The active element of an electrochemical apparatus for producing electrical power and/or hydrogen may be formed as a massive metal body or a mesh-type or perforated sheet-type support structure. The support structure may be made from at least one of magnesium, zinc, aluminum, manganese, iron, or titanium, or an alloy of at least one of these, and may include a coating of boron enhanced carbon/graphite/graphene or a boron enhanced material. The boron enhanced material may include at least two elements selected from carbon/graphite/graphene, nickel, tungsten, phosphorous, and copper.

To provide a solid-state battery that can improve layout by allowing a current collecting position to be optionally disposed and that can suppress the occurrence of short circuits. A solid-state battery includes a positive electrode, a negative electrode, and a solid electrolyte layer disposed between the positive electrode and the negative electrode. A first electrode selected from one of the positive electrode and the negative electrode includes a material mixture filled portion including a metal porous body filled with an electrode material mixture. The solid electrolyte layer is disposed so as to cover a periphery of the material mixture filled portion. A second electrode selected from the other of the positive electrode and the negative electrode is disposed so as to cover the solid electrolyte layer.

Provided is a long aluminum foil capable of suppressing, in a case where the aluminum foil is provided with a region where through-holes are not formed, occurrence of deformation at a boundary portion between a region where through-holes are formed and the region where through-holes are not formed. The long aluminum foil includes, in a width direction orthogonal to a longitudinal direction, a perforated portion, a non-perforated portion, and a boundary portion between the perforated portion and the non-perforated portion, in which the perforated portion has a plurality of through-holes penetrating therethrough in a thickness direction, the non-perforated portion does not have a through-hole, the boundary portion has a plurality of through-holes penetrating therethrough in the thickness direction and a plurality of non-through-holes, and an opening ratio of the through-hole in the boundary portion gradually decreases from a perforated portion side to a non-perforated portion side.

Electroactive materials having a nitrogen-containing carbon coating and composite materials for a high-energy-density lithium-based, as well as methods of formation relating thereto, are provided. The composite electrode material includes a silicon-containing electroactive material having a substantially continuous nitrogen-containing carbon coating formed thereon. The method includes contacting the silicon-containing electroactive material and one or more nitrogen-containing precursor materials and heating the mixture. The one or more nitrogen-containing precursor materials include one or more nitrogen-carbon bonds and during heating the nitrogen of the one or more nitrogen-carbon bonds with silicon in the silicon-containing electroactive material to form the nitrogen-containing carbon coating on exposed surfaces of the silicon-containing electroactive material.

The present invention relates to an anode including multiple current collectors juxtaposed in parallel, and a secondary battery comprising same, wherein the anode enables providing a high-capacity secondary battery while suppressing volume changes due to a silicone component-containing active material employed therein.

A fuel electrode incorporates a first and second corrugated portion that are attached to each other at offset angles respect to their corrugation axis and therefore reinforce each other. A first corrugated portion may extend orthogonally with respect to a second corrugated portion. The first and second corrugated portions may be formed from metal wire and may therefore have a very high volumetric void fraction and a high surface area to volume ratio (sa/vol). In addition, the strands of the wire may be selected to enable high conductivity to the current collectors while maximizing the sa/vol. In addition, the shape of the corrugation, including the period distance, amplitude and geometry may be selected with respect to the stiffness requirements and electrochemical cell application factors. The first and second corrugated portions may be calendared or crushed to reduce thickness of the fuel electrode.

Disclosed is an electrode for a rechargeable energy storage device, including several inner layers interposed between two outer layers, the inner layers including several electrode material layers ME composed of at least one electrode active material and several porous current collector layers CC composed of electrically-conductive material(s) whose electronic conductivity is greater than or equal to 102 S.Math.cm-1, the layers of electrode material ME and current collector CC being alternated. The outer layers do not consist of the porous current collector layers CC. Additionally, the electrode has a total thickness ranging from strictly more than 4 mm, preferably ranging from strictly more than 4 mm to 10 mm, in particular ranging from strictly more than 4 mm to 8 mm.

Alkali metal secondary batteries that include anodes constructed from alkali metal foil applied to only one side of a porous current collector metal foil. Openings in the porous current collectors permit alkali metal accessibility on both sides of the anode structure. Such anode constructions enable the utilization of lower-cost and more commonly available alkali metal foil thickness, while still achieving high cell cycle life at a significantly reduced cost. Aspects of the present disclosure also include batteries with porous current collectors having increased volumetric and gravimetric energy densities, and methods of manufacturing anodes with porous current collectors.

Provided is a current collector 30, including a metal foil 5 having a plurality of first through holes 5a, a metal oxide film 15 formed on a top or bottom surface of the metal foil 5, and a conductive layer 25 formed on a top or bottom surface of the metal oxide film 15. The plurality of first through holes 5a is filled with a conductive connection member 10 to form the metal foil 5. The metal oxide film 15 is formed to have second through holes 15a at locations corresponding to the plurality of first through holes 5a, respectively, on the top or bottom surface of the metal foil 5. The conductive layer 25 is formed to have a third through hole 25a at a location corresponding to each of the second through holes 15a on a top or bottom surface of the metal oxide film 15.

An electrochemical cell comprises a casing having an open-ended container closed by a lid. An anode and cathode are housed inside the casing. The cathode housed inside a primary separator envelope is electrically connected to a positive polarity terminal pin electrically isolated from the casing by a glass-to-metal seal. The anode is electrically connected to the casing serving as a negative terminal. The primary separator enveloping the cathode is contained in a secondary separator comprising an open-ended bag-shaped member extending to an open annular edge. The open annular edge of the secondary separator resides between the cathode electrically connected to the terminal pin and the anode electrically connected to the casing. As electrochemical cells become increasingly smaller to power smaller devices, the physical barrier provided by the upper edge of the secondary separator is important to prevent physical contact between the positive and negative terminals. An electrolyte provided in the casing activates the anode and cathode.