A process for synthesizing a material, includes: (a) providing a plurality of powders including at least one lithiated powder including lithium, at least one TM powder including, for more than 95.0% of its mass, a transition metal chosen from titanium; cobalt, manganese, nickel, niobium, tin, iron and mixtures thereof, and at least one chalcogen powder including, for more than 95.0% of its mass, a chalcogen element chosen from sulfur, selenium, tellurium and mixtures thereof, (b) preparing a particulate mixture by mixing all the powders of the plurality or by mixing one of the powders of the plurality with a milled material obtained by; milling a particulate assembly formed by mixing at least two of the other powders of the plurality, and (c) milling the particulate fixture to form the material.

A negative electrode comprises a negative electrode current collector, a first active material layer, and a second active material layer; wherein the second active material layer is located between the negative electrode current collector and the first active material layer; the first active material layer comprises a first active material and a target compound, the target compound comprises A.sub.xB.sub.y, where 0<x≤4, 0<y≤8, A comprises a metal element comprising at least one of the group consisting of Li, Na, Mg, Ca, Zn, and Cs, and B comprises a non-metallic element comprising at least one of the group consisting of N, S, and Si.

Provided is a cathode for an all-solid-state lithium-sulfur battery that makes the discharge capacity improved. The cathode for an all-solid-state lithium-sulfur battery includes: a cathode mixture containing sulfur, a carbon nanotube, P.sub.2S.sub.5, and an Li.sub.2S—P.sub.2S.sub.5 based solid electrolyte, wherein the sulfur, the carbon nanotube, and the P.sub.2S.sub.5 form a composite, and the cathode mixture contains higher than 0 wt % and lower than 20 wt % of the carbon nanotube.

To reduce an electric resistance of an all-solid-state battery, the all-solid-state battery includes: an anode active material layer; a cathode active material layer; and a solid electrolyte layer disposed between the anode active material layer and the cathode active material layer, wherein the cathode active material layer contains S, Li.sub.2S, P.sub.2S.sub.5, and a single-walled carbon nanotube.

A method of producing a powder mass for a lithium battery, the method comprising: (a) providing a solution containing a sulfonated elastomer dissolved in a solvent or a precursor in a liquid form or dissolved in a solvent; (b) dispersing a plurality of particles of a cathode active material in the solution to form a slurry; and (c) dispensing the slurry and removing the solvent and/or polymerizing/curing the precursor to form the powder mass, wherein the powder mass comprises multiple particulates and at least a particulate comprises one or a plurality of particles of a cathode active material being encapsulated by a thin layer of sulfonated elastomer having a thickness from 1 nm to 10 μm, a fully recoverable tensile strain from 2% to 800%, and a lithium ion conductivity from 10.sup.−7 S/cm to 5×10.sup.−2 S/cm at room temperature.

The present invention concerns a method for producing a solid material according to general formula (I) as follows: Li.sub.6-.sub.x_.sub.2yCu.sub.xPS.sub.5_.sub.yX (I) wherein X is selected from the group consisting of: F, CI, I and Br; 0.005 ≤ x ≤ 5; and 0 ≤y ≤ 0.5.; comprising at least bringing at least lithium sulfide, phosphorous sulfide, halogen compound and a copper compound, optionally in one or more solvents. The invention also refers to said solid materials and their use as solid electrolytes notably for electrochemical devices.

A compound of Formula 1
Li.sub.1+(4−a)αHf.sub.2−αM.sup.a.sub.α(PO.sub.4−δ).sub.3  (1)
is disclosed, wherein M is at least one cationic element having a valence of a, wherein 0<α≤⅔, 1≤a≤4, and 0≤δ≤0.1. Also described are an electrolyte composition, a separator, a protected positive electrode, a protected negative electrode, and a lithium battery, each including the compound of Formula 1.

A method for producing a lithium-sulfur battery with an improved lifetime. This method includes an activation step of forming a positive electrode active material-derived compound from a compound including elemental sulfur by charging and discharging the lithium-sulfur battery, where the battery includes the compound including elemental sulfur and an electrolyte liquid. Additionally, the positive electrode active material-derived compound has a solubility of 1% by weight or greater in the electrolyte liquid. The lithium-sulfur battery may be charged and discharged in a range of greater than 2.0 V and less than 2.4 V in the activation step. Further, the lithium-sulfur battery may be charged and discharged 3 times to 10 times in the activation step. This method avoids a complicated application process of and active material in preparing a lithium-sulfur battery.

Two-dimensional (2D) material-based metal or alloy catalysts synthesized on carbon materials (e.g., carbon nanotubes) prevent polysulfide shuttling and overcome technical challenges for developing practical lithium-sulfur (Li—S) batteries. Soluble lithium polysulfides (LiPSs) tend to shuttle during battery cycling and corrode a Li anode, leading to eventual performance fading in the Li—S battery. This shuttle effect can be reduced by accelerating the conversion of the dissolved polysulfides to the insoluble LiPSs and back to the sulfur. A 2D material-based alloy or 2D material synthesized on carbon materials can suppress polysulfide shuttling by catalyzing polysulfide reactions. 2D material-based alloys with 2H (semiconducting)—1T (metallic) mixed phase exhibit synergistic effects of accelerated electron transfer and catalytic performance as confirmed by the lower charge-transfer resistance of carbon nanotube (CNT)—S cathode and the high binding energy of LiPSs to the catalyst.

The invention provides a method for delaminating a composite by immersing the composite into a delamination solution; wherein the composite comprises a metal substrate and a coating applied on one side or both sides of the metal substrate, wherein the coating comprises a polymeric binder; and wherein the polymeric binder comprises an aqueous copolymer. The use of delamination solution comprising a weak base allows for complete delamination of the composite in a highly efficient and extremely fast manner. Furthermore, the delamination method disclosed herein circumvents complex separation processes, contamination and corrosion of the metal substrate and enables an excellent materials recovery. An application of the method for delaminating an electrode for a battery is disclosed herein.