Solid-state energy harvesters comprising layers of metal suboxides and cerium dioxide utilizing a solid-state electrolyte to produce power and methods of making and using the same are provided. The solid-state energy harvester may have two or three electrodes per cell and produces power in the presence of water vapor and oxygen.

A method of forming an interlayer of a solid oxide cell unit on the surface of a substrate may include: providing a base interlayer solution comprising a solution of a soluble salt precursor of a metal oxide (crystalline) ceramic and crystalline nanoparticles, depositing the base interlayer solution onto the surface of the substrate, drying the base interlayer solution to define a nanocomposite sub-layer of the soluble salt precursor and nanoparticles, heating the sub-layer to decompose it and form a film of metal oxide comprising nanoparticles on the surface, and firing the substrate with the film on the metal surface, to form a nanocomposite crystalline layer.

A laminated all-solid-state battery includes a laminate having positive electrode and positive electrode active material layers, negative electrode layers having negative electrode current collector and negative electrode active material layers, and solid electrolyte layers. The positive and negative electrode layers are alternately laminated with the solid electrolyte layers interposed. The solid electrolyte layers include solid electrolyte layers belonging to first and second groups, the second thicker than the first. The first group includes a first solid electrolyte layer being thinnest. The second group is composed of a second solid electrolyte layer having a thickness of twice or more that of the first. A relationship (1) is satisfied when an average thickness of the plurality of solid electrolyte layers belonging to the first group is defined as t.sub.a and an average thickness of the solid electrolyte layers belonging to the second group is defined as t.sub.b; 2t.sub.a≤t.sub.b . . . (1).

A fuel cell system including: an electrochemical pump including a first anode, a first cathode, and a first electrolyte membrane including a proton conductive oxide, the electrochemical pump separating hydrogen from a gas containing the hydrogen, and a solid oxide fuel cell that includes a second anode, a second cathode, and a second electrolyte membrane including a solid oxide electrolyte, and that generates electricity by reacting a fuel gas and an oxidant gas with each other.

The present disclosure relates to an ionic liquid-based quasi-solid-state electrolyte in a lithium battery and a preparation method thereof. The quasi-solid-state electrolyte is of a porous network structure, which is obtained by a condensation reaction of a lithium salt, ionic liquid, a silane coupling agent and a catalyst, and has a high ionic conductivity. The quasi-solid-state electrolyte can stabilize a stripping/deposition process of lithium metal and inhibit growth of lithium dendrites, and shows a low overpotential and long-term cycle stability in a constant current polarization process. The interface impedance of a lithium metal sheet and the quasi-solid-state electrolyte is low, and is hardly increased with the age of the battery.

A system and a method for forming a composite electrolyte structure are provided. An exemplary composite electrolyte structure includes, at least in part, polymer electrolyte preforms that are bonded into the composite electrolyte structure.

Disclosed is a method of manufacturing a solid oxide fuel cell including a multi-layered electrolyte layer using a calendering process. The method for manufacturing a solid oxide fuel cell is a continuous process, thus providing high productivity and maximizing facility investment and processing costs. In addition, the solid oxide fuel cell manufactured by the method includes an anode that is free of interfacial defects and has a uniform packing structure, thereby advantageously greatly improving the production yield and power density. In addition, the solid oxide fuel cell has excellent interfacial bonding strength between respective layers included therein, and includes a multi-layered electrolyte layer in which the secondary phase at the interface is suppressed and which has increased density, thereby advantageously providing excellent output characteristics and long-term stability even at an intermediate operating temperature.

A glass ceramic seal is formed from a precursor material that includes from 80 mol % to 100 mol % of a primary component containing, on an oxide basis, from 25 mol % to 55 mol % SiO.sub.2, from 20 mol % to 45 mol % CaO, from 5 mol % to 30 mol % MgO, and from 0 mol % to 15 mol % Al.sub.2O.sub.3.

The present disclosure relates to a binder solution for all-solid-state batteries. The binder solution includes a polymer binder, a first solvent, and an ion-conductive additive, wherein the ion-conductive additive includes lithium salt and a second solvent, which is different from the first solvent.

An all-solid-state battery that includes a battery element and an exterior material covering a surface of the battery element, wherein the exterior material includes one or more glass state materials and one or more crystalline state materials.