A novel adsorbent and contactor material based on polymer functionalized with amidoxime and alkylamines moieties. Methods of making the material are also described. The material can be easily processed into any desired sorbent geometry such as solid fibers, electrospun fibers, hollow fibers, monoliths, etc. The adsorbent exhibits a very high affinity toward acidic gases such CO.sub.2 and can be used in direct air capture, power plant-based CO.sub.2 capture, and industrial CO.sub.2 capture applications. The material can also serve as a contactor that accommodates other adsorbents within its structure.

Disclosed is a method of manufacturing an air separation module (ASM) of a nitrogen generation system (NGS), the method providing: determining an at least partially nonlinear shape between opposing ends of a canister, the canister being configured to fit within an installation envelope for the ASM in the NGS and configured to have installed therein an air separating membrane; and additively manufacturing the canister.

Redundant electrochemical systems and methods for vehicles are described. The systems include a first electrochemical device located at a first position on the vehicle wherein the first electrochemical device is configured to generate at least one of inert gas, oxygen, and electrical power and a second electrochemical device located at a second position on the vehicle wherein the second electrochemical device is configured to generate at least one of inert gas, oxygen, and electrical power. The first electrochemical device is configured to operate in a first mode during normal operation of the vehicle and a second mode when the second electrochemical device fails, wherein in the second mode, the first electrochemical device provides the at least one of inert gas, oxygen, and electrical power for at least one vehicle critical system of the vehicle.

A plugin modular, transportable ammonia producing machine is developed that can conveniently produce ammonia from electricity, air and water. The invention includes ammonia synthesis through a plugin modular device. FIG. 5 depicts the overall process flow of the system. Water at state 1 enters the system at room temperature in the water storage tank. Next, at state 2, the water in the storage tank is sent to the circulation pump that delivers water to the air compressor. This is done for two main purposes. Firstly, the circulating water cools the compressor during operation. Secondly, as the circulating water rises in temperature while leaving the air compressor, its temperature increases. This results in an increased inlet water temperature to the proton exchange membrane (PEM) electrolyser that leads to higher water electrolysis performance.

A vacuum system for use with a deoxygenator system includes a housing, a movable assembly positioned within the housing, and a biasing mechanism coupling the movable assembly to the housing. The movable assembly is movable between a first position and a second position within the housing to form a low pressure area between the housing and the movable assembly. A control system including at least one pressure source is arranged in fluid communication with the low pressure area. The control system is operable to selectively communicate fluid from the at least one pressure source to the housing to form the low pressure area.

Described are methods, devices, and systems useful for removing gaseous ammonia from a gas mixture at a pressure in an ambient pressure range by allowing the ammonia to adsorb onto a solid adsorbent, as well as related systems and methods.

An aminated siliceous adsorbent, which is the reaction product of dried acidified rice husk ash having disordered mesopores and an amino silane, wherein amine functional groups are present on an external surface and within the mesopores of the dried acidified rice husk ash, and wherein the aminated siliceous adsorbent has a carbon content of 24 to 30 wt. %, based on a total weight of the aminated siliceous adsorbent. A method of making the aminated siliceous adsorbent and a method of capturing CO.sub.2 from a gas mixture with the aminated siliceous adsorbent.

Disclosed in the present invention are a pressure equalizing system for air separation purification, and a control method. The system comprises: a first air main pipe; a pressurizing gas pipeline, which is connected to the first air main pipe and used for receiving a pressurizing gas and delivering same to the first air main pipe; and a control valve, located on the pressurizing gas pipeline, and having a degree of opening regulated by the flow regulator, thereby regulating an air intake amount of the pressurizing gas pipeline. The present invention solves the problem of an air separation rectification process being affected when dry nitrogen is used for pressure equalization of an adsorber; in the switching process of entering an adsorption stage from a regeneration stage, pressurizing dry nitrogen used in a pressure equalizing step previously mixes with damp air from a main air compressor before entering the adsorber, such that the gas components flowing towards an air separation cold box remain substantially unchanged, in order to reduce disturbance in conditions of gas entering a rectification column to take part in rectification due to a gas component gradually changing from dry nitrogen to dry air in the prior art, thus stabilizing the process conditions of the air separation cold box.

It is provided a water-saturated carbon molecular sieve membrane obtainable by a) providing a hydrophilic carbon molecular sieve membrane (CMSM) comprising pores of a pore size from 0.25 nm to 0.55 nm for molecular sieving, pores of a pore size from 0.55 nm to 0.90 nm for adsorption diffusion and a negligible amount of pores larger than 0.90 nm such that a plot of N.sub.2 permeance versus pressure of permeation at room temperature and at a pressure from 1 to 4 bar has zero or negative slope; and b) humidifying the membrane until obtaining a water-saturated carbon molecular sieve membrane. It is also provided a process for the separation of a gas from a gas mixture with such a water-saturated membrane, and its use for solvent dehydration, and as a membrane reactor.

A membrane including a polymer substrate having pore channels and a metal-organic framework disposed on the polymer substrate. Methods of producing the membrane are described. Methods of separating gases using the membrane are also provided.