A sputtering target comprising a top coat including a composition of lithium cobalt oxide LiyCozOx. x is smaller than or equal to y+z, and the lithium cobalt oxide has an X-Ray diffraction pattern with a peak P2 at 44°±0.2° 2-theta. The X-Ray diffraction pattern is measured with an X-Ray diffractometer with CuKα1 radiation.

A method of manufacturing a battery cathode for a solid state battery is provided. The method includes generating a plasma remote from one or more targets suitable for forming cathodes, such as LiCoO.sub.2, exposing the plasma target or targets to the plasma, thereby generating sputtered material from the target or targets, and depositing sputtered material on a first portion of a substrate, thereby forming crystalline material, such as LiCoO.sub.2 on the first portion of the substrate.

Provided are a member for a sodium-ion secondary battery and a sodium-ion secondary battery both of which are not susceptible to deterioration of charge/discharge cycle characteristics due to charge and discharge. A member 8 for a sodium-ion secondary battery includes: a solid electrolyte layer 2 having sodium-ion conductivity; a metallic sodium layer 6 disposed on one principal surface 2b of the solid electrolyte layer 2 and made of metallic sodium; and a metallic layer 5 provided between the solid electrolyte layer 2 and the metallic sodium layer 6 and made of a metal different from the metallic sodium.

A method for using an integrated battery and device structure includes using two or more stacked electrochemical cells integrated with each other formed overlying a surface of a substrate. The two or more stacked electrochemical cells include related two or more different electrochemistries with one or more devices formed using one or more sequential deposition processes. The one or more devices are integrated with the two or more stacked electrochemical cells to form the integrated battery and device structure as a unified structure overlying the surface of the substrate. The one or more stacked electrochemical cells and the one or more devices are integrated as the unified structure using the one or more sequential deposition processes. The integrated battery and device structure is configured such that the two or more stacked electrochemical cells and one or more devices are in electrical, chemical, and thermal conduction with each other.

A negative electrode for a lithium secondary battery, in which a LiF layer comprising amorphous LiF in an amount of 30 mol % or more is formed on a negative electrode active material layer comprising a carbon-based active material, a lithium secondary battery comprising the same, and a preparation method thereof.

A method of manufacturing a crystalline layer of material on a surface, the crystalline layer including lithium, at least one transition metal and at least one counter-ion. The method includes the following steps: generating a plasma using a remote plasma generator, plasma sputtering material from a first target including lithium onto a surface of or supported by a substrate, there being at least a first plume corresponding to trajectories of particles from the first target onto the surface, and plasma sputtering material from a second target including at least one transition metal onto the surface, there being at least a second plume corresponding to trajectories of particles from the second target onto the surface. The first target is positioned to be non-parallel with the second target, the first plume and the second plume converge at a region proximate to the surface of or supported by the substrate, and the crystalline layer is formed on the surface at the region.

A method of depositing a material on a substrate is provided. The method includes generating a plasma remote from one or more sputter targets suitable for plasma sputtering, wherein at least one distinct region of the one or more targets includes an alkali metal, alkaline earth metal, alkali metal containing compound, alkaline earth metal containing compound or a combination thereof; generating sputtered material from the target or targets using the plasma; and depositing the sputtered material on the substrate, the working distance between the target and the substrate being within +/−50% of the theoretical mean free path of the system.

The present invention provides a method for manufacturing a thin film foil, wherein a metal thin film layer is formed on a base substrate through a vacuum deposition process to form an ultra-thin film foil having a thickness of 5 μm or less, preferably 2 μm or less. The provided method for manufacturing a thin film foil comprises the steps of: preparing a base substrate having release properties; preparing a metal raw material; vacuum-depositing the metal raw material on the base substrate to form a metal layer on the base substrate; and separating the base substrate from the metal layer to form a thin film foil, wherein one of a BeCu alloy, a Cu—Ag—Cr ternary alloy, an Ag alloy, a CuMo alloy, and a CuFeP alloy is prepared as the metal raw material.

Described are energy storage devices employing a gas storage structure, which can accommodate or store gas evolved from the energy storage device. The energy storage device comprises an electrochemical cell with electrodes comprising metal-containing compositions, like metal oxides, metal nitrides, or metal hydrides, and a solid state electrolyte.

A method of forming a crystalline cathode layer of a solid-state battery on a substrate, the method including generating a plasma remote from one or more sputter targets for forming the cathode layer, generating sputtered material from the target or targets using the plasma, and depositing the sputtered material on the substrate, thereby forming the crystalline cathode layer.