Method and systems are disclosed for selectively removing naturally-occurring sugars in beverages in an effective, affordable and scalable manner.

Provided is a method for manufacturing a polymer fiber adsorbent having an MOF uniformly distributed in the matrix thereof, the method comprising the steps of: spinning a spinning dope comprising a polymer matrix and a metal precursor of an MOF to prepare a polymer fiber adsorbent precursor comprising the metal precursor; and contacting the polymer fiber adsorbent precursor with an organic ligand of the MOF to form an MOF in the polymer fiber adsorbent precursor. A polymer fiber adsorbent manufacturing method provided by an aspect of the present invention offers a method capable of easy synthesis of an MOF which is sensitive to water, thereby obtaining a polymer fiber adsorbent excellent in terms of adsorption performance and long-term stability.

Despite the fact that the amount and type of gas to be stored may vary in accordance with the type of substituent, metal-organic frameworks only using a terephthalic acid having substituents within the limited range have been produced conventionally. An object of the present invention is to provide a novel metal-organic framework using a 2,5-disubstituted terephthalic acid. A metal-organic framework comprising a carboxylate ion of formula (I) and a multivalent metal ion bound to each other is a novel metal-organic framework, enabling a gas such as hydrogen and nitrogen to be store efficiently. (wherein in formula (I), X is an unsubstituted or substituted cycloalkyl group, an unsubstituted or substituted aryl group, an unsubstituted or substituted heterocyclyl group or —Si(R.sup.1) (R.sup.2) (R.sup.3) ; and Y is a single bond, an alkylene group, —O—, —S—, —S(O)—, —SO.sub.2—, —N(R.sup.4)— or a group formed by a combination thereof; provided that X—Y— is a phenyl group, a benzyloxy group, a pyrazol-1-yl group or a group of formula (II) except for a case where m is 3, 6, 8, 9, 10, 11 and 12).

##STR00001##

A method for capturing CO.sub.2 from a gas stream using a metal organic framework (MOF) based physisorbent CO.sub.2 concentrator is provided. In the method, MOF material is pretreated, a gas stream is then introduced into the CO.sub.2 concentrator which comprises the pretreated MOF material. CO.sub.2 from the gas stream is captured with the CO.sub.2 concentrator to generate a CO.sub.2-free stream, which is discharged the from the CO.sub.2 concentrator into the atmosphere. Introduction of the gas stream into the CO.sub.2 concentrator is stopped when the pretreated MOF material becomes saturated with CO.sub.2. The CO.sub.2 concentrator with the saturated MOF material is then regenerated by introducing hot air, hot nitrogen, vacuum, or a combination thereof into the CO.sub.2 concentrator thereby generating a CO.sub.2-rich stream. The CO.sub.2-rich stream is diverted for purification and the regenerated CO.sub.2 concentrator is recycled for future capture of CO.sub.2.

Embodiments of the present disclosure pertain to methods of capturing one or more ions from an environment by associating the environment with a composition that includes a metal-organic framework. The association results in the capture of the one or more ions by the metal-organic framework. The metal-organic frameworks may include a plurality of metals and a plurality of triphenylene-based ligands that interconnect the plurality of the metals. The methods of the present disclosure may also include a step of detecting one or more captured ions. Additional embodiments of the present disclosure pertain to the compositions for capturing one or more ions from an environment.

The present invention relates to an adsorbent suitable for the adsorption of MOAH and/or MOSH compounds, the use of the adsorbent for the production of a packaging material or a container comprising the adsorbent, the process of production of the packaging material or container as well as the respective packaging material and container.

The present invention relates to an adsorbent suitable for the adsorption of MOAH and/or MOSH compounds, the use of the adsorbent for the production of a packaging material or a container comprising the adsorbent, the process of production of the packaging material or container as well as the respective packaging material and container.

A sparsely pillared organic-inorganic hybrid compound is provided. The sparsely pillared organic-inorganic hybrid compound includes: two inorganic material layers, each extending in one direction and facing each other; and an organic material layer disposed between the two inorganic material layers, wherein each of the inorganic material layers has a gibbsite structure in which a divalent metal cation is doped to an octahedral site, and the organic material layer includes a plurality of pillar portions, each of which is chemically bound to each of the two inorganic material layers such that the two inorganic material layers are connected to each other.

A method for making a metal-organic framework, MOF, as nanosheets, includes providing a MXene, wherein the MXene has a general formula of M.sub.n+1X.sub.nT.sub.x, with n=1-3, M represents an early transition metal, X is C and/or N, and Tx is surface terminations; providing a ligand; mixing the MXene and the ligand in a vessel; heating the MXene and the ligand in the vessel; and forming the MX-MOF nanosheets. The MX-MOF nanosheets have a thickness less than 10 nm.

A method for forming an amine-functionalized solid CO.sub.2 sorbent for carbon capture may include providing a support material and applying at least one cycle of molecular layer deposition (MLD) with an amine precursor onto the surface of the support material. An amine layer formed on the support material contains amine groups/amine-containing ligands to adsorb CO.sub.2 onto the support material in a low temperature operating window for adsorption and desorption without the loss of active sites.