H01M4/747

Lithium-sulfur secondary battery containing gradient electrolyte

A rechargeable lithium-sulfur cell comprising a cathode, an anode, a separator electronically separating the two electrodes, a first electrolyte in contact with the cathode, and a second electrolyte in contact with the anode, wherein the first electrolyte contains a first concentration, C.sub.1, of a first lithium salt dissolved in a first solvent when the first electrolyte is brought in contact with the cathode, and the second electrolyte contains a second concentration, C.sub.2, of a second lithium salt dissolved in a second solvent when the second electrolyte is brought in contact with the anode, wherein C.sub.1 is less than C.sub.2. The cell exhibits an exceptionally high specific energy and a long cycle life.

PREPARATION METHODS OF COMPOSITE CURRENT COLLECTORS FOR ZINC SECONDARY BATTERIES, NEGATIVE ELECTRODE PLATES, AND ZINC SECONDARY BATTERIES

The present disclosure provides a preparation method of a composite current collector for a zinc secondary battery, a negative electrode plate, and a zinc secondary battery. The preparation method of the composite current collector for the zinc secondary battery comprises: 1) disposing a layer of carbon cloth between two layers of zinc mesh, thermally pressing the two layers of zinc mesh with the carbon cloth, and rolling the two layers of zinc mesh with the carbon cloth to obtain a pressed zinc mesh; 2) soaking the pressed zinc mesh in a graphene dispersion, then taking out and drying the pressed zinc mesh after soaking; and 3) coating two surfaces of the dried pressed zinc mesh with a conductive paste and drying to obtain the composite current collector for the zinc secondary battery. According to the composite current collector for the zinc secondary battery, the two metal layers are made by compositing the zinc mesh and tin, and the carbon cloth is disposed between the two metal layers, such that corrosion of a zinc negative electrode during use of the battery is reduced while ensuring the conductivity of the current collector, and the cycle performance of the battery is improved.

Electrode for secondary battery, preparation thereof, and secondary battery and cable-type secondary battery comprising the same

The present disclosure provides a sheet-form electrode for a secondary battery, comprising a current collector; an electrode active material layer formed on one surface of the current collector; and a first porous supporting layer formed on the electrode active material layer. The sheet-form electrode for a secondary battery according to the present disclosure has supporting layers on at least one surface thereof to exhibit surprisingly improved flexibility and prevent the release of the electrode active material layer from a current collector even if intense external forces are applied to the electrode, thereby preventing the decrease of battery capacity and improving the cycle life characteristic of the battery.

CORRUGATED FUEL ELECTRODE

A fuel electrode incorporates a first and second corrugated portion that are attached to each other at offset angles respect to their corrugation axis and therefore reinforce each other. A first corrugated portion may extend orthogonally with respect to a second corrugated portion. The first and second corrugated portions may be formed from metal wire and may therefore have a very high volumetric void fraction and a high surface area to volume ratio (sa/vol). In addition, the strands of the wire may be selected to enable high conductivity to the current collectors while maximizing the sa/vol. In addition, the shape of the corrugation, including the period distance, amplitude and geometry may be selected with respect to the stiffness requirements and electrochemical cell application factors. The first and second corrugated portions may be calendared or crushed to reduce thickness of the fuel electrode.

Lithium-sulfur secondary battery containing gradient electrolyte

A rechargeable lithium-sulfur cell comprising a cathode, an anode, a separator electronically separating the two electrodes, a first electrolyte in contact with the cathode, and a second electrolyte in contact with the anode, wherein the first electrolyte contains a first concentration, C.sub.1, of a first lithium salt dissolved in a first solvent when the first electrolyte is brought in contact with the cathode, and the second electrolyte contains a second concentration, C.sub.2, of a second lithium salt dissolved in a second solvent when the second electrolyte is brought in contact with the anode, wherein C.sub.1 is less than C.sub.2. The cell exhibits an exceptionally high specific energy and a long cycle life.

Foil-like functional material and method for the production therof
12170377 · 2024-12-17 · ·

A foil-like functional material (1) providing a predefined function and may be used for targeted physical, chemical, physicochemical, biological, technical and technological purposes, and in which is arranged a support medium (2), which comprises a total support volume, has a cross-sectional extent (7) of 100 m, like a matrix, and is formed from linear support elements (3a) and node-like support elements (3b), which form the substance components of the support medium (2) and pass through the total support volume to form a strip-like extent with interconnected partial volumes (5), situated therein and spanned by support elements (3) close by. The support elements (3) are sheathed with a first functional substance (4) which provides a first function. The remaining volume of the total support volume is filled with one second functional substance (6) which differs from the first function.

Lithiated transition metal oxides

Process for the fabrication of an electrode structure comprising an electrochemically active material suitable for use in an energy storage device. The method includes electrodepositing the electrochemically active material onto an electrode in electrodeposition bath containing a non-aqueous electrolyte. The electrode structure can be used for various applications such as electrochemical energy storage devices including high power and high-energy lithium-ion batteries.

Three-dimensional net-like aluminum porous body, electrode using the aluminum porous body, nonaqueous electrolyte battery using the electrode, and nonaqueous electrolyte capacitor using the electrode

Provided are a three-dimensional net-like aluminum porous body in which the diameter of cells in the porous body is uneven in the thickness direction of the porous body; a current collector and an electrode each using the aluminum porous body; and methods for producing these members. The porous body is a three-dimensional net-like aluminum porous body in a sheet form, for a current collector, in which the diameter of cells in the porous body is uneven in the thickness direction of the porous body. When a cross section in the thickness direction of the three-dimensional net-like aluminum porous body is divided into three regions of a region 1, a region 2 and a region 3 in this order, the average cell diameter of the regions 1 and 3 is preferably different from the cell diameter of the region 2.

Supporter of lithium metal and methods thereof

A supporter of lithium metal, a material of the supporter of lithium metal is at least one of copper, an alloy of the copper, nickel, or an alloy of the nickel, and a surface of the supporter of lithium metal comprises a lithiophilic surface.

ELECTROCHEMICAL CELLS WITH MOBILE ELECTROLYTE
20170125829 · 2017-05-04 ·

An electrode comprising galvanic membranes having a thickness defined by an average length of vectors normal to a membrane first surface and extending to where said vectors intersect a membrane uncompressed second surface; a non-porous metal sheet having first and second surfaces; a non-porous dielectric sheet having first and second surfaces; square weave metal wire screens having a wire diameter slightly greater than one half the at least one galvanic membrane thickness dimension; wherein, at least one galvanic membrane is adjacent the metal wire screen on the at least one galvanic membrane first and second surfaces in a stack of membranes and screens; the metal wire screen is adjacent the first surface of the non-porous dielectric sheet; the second surfaces of non-porous metal sheets have a sustained pressure of at least 7 million Pascal; and; the metal wire screen is collectively in incompressible vertical alignment with another metal wire screen.