each a hydrogen atom or a hydrocarbon group, and R.sup.1 or R.sup.2 may be bonded to X, and at least one of the alkoxysilyl groups of the crown ether structure reacts to be bonded to at least a part of the surface of the solid.

An electrode for measuring bioelectric signals of an individual includes a dome-like shape support body having a concave contact side facing the individual and an opposite convex connector side. The support body defines a central axis arranged centrally through the contact and connector sides. The electrode includes outer contact pins located on the contact side at a radially outer region of the support body for contacting an area of interest to be measured. The electrode is made of elastomeric material and has conductive properties. The support body is flexible such that after applying the electrode to the individual a force exerted centrally onto the connector side and parallel to the central axis leads to an upwards bending of the radially outer region. The upwards bending leads to tilting of the outer contact pins such that a tip of the outer contact pins moves radially outwards along the area of interest.

An electrode for measuring bioelectric signals of an individual includes a dome-like shape support body having a concave contact side facing the individual and an opposite convex connector side. The support body defines a central axis arranged centrally through the contact and connector sides. The electrode includes outer contact pins located on the contact side at a radially outer region of the support body for contacting an area of interest to be measured. The electrode is made of elastomeric material and has conductive properties. The support body is flexible such that after applying the electrode to the individual a force exerted centrally onto the connector side and parallel to the central axis leads to an upwards bending of the radially outer region. The upwards bending leads to tilting of the outer contact pins such that a tip of the outer contact pins moves radially outwards along the area of interest.

An electrode according to the present invention contains a conductive polymer; a binder resin; and a plasticizing agent, wherein the electrode has a plate shape having a pair of principal surfaces parallel to each other, and wherein a ratio of a content of the plasticizing agent to a content of the conductive polymer being 0.5 to 500.0 in a surface part of the electrode located at less than or equal to 1 μm from a surface of the electrode.

A conductive sheet comprising a conductive substrate layer and a hydrogel layer formed of a silicone hydrogel having a polymer comprising a repeat unit (A) derived from a monomer represented by Formula (I) as a gel skeleton. Provided is a conductive sheet which can maintain adhesiveness and flexibility even when used for a long period of time and can attain high biocompatibility.

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A conductive sheet comprising a conductive substrate layer and a hydrogel layer formed of a silicone hydrogel having a polymer comprising a repeat unit (A) derived from a monomer represented by Formula (I) as a gel skeleton. Provided is a conductive sheet which can maintain adhesiveness and flexibility even when used for a long period of time and can attain high biocompatibility.

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A stretchable raised electrode having a stretch property that can be used as a biological electrode for collecting biological signals while being pressed against a body is provided, and a method of manufacturing the stretchable raised electrode is provided. This raised electrode is a raised electrode formed by raising a surface of a sheet material having the stretch property. This raised electrode includes: a resin layer configured to be stretchable to follow the surface of the sheet material; and a plurality of conductive fibers each having an inserted portion, one end of which is inserted into the resin layer. The conductive fibers that are adjacent to one another are electrically in contact with one another at non-inserted portions into the resin layer, and the conductive fibers are formed in the resin layer so as to have such a density as causing an in-plane isotropic electric conductivity of an electrode region of the sheet material in which the conductive fibers are formed. This raised electrode can be obtained by an electrostatic spraying method.

A bio-electrode composition contains (A) a reaction composite of an ionic polymer material and a carbon particle. The component (A) contains the carbon particle bonding to the polymer containing a repeating unit having a structure selected from the group consisting of salts of ammonium, lithium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity and biocompatibility, light-weight, and manufacturable at low cost, and which prevents significant reduction in the electric conductivity even when wetted with water or dried; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.

A bio-electrode composition contains (A) an ionic polymer material, (B) an addition reaction-curable silicone having at least a hydrosilyl group, (C) a platinum-group catalyst, and a solvent. The bio-electrode composition has a water content of 0.2 mass % or less. The solvent includes one or more of an ether solvent, an ester solvent, and a ketone solvent each of which does not contain a hydroxy group, a carboxyl group, a nitrogen atom, or a thiol group. Thus, present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity and biocompatibility, light-weight, and manufacturable at low cost, and which does not leave residue on skin after attachment to and peeling from the skin; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.