Provided is an all-solid-state battery with high charge-discharge efficiency. Disclosed is an all-solid-state battery, wherein the all-solid-state battery comprises a cathode comprising a cathode layer, an anode comprising an anode layer, and a solid electrolyte layer disposed between the cathode layer and the anode layer; wherein the anode layer contains at least one selected from the group consisting of a lithium metal and a lithium alloy; and wherein a protective layer comprising a composite metal oxide represented by Li—M—O (where M is at least one metal element selected from the group consisting of Mg, Au, Al and Sn) is disposed between the anode layer and the solid electrolyte layer.

A method of making a lithiated silicon-based precursor material for a negative electrode material of an electrochemical cell that cycles lithium ions is provided. An admixture comprising a plurality of lithium particles and a plurality of silicon particles is briquetted by applying pressure of greater than or equal to about 10 MPa and applying heat at a temperature of less than or equal to about 180° C. to form a precursor briquette. The briquette has lithium particles and silicon particles distributed in a matrix and has a porosity level of less than or equal to about 60% of the total volume of the precursor briquette. The briquetting is conducted in an environment having less than or equal to about 0.002% by weight of any oxygen-bearing species or nitrogen (N.sub.2).

A solid-state ion conductor includes a compound of Formula 1:
Li.sub.6+(5−a)x−b*y−z(c+2)wA.sub.1−x(M1).sup.a.sub.x(M2).sup.b.sub.yO.sub.5−z−wX.sub.1+zQ.sup.c.sub.w  Formula 1
wherein, in Formula 1, A is an element having an oxidation state of +5, M1 is an element having an oxidation state of a, wherein a is +2, +3, +4, +6, +7, or a combination thereof, M2 is an element having an oxidation state of b, wherein b is +1, +2, or a combination thereof, X is an element having an oxidation state of −1, Q is an element having an oxidation state of c, wherein c is less than −2, and wherein −2≤(5−a)x−b*y−z−(c+2)w≤2, 0≤x≤0.5, 0≤y≤0.5, −1≤z≤1, 0≤w≤0.5.

A separator for a lithium-containing electrochemical cell is provided herein. The separator includes a porous substrate having a first side and an opposing second side and a coating layer disposed adjacent to at least the first side of the porous substrate. The coating layer includes three-dimensionally (3D) ordered porous ceramic particles. An electrochemical cell including such a separator is also provided herein. The electrochemical cell may or may not include a negative electrode.

Provided is an anode active material layer for a lithium battery. This layer comprises multiple particulates of an anode active material, wherein at least a particulate is composed of one or a plurality of particles of a high-capacity anode active material being encapsulated by a thin layer of elastomeric material that has a lithium ion conductivity no less than 10.sup.−7 S/cm (preferably no less than 10.sup.−5 S/cm) at room temperature and an encapsulating shell thickness from 1 nm to 10 μm, and wherein the high-capacity anode active material (e.g. Si, Ge, Sn, SnO.sub.2, Co.sub.3O.sub.4, etc.) has a specific capacity of lithium storage greater than 372 mAh/g (the theoretical lithium storage limit of graphite).

An electrolyte for a lithium metal battery and a lithium metal battery including the same, more specifically an electrolyte for a lithium metal battery including a lithium salt, an organic solvent and an additive, wherein the additive includes a functional group that binds to lithium metal at one end thereof and a fluorinated hydrocarbon group at the other end. The electrolyte for the lithium metal battery includes an additive including particular functional groups to improve the stability of the lithium metal and suppress the side reaction at the surface, thereby enabling the lithium metal battery to have high capacity, high stability, and long life.

The invention relates to composite multilayer lithium ion battery anodes that include a porous metal alloy foam, and a lithium ion conductor coating applied to the metal alloy foam. The metal alloy foam can include structurally isomorphous alloys of lithium and, optionally, lithium and magnesium. The lithium ion conductor coating can include ternary lithium silicate, such as, lithium orthosilicate. Lithium ions from the ternary lithium silicate may be deposited within the pores of the metal alloy foam. Optionally, the lithium ion conductor coating may include a dopant. The dopant can include one or more of magnesium, calcium, vanadium, niobium and fluorine, and mixtures and combinations thereof.

The present invention provides a non-aqueous electrolyte solution for a lithium secondary battery and a lithium secondary battery including the same. Specifically, since the non-aqueous electrolyte solution forms a robust solid electrolyte interphase (SEI) by including a lithium salt, an organic solvent, and a compound represented by Formula 1, the non-aqueous electrolyte solution for a lithium secondary battery may improve battery performance,

##STR00001## wherein, in Formula 1, R and R.sub.1 are described herein.

Some aspects of the disclosure are related to lithium batteries, and more specifically, to integrated battery electrode and separator. In some embodiments, an electrochemical cell comprises a single integrated unit comprising insulating layer, current collectors, electroactive material layers, separators, and the like. Methods of manufacturing of the integrated battery unit are disclosed herein. Some embodiments of the disclosure are also directed to an integrated anode-free electrochemical cell that lacks an anode or anode electroactive material layer. In some such embodiments, methods directed to electrical storage and use of such an anode-free electrochemical cell are disclosed herein.

The present disclosure discloses a primary lithium battery comprising a reactive solid cathode, a liquid electrolyte, a separator, and a lithium anode. The liquid electrolyte is ionic conductive and is configured to undergo a series coupling reaction after solid phase reaction of the reactive solid cathode and the lithium anode. The liquid electrolyte comprises a solvent and an electrolyte salt, and a concentration of the electrolyte salt in the liquid electrolyte is 0.1-3 mol/L. The solvent comprises a sulfite ester type compound and an organic solvent, and a concentration of the sulfite ester type compound in the organic solvent is 5 wt % to 90 wt %.