Materials and methods for preparing electrode film mixtures and electrode films including reduced damage bulk active materials are provided. In a first aspect, a method for preparing an electrode film mixture for an energy storage device is provided, comprising providing an initial binder mixture comprising a first binder and a first active material, processing the initial binder mixture under high shear to form a secondary binder mixture, and nondestructively mixing the secondary binder mixture with a second portion of active materials to form an electrode film mixture.

Provided is a method for producing a nonaqueous electrolyte secondary battery, and a production system therefor, that allow forming a good SEI film in a shorter time. The production method includes an assembly step, an initial charging step and a high-temperature aging step. At least one from among the initial charging step and the high-temperature aging step has the following sub-steps: a step of performing an AC impedance measurement on the nonaqueous electrolyte secondary battery and, on the basis of the AC impedance measurement, calculating an ionic conductivity of an SEI film that is formed the surface of a negative electrode of the nonaqueous electrolyte secondary battery; and a step of determining whether the calculated ionic conductivity falls within a predetermined range or not, and terminating the initial charging step or the high-temperature aging step when the ionic conductivity falls within the predetermined range, and continuing the initial charging step or the high-temperature aging step when the ionic conductivity does not fall within the predetermined range.

A method of manufacturing a negative electrode includes providing a negative electrode roll on which a negative electrode structure including a negative electrode current collector, a first negative electrode active material layer formed on one side of the negative electrode current collector, and a second negative electrode active material layer formed on the other side of the negative electrode current collector is wound, preparing a pre-lithiation bath including an impregnation section and a pre-lithiation section and containing a pre-lithiation solution, unwinding the negative electrode structure, moving the negative electrode structure to the impregnation section, and impregnating the negative electrode structure with the pre-lithiation solution; and pre-lithiating the negative electrode structure by moving the same from the impregnation section to the pre-lithiation section. The pre-lithiation is carried out by alternately electrochemically charging the first negative electrode active material layer and the second negative electrode active material layer in the pre-lithiation section.

A device for pre-lithiation including a pre-lithiation reactor sequentially divided into an impregnation section, a pre-lithiation section, and an aging section. The pre-lithiation reactor accommodates a pre-lithiation solution through which a negative electrode structure is moved. A negative electrode roll is arranged outside the pre-lithiation solution, and the pre-movement negative electrode structure is wound. A lithium metal counter electrode is arranged in the pre-lithiation solution of the pre-lithiation section, and is arranged to be spaced apart from the negative electrode structure to face the negative electrode structure moving in the pre-lithiation solution. A charging and discharging unit is connected to the negative electrode structure and connected to the lithium metal counter electrode, wherein the lithium metal counter electrode is tilted and the a separation distance between the lithium metal counter electrode and the negative electrode structure gradually increases in the moving direction of the negative electrode structure.

Cathode materials for lithium ion batteries, lithium ion batteries incorporating the cathode materials, and methods of operating the lithium ion batteries are provided. The materials, which are composed of lithium iron oxides, are able to undergo reversible anionic and cationic redox reactions with no O.sub.2(g) generation.

A method for producing a nonaqueous electrolyte secondary battery, and a production system therefor, that allow forming a SEI film in a shorter time. The method includes assembly, initial charging, and high-temperature aging steps. At least one from the initial charging and the high-temperature aging has the following sub-steps: a step of performing an AC impedance measurement on the battery and, on the basis of the AC impedance measurement, calculating an ionic conductivity of an SEI film that is formed the surface of a negative electrode of the battery; and a step of determining whether the calculated ionic conductivity falls within a predetermined range or not, and terminating the initial charging step or the high-temperature aging step when the ionic conductivity falls within the predetermined range, and continuing the initial charging step or the high-temperature aging step when the ionic conductivity does not fall within the predetermined range.

An electrode for a lithium-ion battery. The electrode has at least one porous silicon layer and a copper layer. There is also described a battery with such an electrode, a method for producing an electrode of this kind, and the use of an electrode of this kind in a battery.

The disclosure provides a primary battery and an electrode assembly thereof. The electrode assembly includes a separator, a positive electrode, and a negative electrode current collector. The separator has a positive electrode side and a negative electrode side opposite to each other. The positive electrode is located at the positive electrode side of the separator, and the positive electrode includes a positive electrode current collector and a positive electrode material. The negative electrode current collector is located at the negative electrode side of the separator. The electrode assembly does not include a negative electrode material before charging or activation.

A lead-based alloy containing alloying additions of bismuth, antimony, arsenic, and tin is used for the production of doped leady oxides, lead-acid battery active materials, lead-acid battery electrodes, and lead-acid batteries.

An electrochemical device of the present invention includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The positive electrode includes a positive current collector containing aluminum, a positive electrode material layer containing a conductive polymer, and an aluminum oxide layer disposed on a surface of the positive current collector. The aluminum oxide layer contains fluorine.