The present application relates to a cathode material and an electrochemical device comprising the same. In particular, the present application relates to a cathode material having a surface heterophasic structure, wherein the cathode material includes a lithium cobalt oxide and an oxide of cobalt, wherein a Raman spectrum of the cathode material has characteristic peaks in the range of about 470 cm.sup.−1 to about 530 cm.sup.−1, about 560 cm.sup.−1 to about 630 cm.sup.−1 and about 650 cm.sup.−1 to about 750 cm.sup.−1, and wherein the surface heterophasic structure of the cathode material includes the lithium cobalt oxide and the oxide of cobalt. The electrochemical device using the cathode material having a surface heterophasic structure of the present application can exhibit excellent cycle performance and thermal stability.

A positive electrode active material for a lithium secondary battery comprising a compound represented by Chemical Formula 1 is introduced.

Li.sub.1+mNi.sub.1-w-x-y-zCo.sub.wMn.sub.xM1.sub.yM2.sub.zO.sub.2-pX.sub.p  [Chemical Formula 1] (In the Chemical Formula 1, M1 and M2 are different from each other, and any one element selected from the group consisting of Al, Mg, Zr, Sn, Ca, Ge, Ti, Cr, Fe, Zn, Y, Ba, La, Ce, Sm, Gd, Yb, Sr, Cu and Ga respectively, X is any one element selected from the group consisting of F, N, S, and P, w, x, y, z, p and m are respectively 0.125<w<0.202, 0.153<x<0.225, 0≤y≤0.1, 0≤z≤0.1, 0.34≤w+x≤0.36, 0≤p≤0.1, and −0.1≤m≤0.2.)

A positive electrode active material that is used in a high-temperature operation type lithium ion solid secondary battery, wherein the positive electrode active material is made of oxide particles, which contains a first transition element and does not include an alkali metal.

The present invention provides a battery electrode comprising an active battery material enclosed in the pores of a conductive nanoporous scaffold. The pores in the scaffold constrain the dimensions for the active battery material and inhibit sintering, which results in better cycling stability, longer battery lifetime, and greater power through less agglomeration. Additionally, the scaffold forms electrically conducting pathways to the active battery nanoparticles that are dispersed. In some variations, a battery electrode of the invention includes an electrically conductive scaffold material with pores having at least one length dimension selected from about 0.5 nm to about 100 nm, and an oxide material contained within the pores, wherein the oxide material is electrochemically active.

A prelithiated anode may include a current collector may include a metal oxide layer. Prelithiated anodes may in addition include a lithiated storage layer overlaying the metal oxide layer. The lithiated storage layer may be formed by incorporating lithium into a continuous porous lithium storage layer may include at least 80 atomic % silicon. The lithiated storage layer may include less than 1% by weight of carbon-based binders. The lithiated storage layer may further include lithium in a range of 1% to 90% of a theoretical lithium storage capacity of the continuous porous lithium storage layer. Batteries may include the prelithiated anode.

Disclosed herein is a composite particulate comprising a plurality of active material particles; and a single graphene sheet or a plurality of graphene sheets surrounds the plurality of active material particles and a surface of the composite particulate, wherein a single graphene sheet or a plurality of graphene sheets provides an electron-conducting path.

The present invention relates to a battery electrode. The battery electrode comprises a plurality of carbon nanotubes and a plurality of transition metal oxide nanoparticles. The plurality of transition metal oxide nanoparticles are chemically bonded to the plurality of carbon nanotubes through carbon-oxygen-metal (C-O-M) linkages, wherein the metal being a transition metal element. The present invention also relates a method for making the battery electrode and a hybrid energy storage device using the battery electrode.

Cathode materials for lithium ion batteries, lithium ion batteries incorporating the cathode materials, and methods of operating the lithium ion batteries are provided. The materials, which are composed of lithium iron oxides, are able to undergo reversible anionic and cationic redox reactions with no O.sub.2(g) generation.

Described herein are acidified metal oxide (“AMO”) materials useful in applications such as a battery electrode or photovoltaic component, in which the AMO material is used in conjunction with one or more acidic species. Advantageously, batteries constructed of AMO materials and incorporating acidic species, such as in the electrode or electrolyte components of the battery exhibit improved capacity as compared to a corresponding battery lacking the acidic species.

An electrode comprises carbon nanoparticles and at least one of metal particles, metal oxide particles, metalloid particles and/or metalloid oxide particles. A surfactant attaches the carbon nanoparticles and the metal particles, metal oxide particles, metalloid particles and/or metalloid oxide particles to form an electrode composition. A binder binds the electrode composition such that it can be formed into a film or membrane. The electrode has a specific capacity of at least 450 mAh/g of active material when cycled at a charge/discharge rate of about 0.1 C.