An lead-acid battery is described. The battery includes a carbon fiber electrode having a paste containing a novel additive including one or more carbons, organic expanders, and barium sulfate.

In an embodiment, a Li-ion battery cell comprises an anode electrode with an electrode coating that (1) comprises Si-comprising active material particles, (2) exhibits an areal capacity loading in the range of about 3 mAh/cm.sup.2 to about 12 mAh/cm.sup.2, (3) exhibits a volumetric capacity in the range from about 600 mAh/cc to about 1800 mAh/cc in a charged state of the cell, (4) comprises conductive additive material particles, and (5) comprises a polymer binder that is configured to bind the Si-comprising active material particles and the conductive additive material particles together to stabilize the anode electrode against volume expansion during the one or more charge-discharge cycles of the battery cell while maintaining the electrical connection between the metal current collector and the Si-comprising active material particles.

A sodium nickel chloride battery for high-performance batteries of electric vehicles and other demanding stationary applications. The battery which permits a current collector with a maximum surface-to-cross-section ratio and simple manufacture thereof as well as simplified electrode filling of the battery includes a cathode-side metallic current collector elongated in a cathode chamber about a central axis that is made of a metal tube with high electrical conductivity and has, in a part of the current collector immersed in a separator, a formed tube section, provided with elements for increasing the surface area of the current collector, and has, at a transition from an unpressed tube section as a filler tube to a pressed tube section, a through-hole opening the filler tube to the outside, so that the filler tube can be used as a filling opening for the porous mixture of the cathode and the secondary electrolyte.

A negative electrode for lithium secondary batteries is provided. The negative electrode comprises a negative electrode current collector including a porous structure having an inner pore or a through-hole formed therethrough from an upper surface to a lower surface thereof, wherein a lithiophilic material is applied to a surface of the porous structure or the through-hole excluding a first surface of the negative electrode current collector that faces a positive electrode.

A negative electrode for lithium secondary batteries is provided. The negative electrode comprises a negative electrode current collector including a porous structure having an inner pore or a through-hole formed therethrough from an upper surface to a lower surface thereof, wherein a lithiophilic material is applied to a surface of the porous structure or the through-hole excluding a first surface of the negative electrode current collector that faces a positive electrode.

The present disclosure provides a porous electrode for a flow-through rechargeable electrochemical cell including a high-porosity metal current collector, an active material surrounding the metal current collector, and a self-supporting synthetic membrane material surrounding the active material. The present disclosure further includes a flow-through rechargeable battery including multiple electrochemical cells, a closed loop, and a pump.

Apparatus, systems, and methods described herein relate to safety devices for electrochemical cells comprising an electrode tab electrically coupled to an electrode, the electrode including an electrode material disposed on a current collector. In some embodiments, a fuse can be operably coupled to or formed in the electrode tab. In some embodiments, the fuse can be formed by removing a portion of the electrode tab. In some embodiments, the fuse can include a thin strip of electrically resistive material configured to electrically couple multiple electrodes. In some embodiments, the current collector can include a metal-coated deformable mesh material such that the current collector is self-fusing. In some embodiments, the fuse can be configured to deform, break, melt, or otherwise discontinue electrical communication between the electrode and other components of the electrochemical cell in response to a high current condition, a high voltage condition, or a high temperature condition.

Apparatus, systems, and methods described herein relate to safety devices for electrochemical cells comprising an electrode tab electrically coupled to an electrode, the electrode including an electrode material disposed on a current collector. In some embodiments, a fuse can be operably coupled to or formed in the electrode tab. In some embodiments, the fuse can be formed by removing a portion of the electrode tab. In some embodiments, the fuse can include a thin strip of electrically resistive material configured to electrically couple multiple electrodes. In some embodiments, the current collector can include a metal-coated deformable mesh material such that the current collector is self-fusing. In some embodiments, the fuse can be configured to deform, break, melt, or otherwise discontinue electrical communication between the electrode and other components of the electrochemical cell in response to a high current condition, a high voltage condition, or a high temperature condition.

This disclosure relates to an SO.sub.2-based electrolyte for a rechargeable battery cell containing at least one conducting salt of the Formula (I) ##STR00001##
wherein M is a metal selected from the group consisting of alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements and aluminum; x is an integer from 1 to 3; the substituents R, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from the group consisting of C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.1 alkenyl, C.sub.2-C.sub.1 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl, and C.sub.5-C.sub.14 heteroaryl; and Z is aluminum or boron.

Low-cost electrochemical energy storage devices having electrochemical cells containing zinc electrodes in aqueous electrolytes, which exhibit superior cycle performance, preferably comprise the following elements: (a) a cathode formed of manganese dioxide particles, preferably doped with at least one of magnesium, strontium, barium, calcium, and lanthanum, wherein the manganese dioxide particles preferably form at least one of (1) a delta manganese dioxide structure and (2) a todokorite manganese dioxide structure; (b) an anode formed of particles comprising zinc, wherein the particles are preferably treated with at least one of bismuth, indium, gallium, antimony, and tin; (c) a mixed ion electrolyte solution with a pH greater than or equal to three and less than or equal to seven, wherein the solution preferably comprises at least one monovalent salt and at least one divalent salt; and (d) a mesh as cathode current collector comprising at least one of titanium, stainless steel, tantalum, and niobium, wherein the mesh is preferably coated by an electrically conductive and yet oxidation resistant material comprising but not limited to carbon.