Synthesis process for new particles of Li.sub.4Ti.sub.5O.sub.12, Li.sub.(4-)Z.sub.Ti.sub.5O.sub.12 or Li.sub.4Z.sub.Ti.sub.(5-)O.sub.12, preferably having a spinel structure, wherein is greater than 0 and less than or equal to 0.5 (preferably having a spinel structure), representing a number greater than zero and less than or equal to 0.33, Z representing a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators.

This disclosure relates to a rechargeable battery cell comprising an active metal, at least one positive electrode, at least one negative electrode, a housing and an electrolyte, the positive electrode comprising at least one polyanionic compound as an active material and the electrolyte being based on SO.sub.2 and comprising at least one first conducting salt which has the formula (I), ##STR00001##
M being a metal selected from the group formed by alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements, and aluminum; x being an integer from 1 to 3; the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 being selected independently of one another from the group formed by C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.10 alkenyl, C.sub.2-C.sub.10 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl and C.sub.5-C.sub.14 heteroaryl; and Z being aluminum or boron.

A method for producing a composite electrode for an electrochemical cell is provided herein. The method includes: applying a self-supporting electrode film and/or a dry electrode mixture to a porous collector foil; and compressing the self-supporting electrode film and/or the dry electrode mixture and the porous collector foil to form a composite electrode. The self-supporting electrode film and/or the dry electrode mixture includes a multiplicity of dry-processed particles, the multiplicity of dry-processed particles containing at least a binder, a conductivity additive, and an active material; the porous collector foil ahs openings that extend through the porous collector foil; the electrode film or the dry electrode mixture is pressed at least partially into the openings of the porous collector foil; and the composite electrode is free from adhesion promoters. A composite electrode is further provided. An electrochemical cell including at least one composite electrode is further provided.

Disclosed herein are exemplary embodiments of improved electrode plate and separator assemblies (400) for lead acid batteries, improved lead acid cells or batteries incorporating the improved assemblies, systems or vehicles incorporating the improved assemblies (400) and/or batteries (100), and methods related thereto. The electrode plate (200, 201) may have a grid (202) of a stamped, cast, or expanded metal manufacturing process. The grid (202) may have a non-uniform application of active material (203). The separators (300) preferably provide a support structure for resisting or mitigating any plate warping or plate deflection.

This disclosure relates to a rechargeable battery cell having an active metal, at least one positive electrode, at least one negative electrode, a housing and an electrolyte, the positive electrode comprising at least one compound in the form of a layered oxide as an active material and the electrolyte being based on SO.sub.2 and comprising at least one first conducting salt which has the formula (I), ##STR00001## M being a metal selected from the group formed by alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements, and aluminum; x being an integer from 1 to 3; the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 being selected independently of one another from the group formed by C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.10 alkenyl, C.sub.2-C.sub.10 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl and C.sub.5-C.sub.14 heteroaryl; and Z being aluminum or boron.

A current collector includes a support layer, a first conductive layer, and a tab. The support layer is made of a resin composition having electrical insulation properties. The first conductive layer is laminated on the support layer. The tab includes a first fixed part and a first extended part. The first fixed part and the first extended part are made of metal. The first fixed part and the first extended part are provided integrally. The first fixed part extends along the first conductive layer. The first extended part is extended from the first fixed part. The first fixed part includes a plurality of first protruding portions. The first fixed part is fixed on the first conductive layer by the first protruding portions penetrating into the first conductive layer.