The present disclosure relates to compositions including metal-organic framework materials and a polymeric binder. The compositions may have a crush strength of about 2.5 lb-force or greater. The present disclosure also relates to processes for producing metal-organic framework extrudates. Processes may include mixing a metal-organic framework material, a polymeric binder, and optionally a solvent to form a mixture. The process may also include extruding the mixture to form a metal-organic framework extrudate.

This invention relates to a process for treating acid mine drainage (AMD). The process includes the steps of adjusting the pH of the AMD to be in the range of 3 to 5; adding maghemite nanoparticles to form a slurry; and a) aerating the slurry obtained in step 3), or b) simultaneously heating and mixing the slurry obtained in step 3). Thereafter maghemite nanoparticles loaded with one or more metals and sulphate and precipitated metals is separated from the slurry.

Materials for decontamination of compounds having a phosphorous-sulfur bond or a phosphorous-oxygen bond. A porous polymer, such as poly(dicyclopentadiene), contains particles of zirconium hydroxide. The polymer optionally has hydroperoxide groups.

The present disclosure relates to synthesis of porous polymer networks and applications of such materials. The present disclosure relates to a method of fabricating of a porous polymer network comprising: (a) providing: (i) a first reactant comprising a plurality of compounds comprising at least one acetyl group, said plurality of compounds comprising at least one compound type, and (ii) a second reactant comprising an alkylsulfonic acid, and (b) creating a solution of said reactants, (c) casting said solution in a form, and (d) treating said solution under such conditions so as to produce a porous polymer network. In one embodiment, the invention relates to a porous polymer network which has a basic structure selected from the group consisting of ##STR00001##

A silver-doped, nano-porous hydroxyapatite material is provided that can be utilized to capture radioactive iodine, .sup.129I. Methods of using the silver-doped, nano-porous hydroxyapatite material to remove radioactive iodine, and methods of manufacturing the material are also provided.

Provided is a method for manufacturing a polymer fiber adsorbent having an MOF uniformly distributed in the matrix thereof, the method comprising the steps of: spinning a spinning dope comprising a polymer matrix and a metal precursor of an MOF to prepare a polymer fiber adsorbent precursor comprising the metal precursor; and contacting the polymer fiber adsorbent precursor with an organic ligand of the MOF to form an MOF in the polymer fiber adsorbent precursor. A polymer fiber adsorbent manufacturing method provided by an aspect of the present invention offers a method capable of easy synthesis of an MOF which is sensitive to water, thereby obtaining a polymer fiber adsorbent excellent in terms of adsorption performance and long-term stability.

A process for preparing a granular composite adsorbent, that includes combining poly (diallyl dimethyl ammonium halide) and a clay mineral in water, maintaining the mixture under stirring, recovering a wet mass, forming the wet mass into granules and drying the granules to obtain the granular adsorbent having surface layer with positive zeta potential. The granular material and methods using the granular material in water treatment are also disclosed.

A binderless zeolite adsorbent for separation of oxygen from a gaseous stream. The adsorbent is a blend of a lithium exchanged zeolite 13X, a lithium exchanged low silica zeolite X zeolite, and halloysite clay. Also disclosed is a process of making the binderless zeolite adsorbent. Further disclosed is a process for production of oxygen from a gaseous stream utilizing the binderless zeolite adsorbent.

A porous sorbent ceramic product includes a three-dimensional structure having an electrically conductive ceramic material, wherein the conductive ceramic material has an open cell structure with a plurality of intra-material pores, a sorbent additive primarily present in the intra-material pores of the conductive ceramic material for adsorption of a gas, and at least two electrodes in electrical communication with the conductive ceramic material.

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5 Å for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.